Synthesis and late transition metal complexes of the heterofunctional phosphane o-Ph2PNHC6H4P(S)Ph-2

• Published in: European journal of inorganic chemistry no. 9; pp. 2408 - 2418
• Main Authors: Aucott, SM, Slawin, AMZ, Woollins, JD
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 01.09.2002
• Subjects: Chemistry; Chemistry, Inorganic & Nuclear; Physical Sciences; Science & Technology; COORDINATION CHEMISTRY; PLATINUM(II) COMPLEXES; MOLECULAR-STRUCTURE; chelate complexes; NUCLEAR-MAGNETIC-RESONANCE; phosphorus-sulfur ligands; ORGANOMETALLIC COMPLEXES; TRIDENTATE LIGAND; monodentate complexes; BONDING PROPERTIES; SULFUR; PALLADIUM(II)

The difunctional ligand o-Ph2PNHC6H4P(S)Ph-2 (PS) has been prepared by treatment of the lithium amide salt of 2-(diphenylthiophosphanyl) aniline {2-[Ph2P(S)]C6H4NH2} with Ph2PCl. The new ligand was oxidised to give the mixed chalcogen species Ph2P(E)NHC6H4P(S)Ph-2, by treatment with H2O2 (where E =...