Hyperbranched polyalkoxysiloxanes via AB(3)-type monomers
We have synthesized polyethoxysiloxanes starting from the AB(3)-type monomers triethoxysilanol and acetoxytriethoxysilane. The polymers are liquid and soluble in organic solvents. Si-29 NMR spectroscopy and MALDI-ToF mass spectrometry analyses show that the polymers have a hyperbranched structure wi...
Saved in:
Published in | Macromolecular chemistry and physics Vol. 204; no. 7; pp. 1014 - 1026 |
---|---|
Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
WEINHEIM
Wiley
07.05.2003
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Abstract | We have synthesized polyethoxysiloxanes starting from the AB(3)-type monomers triethoxysilanol and acetoxytriethoxysilane. The polymers are liquid and soluble in organic solvents. Si-29 NMR spectroscopy and MALDI-ToF mass spectrometry analyses show that the polymers have a hyperbranched structure with additional internal cyclization. Si-29 NMR spectroscopy indicates that the polymer synthesized from acetoxytriethoxysilane is less branched than the polymer synthesized from triethoxysilanol. Analysis of the molar mass and mass distribution of the polymers via size exclusion chromatography (calibrated via MALDI-ToF MS and viscosimetry) yields a molar mass of (M) over bar (n)approximate to2 kg.mol(-1) and (M) over bar (w)approximate to8 kg.mol(-1) for polymers synthesized from triethoxysilanol. The molar mass of the polymers synthesized from acetoxytriethoxysilane can be controlled by variation of the polymerization time in the range of (M) over bar (n)approximate to1.8-12 kg.mol(-1) and (M) over bar (w)approximate to2.1-2 200 kg.mol(-1). |
---|---|
AbstractList | We have synthesized polyethoxysiloxanes starting from the AB(3)-type monomers triethoxysilanol and acetoxytriethoxysilane. The polymers are liquid and soluble in organic solvents. Si-29 NMR spectroscopy and MALDI-ToF mass spectrometry analyses show that the polymers have a hyperbranched structure with additional internal cyclization. Si-29 NMR spectroscopy indicates that the polymer synthesized from acetoxytriethoxysilane is less branched than the polymer synthesized from triethoxysilanol. Analysis of the molar mass and mass distribution of the polymers via size exclusion chromatography (calibrated via MALDI-ToF MS and viscosimetry) yields a molar mass of (M) over bar (n)approximate to2 kg.mol(-1) and (M) over bar (w)approximate to8 kg.mol(-1) for polymers synthesized from triethoxysilanol. The molar mass of the polymers synthesized from acetoxytriethoxysilane can be controlled by variation of the polymerization time in the range of (M) over bar (n)approximate to1.8-12 kg.mol(-1) and (M) over bar (w)approximate to2.1-2 200 kg.mol(-1). |
Author | Rebrov, EA Jaumann, M Kazakova, VV Muzafarov, AM Goedel, WA Moller, M |
Author_xml | – sequence: 1 givenname: M surname: Jaumann fullname: Jaumann, M – sequence: 2 givenname: EA surname: Rebrov fullname: Rebrov, EA – sequence: 3 givenname: VV surname: Kazakova fullname: Kazakova, VV – sequence: 4 givenname: AM orcidid: 0000-0002-3050-3253 surname: Muzafarov fullname: Muzafarov, AM email: aziz@ispm.ru – sequence: 5 givenname: WA surname: Goedel fullname: Goedel, WA email: werner.goedel@chemie.uni-ulm.de – sequence: 6 givenname: M surname: Moller fullname: Moller, M email: moeller@dwi.rwth-aachen.de |
BookMark | eNqVzUsKwjAUheEgCj6njjtUpHqT0NoMtSguwLnEesVom1uS-ujureACdHT-wQenz9qWLDI25jDnAGJR6KycCwCpAOJli_V4JHgolYzaTYMQIZeR6LK-91cASEAte0zt6hLd0WmbXfAUlJTXOr_Rq_Ymp5e26IOH0cFqPZHTsGpsUJClAp0fss5Z5x5H3x2w2XazT3fhE4909plBm-GhdKbQrj40hzwRKk7iT3H5r05-16mpdGXIpnS3lXwDpq5Vtw |
Cites_doi | 10.1021/ma0014766 |
ContentType | Journal Article |
DBID | 1KM BLEPL DTL FVWVB |
DOI | 10.1002/macp.200390067 |
DatabaseName | Index Chemicus Web of Science Core Collection Science Citation Index Expanded Web of Science - Science Citation Index Expanded - 2003 |
DatabaseTitle | Web of Science |
DatabaseTitleList | Web of Science |
Database_xml | – sequence: 1 dbid: 1KM name: Index Chemicus url: https://proxy.k.utb.cz/login?url=https://www.webofscience.com/wos/woscc/search-with-editions?editions=WOS.IC sourceTypes: Index Database Enrichment Source |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1521-3935 |
EndPage | 1026 |
ExternalDocumentID | 000182968600011 |
GroupedDBID | -~X .3N .GA .Y3 05W 0R~ 10A 1KM 1L6 1OB 1OC 1ZS 31~ 33P 3SF 3WU 4ZD 50Y 50Z 51W 51X 52M 52N 52O 52P 52S 52T 52U 52W 52X 53G 5GY 5VS 66C 6P2 702 7PT 8-0 8-1 8-3 8-4 8-5 8UM 930 A03 AAESR AAEVG AAHHS AANLZ AAONW AASGY AAXRX AAZKR ABCQN ABCUV ABIJN ABJNI ABLJU ABPVW ACAHQ ACBWZ ACCFJ ACCZN ACGFS ACIWK ACPOU ACXBN ACXQS ADBBV ADEOM ADIZJ ADKYN ADMGS ADOZA ADXAS ADZMN AEEZP AEIGN AEIMD AENEX AEQDE AEUQT AEUYR AFBPY AFFPM AFGKR AFPWT AFZJQ AHBTC AITYG AIURR AIWBW AJBDE AJXKR ALAGY ALMA_UNASSIGNED_HOLDINGS ALUQN AMBMR AMYDB ATUGU AUFTA AZBYB AZFZN AZVAB BAFTC BDRZF BFHJK BHBCM BLEPL BMNLL BMXJE BNHUX BROTX BRXPI BY8 CS3 D-E D-F DCZOG DPXWK DR1 DR2 DRFUL DRSTM DTL DU5 EBS EJD F00 F01 F04 F5P FEDTE G-S G.N GNP GODZA GROUPED_WOS_SCIENCE_CITATION_INDEX_EXPANDED GYXMG H.T H.X HBH HGLYW HHY HHZ HVGLF HZ~ IX1 J0M JPC KQQ LATKE LAW LC2 LC3 LEEKS LH4 LITHE LOXES LP6 LP7 LUTES LW6 LYRES MEWTI MK4 MRFUL MRSTM MSFUL MSSTM MXFUL MXSTM N04 N05 N9A NF~ NNB O66 O9- OIG P2P P2W P2X P4D Q.N Q11 QB0 QRW R.K RNS ROL RWB RWI RX1 SUPJJ UB1 V2E W8V W99 WBKPD WFSAM WIB WIH WIK WJL WOHZO WQJ WRC WXSBR WYISQ XG1 XPP XV2 ZZTAW ~IA ~WT |
ID | FETCH-webofscience_primary_0001829686000113 |
ISICitedReferencesCount | 67 |
ISICitedReferencesURI | https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=CitingArticles&UT=000182968600011 |
ISSN | 1022-1352 |
IngestDate | Wed Sep 18 01:51:27 EDT 2024 Fri Oct 11 20:14:07 EDT 2024 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 7 |
Keywords | gel permeation chromatography (GPC) POLYMERS RATES CONDENSING VINYL POLYMERIZATION ACID MALDI ethylsilicate polyethoxysiloxane branched POLYCONDENSATION hyperbranched polymers |
Language | English |
LinkModel | OpenURL |
LogoURL | https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg |
MergedId | FETCHMERGED-webofscience_primary_0001829686000113 |
ORCID | 0000-0002-3050-3253 |
PageCount | 13 |
ParticipantIDs | webofscience_primary_000182968600011 webofscience_primary_000182968600011CitationCount |
PublicationCentury | 2000 |
PublicationDate | 2003-05-07 |
PublicationDateYYYYMMDD | 2003-05-07 |
PublicationDate_xml | – month: 05 year: 2003 text: 2003-05-07 day: 07 |
PublicationDecade | 2000 |
PublicationPlace | WEINHEIM |
PublicationPlace_xml | – name: WEINHEIM |
PublicationTitle | Macromolecular chemistry and physics |
PublicationTitleAbbrev | MACROMOL CHEM PHYS |
PublicationYear | 2003 |
Publisher | Wiley |
Publisher_xml | – name: Wiley |
References | BOULOS EN (WOS:000182968600011.5) 1988; 121 BRINKER CJ (WOS:000182968600011.6) 1990 Roth, MJ (WOS:A1996VG42500010) 1996; 521 KIM, YH (WOS:A1990DE90200094) 1990; 112 Simon, PFW (WOS:000167372100026) 2001; 34 Voit, B (WOS:000087656700001) 2000; 38 AYEN RJ (WOS:000182968600011.2) 1986; 73 KELTS LW (WOS:000182968600011.32) 1988; 121 Haag, R (WOS:000166762000001) 2001; 7 TURNER, SR (WOS:A1993LT71100031) 1993; 26 SAKKA, S (WOS:A1984SH20600022) 1984; 63 HAWKER, CJ (WOS:A1991FP84400030) 1991; 113 ENGELHARDT, G (WOS:A1974S583500017) 1974; 14 (WOS:000182968600011.1) 1988 KAZAKOVA VV (WOS:000182968600011.29) 1999; 41 POUXVIEL, JC (WOS:A1987G515500009) 1987; 89 SANCHEZ, J (WOS:A1994MU68300008) 1994; 167 Czichocki, G (WOS:000170654100005) 2001; 38 Sunder, A (WOS:000088319900001) 2000; 6 BENOIT, H (WOS:A19668897500011) 1966; 63 KAZAKOVA VV (WOS:000182968600011.28) 1996; 349 Boogh, L (WOS:A1997WA62100008) 1997; 33 COGAN JD (WOS:000182968600011.10) 1946; 24 GOEDEL WA (WOS:000182968600011.17) 2001; 42 BRINKER CJ (WOS:000182968600011.7) 1990 Post, HW (WOS:000200574200012) 1940; 5 KAZAKOVA V (WOS:000182968600011.30) 1998; 39 KELTS, LW (WOS:A1989T619400028) 1989; 4 Holter, D (WOS:A1997WJ95100005) 1997; 48 BRINKER CJ (WOS:000182968600011.8) 1990 FLORY, PJ (WOS:A1952UB42200008) 1952; 74 KIM YH (WOS:000182968600011.33) 1999; 53 Yan, DY (WOS:A1997YH24700002) 1997; 30 SUGAHARA, Y (WOS:A1992JW92000005) 1992; 147 WOOLEY, KL (WOS:A1994PM11600003) 1994; 35 VOIGT BJ (WOS:000182968600011.47) 1995; 46 SAKKA, S (WOS:A1986C996300005) 1986; 82 Hook, RJ (WOS:A1996UA87000001) 1996; 195 FRECHET, JMJ (WOS:A1995RQ74800037) 1995; 269 GOLDWASSER, JM (WOS:A1993KX84200016) 1993; 521 Hedrick, JL (WOS:A1997YJ88700037) 1997; 30 Xiao, YX (WOS:000170837900020) 2001; 39 GRUBISIC, Z (WOS:A19679972800003) 1967; 5 UNGER, K (WOS:A1975AP15700005) 1975; 253 Gong, CG (WOS:000088329800015) 2000; 38 Brus, J (WOS:A1996UN13500004) 1996; 61 Holter, D (WOS:A1997XQ79200002) 1997; 48 TOMALIA, DA (WOS:A1985ACB5700010) 1985; 17 Emrick, T (WOS:000165713600024) 2000; 38 Hanselmann, R (WOS:000074343700005) 1998; 31 Gaynor, SG (WOS:A1996TT68800046) 1996; 29 |
References_xml | – volume: 38 start-page: 168 year: 2001 ident: WOS:000170654100005 article-title: Synthesis of polyisoprenes with sulfonate head groups and their purification by HPLC publication-title: TENSIDE SURFACTANTS DETERGENTS contributor: fullname: Czichocki, G – volume: 121 start-page: 519 year: 1988 ident: WOS:000182968600011.32 publication-title: MATER RES SOC S P contributor: fullname: KELTS LW – volume: 38 start-page: 2970 year: 2000 ident: WOS:000088329800015 article-title: End functionalization of hyperbranched poly(siloxysilane): Novel crosslinking agents and hyperbranched-linear star block copolymers publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY contributor: fullname: Gong, CG – volume: 7 start-page: 327 year: 2001 ident: WOS:000166762000001 article-title: Dendrimers and hyperbranched polymers as high-loading supports for organic synthesis publication-title: CHEMISTRY-A EUROPEAN JOURNAL contributor: fullname: Haag, R – volume: 74 start-page: 2718 year: 1952 ident: WOS:A1952UB42200008 article-title: MOLECULAR SIZE DISTRIBUTION IN THREE DIMENSIONAL POLYMERS .6. BRANCHED POLYMERS CONTAINING A-R-BF-1 TYPE UNITS publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: FLORY, PJ – volume: 195 start-page: 1 year: 1996 ident: WOS:A1996UA87000001 article-title: A Si-29 NMR study of the sol-gel polymerisation rates of substituted ethoxysilanes publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: Hook, RJ – volume: 42 start-page: 242 year: 2001 ident: WOS:000182968600011.17 publication-title: POLYM PREPR AM CHEM contributor: fullname: GOEDEL WA – volume: 46 start-page: 87 year: 1995 ident: WOS:000182968600011.47 publication-title: ACTA POLYM contributor: fullname: VOIGT BJ – volume: 61 start-page: 691 year: 1996 ident: WOS:A1996UN13500004 article-title: Si-29 NMR study of distribution of oligomers in polycondensation of tetraethoxysilane publication-title: COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS contributor: fullname: Brus, J – volume: 33 start-page: 45 year: 1997 ident: WOS:A1997WA62100008 article-title: Novel tougheners for epoxy-based composites publication-title: SAMPE JOURNAL contributor: fullname: Boogh, L – volume: 30 start-page: 7024 year: 1997 ident: WOS:A1997YH24700002 article-title: Molecular parameters of hyperbranched polymers made by self-condensing vinyl polymerization .2. Degree of branching publication-title: MACROMOLECULES contributor: fullname: Yan, DY – volume: 29 start-page: 1079 year: 1996 ident: WOS:A1996TT68800046 article-title: Synthesis of branched and hyperbranched polystyrenes publication-title: MACROMOLECULES contributor: fullname: Gaynor, SG – volume: 113 start-page: 4583 year: 1991 ident: WOS:A1991FP84400030 article-title: ONE-STEP SYNTHESIS OF HYPERBRANCHED DENDRITIC POLYESTERS publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: HAWKER, CJ – volume: 48 start-page: 298 year: 1997 ident: WOS:A1997XQ79200002 article-title: Degree of branching in hyperbranched polymers .2. Enhancement of the DB: Scope and limitations publication-title: ACTA POLYMERICA contributor: fullname: Holter, D – volume: 269 start-page: 1080 year: 1995 ident: WOS:A1995RQ74800037 article-title: SELF-CONDENSING VINYL POLYMERIZATION - AN APPROACH TO DENDRITIC MATERIALS publication-title: SCIENCE contributor: fullname: FRECHET, JMJ – volume: 6 start-page: 2499 year: 2000 ident: WOS:000088319900001 article-title: Controlling the growth of polymer trees: Concepts and perspectives for hyperbranched polymers publication-title: CHEMISTRY-A EUROPEAN JOURNAL contributor: fullname: Sunder, A – volume: 82 start-page: 24 year: 1986 ident: WOS:A1986C996300005 article-title: HYDROLYSIS AND POLYCONDENSATION OF DIMETHYLDIETHOXYSILANE AND METHYLTRIETHOXYSILANE AS MATERIALS FOR THE SOL-GEL PROCESS publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: SAKKA, S – volume: 63 start-page: 1507 year: 1966 ident: WOS:A19668897500011 article-title: ETUDE PAR CHROMATOGRAPHIE EN PHASE LIQUIDE DE POLYSTYRENES LINEAIRES ET RAMIFIES DE STRUCTURES CONNUES publication-title: JOURNAL DE CHIMIE PHYSIQUE contributor: fullname: BENOIT, H – volume: 112 start-page: 4592 year: 1990 ident: WOS:A1990DE90200094 article-title: WATER-SOLUBLE HYPERBRANCHED POLYPHENYLENE - A UNIMOLECULAR MICELLE publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: KIM, YH – volume: 63 start-page: 223 year: 1984 ident: WOS:A1984SH20600022 article-title: FORMATION OF SHEETS AND COATING FILMS FROM ALKOXIDE SOLUTIONS publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: SAKKA, S – volume: 17 start-page: 117 year: 1985 ident: WOS:A1985ACB5700010 article-title: A NEW CLASS OF POLYMERS - STARBURST-DENDRITIC MACROMOLECULES publication-title: POLYMER JOURNAL contributor: fullname: TOMALIA, DA – volume: 73 start-page: 801 year: 1986 ident: WOS:000182968600011.2 publication-title: MATER RES SOC S P contributor: fullname: AYEN RJ – year: 1988 ident: WOS:000182968600011.1 – volume: 5 start-page: 443 year: 1940 ident: WOS:000200574200012 article-title: Studies in silico-organic compounds. (II). The reactions of silicoorthoesters with certain acid anhydrides publication-title: JOURNAL OF ORGANIC CHEMISTRY contributor: fullname: Post, HW – start-page: 541 year: 1990 ident: WOS:000182968600011.7 publication-title: SOL GEL SCI contributor: fullname: BRINKER CJ – volume: 121 start-page: 531 year: 1988 ident: WOS:000182968600011.5 publication-title: MAT RES SOC P contributor: fullname: BOULOS EN – volume: 253 start-page: 658 year: 1975 ident: WOS:A1975AP15700005 article-title: POROUS SILICON DIOXIDE WITH VARIABLE AND REPRODUCIBLE PORE STRUCTURE FROM POLYETHOXYSILOXANE publication-title: COLLOID AND POLYMER SCIENCE contributor: fullname: UNGER, K – volume: 26 start-page: 4617 year: 1993 ident: WOS:A1993LT71100031 article-title: ALL-AROMATIC HYPERBRANCHED POLYESTERS WITH PHENOL AND ACETATE END-GROUPS - SYNTHESIS AND CHARACTERIZATION publication-title: MACROMOLECULES contributor: fullname: TURNER, SR – volume: 521 start-page: 243 year: 1993 ident: WOS:A1993KX84200016 article-title: ABSOLUTE MN DETERMINED BY GEL-PERMEATION CHROMATOGRAPHY DIFFERENTIAL VISCOMETRY publication-title: ACS SYMPOSIUM SERIES contributor: fullname: GOLDWASSER, JM – volume: 53 start-page: 201 year: 1999 ident: WOS:000182968600011.33 publication-title: PLAST ENG contributor: fullname: KIM YH – volume: 41 start-page: 283 year: 1999 ident: WOS:000182968600011.29 publication-title: POLYM SCI SER A contributor: fullname: KAZAKOVA VV – start-page: 110 year: 1990 ident: WOS:000182968600011.8 publication-title: SOL GEL SCI contributor: fullname: BRINKER CJ – volume: 38 start-page: 2505 year: 2000 ident: WOS:000087656700001 article-title: New developments in hyperbranched polymers publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY contributor: fullname: Voit, B – volume: 521 start-page: 65 year: 1996 ident: WOS:A1996VG42500010 article-title: Hydrosilane cleavage reactions accelerated by tartaric acid and dimethyl sulphoxide publication-title: JOURNAL OF ORGANOMETALLIC CHEMISTRY contributor: fullname: Roth, MJ – volume: 39 start-page: 3383 year: 2001 ident: WOS:000170837900020 article-title: Hyperbranched polymers from propargyloxysilanes: New types of acetylenic resins publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY contributor: fullname: Xiao, YX – volume: 31 start-page: 3790 year: 1998 ident: WOS:000074343700005 article-title: Hyperbranched polymers prepared via the core-dilution/slow addition technique: Computer simulation of molecular weight distribution and degree of branching publication-title: MACROMOLECULES contributor: fullname: Hanselmann, R – volume: 39 start-page: 483 year: 1998 ident: WOS:000182968600011.30 publication-title: POLYM PREPR contributor: fullname: KAZAKOVA V – start-page: 102 year: 1990 ident: WOS:000182968600011.6 publication-title: SOL GEL SCI PHYSICS contributor: fullname: BRINKER CJ – volume: 167 start-page: 289 year: 1994 ident: WOS:A1994MU68300008 article-title: INTRAMOLECULAR VS INTERMOLECULAR CONDENSATION RATES IN THE ACIDIC POLYMERIZATION OF OCTAETHOXYTRISILOXANE publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: SANCHEZ, J – volume: 14 start-page: 109 year: 1974 ident: WOS:A1974S583500017 article-title: STRUCTURAL STUDIES ON SILICATE ANIONS IN AQUEOUS-SOLUTION USING SI-29 NMR-SPECTROSCOPY publication-title: ZEITSCHRIFT FUR CHEMIE contributor: fullname: ENGELHARDT, G – volume: 30 start-page: 7607 year: 1997 ident: WOS:A1997YJ88700037 article-title: Structure control in organic-inorganic hybrids using hyperbranched high-temperature polymers publication-title: MACROMOLECULES contributor: fullname: Hedrick, JL – volume: 5 start-page: 753 year: 1967 ident: WOS:A19679972800003 article-title: A UNIVERSAL CALIBRATION FOR GEL PERMEATION CHROMATOGRAPHY publication-title: JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS contributor: fullname: GRUBISIC, Z – volume: 48 start-page: 30 year: 1997 ident: WOS:A1997WJ95100005 article-title: Degree of branching in hyperbranched polymers publication-title: ACTA POLYMERICA contributor: fullname: Holter, D – volume: 35 start-page: 4489 year: 1994 ident: WOS:A1994PM11600003 article-title: INFLUENCE OF SHAPE ON THE REACTIVITY AND PROPERTIES OF DENDRITIC, HYPERBRANCHED AND LINEAR AROMATIC POLYESTERS publication-title: POLYMER contributor: fullname: WOOLEY, KL – volume: 89 start-page: 345 year: 1987 ident: WOS:A1987G515500009 article-title: NMR-STUDY OF THE SOL-GEL POLYMERIZATION publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: POUXVIEL, JC – volume: 4 start-page: 423 year: 1989 ident: WOS:A1989T619400028 article-title: A SI-29 NMR-STUDY OF THE STRUCTURAL INTERMEDIATES IN LOW PH SOL-GEL REACTIONS publication-title: JOURNAL OF MATERIALS RESEARCH contributor: fullname: KELTS, LW – volume: 24 start-page: 2499 year: 1946 ident: WOS:000182968600011.10 publication-title: CHEM ENG NEWS contributor: fullname: COGAN JD – volume: 34 start-page: 1677 year: 2001 ident: WOS:000167372100026 article-title: Characterization of highly branched poly(methyl methacrylate) by solution viscosity and viscoelastic spectroscopy publication-title: MACROMOLECULES doi: 10.1021/ma0014766 contributor: fullname: Simon, PFW – volume: 349 start-page: 190 year: 1996 ident: WOS:000182968600011.28 publication-title: DOKL CHEM contributor: fullname: KAZAKOVA VV – volume: 38 start-page: 4850 year: 2000 ident: WOS:000165713600024 article-title: The preparation of hyperbranched aromatic and aliphatic polyether epoxies by chloride-catalyzed proton transfer polymerization from AB(n) and A(2)+B-3 monomers publication-title: JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY contributor: fullname: Emrick, T – volume: 147 start-page: 24 year: 1992 ident: WOS:A1992JW92000005 article-title: POLYSILOXANE FORMATION FROM A TETRAETHOXYSILANE ETHYL-ALCOHOL OXALIC-ACID SYSTEM publication-title: JOURNAL OF NON-CRYSTALLINE SOLIDS contributor: fullname: SUGAHARA, Y |
SSID | ssj0008097 |
Score | 4.009604 |
Snippet | We have synthesized polyethoxysiloxanes starting from the AB(3)-type monomers triethoxysilanol and acetoxytriethoxysilane. The polymers are liquid and soluble... |
Source | Web of Science |
SourceID | webofscience |
SourceType | Index Database Enrichment Source |
StartPage | 1014 |
SubjectTerms | Physical Sciences Polymer Science Science & Technology |
Title | Hyperbranched polyalkoxysiloxanes via AB(3)-type monomers |
URI | http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000182968600011 |
Volume | 204 |
WOS | 000182968600011 |
WOSCitedRecordID | wos000182968600011 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1Na8JAEF2sPbSX0k9qv8jBQ0tImw-TuEe1LVKwh2LFm8wmKy1qIhLF-us7u0lMIh5sL0FC2BDf8PZlMvOGkKrBGdWp6WtDsC2tBp6rgTvkmo3ywvGZz2xpu9h5d9qftbe-3S-V5vnukog9equtfSX_QRXPIa6iS_YPyK4XxRP4G_HFIyKMx50wbuNL5IyJ0RhfqBun4fgHxqNwif_8OFwCkpi6-Aa10UQVKRKqmsy3TkQbQ1L3nsrSDsiyvGRSruqlU-BiGwEJZVZqCCLvHxQyqQjSLFxIXs0oHFYwChdSnPZ6GbArGEJycVJdkCYd4hI_t0htOdYULQGGFVvRPvKESU1DE32_eao141HDSUy5OeIUI4NzmzCu6Gwl-NgwdgKe9Bq1qNhts60s_Xy_scOt6w6Foq2b1Kk7UgvvkX3TpbaoBH3-yFzH6no8kyd9qtTrUzefijfeKlakMOkek6PkjUJpxOFxQko8OCUHrRTCM0ILYaJsCRMFw0RpNO-tBxkiShoi50R9fem22lr-_oNpbFAy2HhM64KUgzDgl0TxHJtanLm-7tVrzBpS3WM-cAMM2wfgdoVUd1mxQoxdLmslNvPCXiG62m3pa3KYBdwNKUezOb9F3RexO4nSL-bSW5E |
link.rule.ids | 315,786,790,27955,27956 |
linkProvider | Wiley-Blackwell |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Hyperbranched+polyalkoxysiloxanes+via+AB%283%29-type+monomers&rft.jtitle=Macromolecular+chemistry+and+physics&rft.au=Jaumann%2C+M&rft.au=Rebrov%2C+EA&rft.au=Kazakova%2C+VV&rft.au=Muzafarov%2C+AM&rft.date=2003-05-07&rft.pub=Wiley&rft.issn=1022-1352&rft.eissn=1521-3935&rft.volume=204&rft.issue=7&rft.spage=1014&rft.epage=1026&rft_id=info:doi/10.1002%2Fmacp.200390067&rft.externalDBID=n%2Fa&rft.externalDocID=000182968600011 |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1022-1352&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1022-1352&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1022-1352&client=summon |