[PtCl3(C2H4)]-[AmH]+ Complexes Containing Chiral Secondary Amines: Use as Chiral Derivatizing Agents for the Enantiodiscrimination of Unsaturated Compounds by 195Pt NMR Spectroscopy and NMR Stereochemical Investigation
Ionic complexes [PtCl3(C2H4)]-[AmH]+, containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via 195Pt NMR spectroscopy. The NMR conformational analysis allows us to search for th...
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Published in | Journal of organic chemistry Vol. 66; no. 1; pp. 123 - 129 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
12.01.2001
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Online Access | Get full text |
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Summary: | Ionic complexes [PtCl3(C2H4)]-[AmH]+, containing chiral secondary amines, constitute a versatile class of chiral derivatizing agents (CDAs) for the enantiomeric purity determination of chiral unsaturated compounds via 195Pt NMR spectroscopy. The NMR conformational analysis allows us to search for the stereochemical basis of their enhanced versatility. |
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Bibliography: | ark:/67375/TPS-BRM0HNP8-8 istex:526BF95B2FCB36D103C6A44AD88774A2C52522E7 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0022-3263 1520-6904 |
DOI: | 10.1021/jo001165t |