Hydroboration of Phosphaalkynes by HB(C6F5)(2)
The hydroboration of phosphaalkynes with Piers' borane (HB(C6F5)(2)) generated unusual phosphaalkenylboranes [RCH=PB(C6F5)(2)](2) that persisted as dimers in both solution and the solid state. These P2B2 heterocycles underwent ring opening when subjected to nucleophiles, such as pyridine and te...
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Published in | Chemistry : a European journal Vol. 22; no. 36; pp. 12665 - 12669 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
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Wiley
26.08.2016
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Abstract | The hydroboration of phosphaalkynes with Piers' borane (HB(C6F5)(2)) generated unusual phosphaalkenylboranes [RCH=PB(C6F5)(2)](2) that persisted as dimers in both solution and the solid state. These P2B2 heterocycles underwent ring opening when subjected to nucleophiles, such as pyridine and tert-butylisocyanide, to yield monomeric phosphaalkenylborane adducts RCH=PB(C6F5)(2)(L). DFT calculations were performed to probe the nature of the interaction of phosphaalkynes with boranes. |
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AbstractList | The hydroboration of phosphaalkynes with Piers' borane (HB(C6F5)(2)) generated unusual phosphaalkenylboranes [RCH=PB(C6F5)(2)](2) that persisted as dimers in both solution and the solid state. These P2B2 heterocycles underwent ring opening when subjected to nucleophiles, such as pyridine and tert-butylisocyanide, to yield monomeric phosphaalkenylborane adducts RCH=PB(C6F5)(2)(L). DFT calculations were performed to probe the nature of the interaction of phosphaalkynes with boranes. |
Author | Russell, Christopher A. Longobardi, Lauren E. Stephan, Douglas W. Johnstone, Timothy C. Falconer, Rosalyn L. |
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Keywords | COORDINATION CHEMISTRY ACTIVATION CARBON hydroboration COMPLEXES SINGLET DIRADICALS REACTIVITY phosphaalkyne FRUSTRATED LEWIS PAIRS PHOSPHORUS-COMPOUNDS heterocycles BORENIUM CATIONS BOND phosphaalkene phosphaalkenylborane |
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Snippet | The hydroboration of phosphaalkynes with Piers' borane (HB(C6F5)(2)) generated unusual phosphaalkenylboranes [RCH=PB(C6F5)(2)](2) that persisted as dimers in... |
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Title | Hydroboration of Phosphaalkynes by HB(C6F5)(2) |
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