[PtCl3(C2H4)]-[AmH]+ Complexes Containing Chiral Secondary Amines:  Use as Chiral Derivatizing Agents for the Enantiodiscrimination of Unsaturated Compounds by 195Pt NMR Spectroscopy and NMR Stereochemical Investigation

Ionic complexes [PtCl3(C2H4)]-[AmH]+, containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via 195Pt NMR spectroscopy. The NMR conformational analysis allows us to search for th...

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Bibliographic Details
Published inJournal of organic chemistry Vol. 66; no. 1; pp. 123 - 129
Main Authors Uccello-Barretta, Gloria, Bernardini, Raffaella, Balzano, Federica, Salvadori, Piero
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 12.01.2001
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Summary:Ionic complexes [PtCl3(C2H4)]-[AmH]+, containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via 195Pt NMR spectroscopy. The NMR conformational analysis allows us to search for the stereochemical basis of their enhanced versatility.
Bibliography:ark:/67375/TPS-BRM0HNP8-8
istex:526BF95B2FCB36D103C6A44AD88774A2C52522E7
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo001165t