Cycloaddition reactions of the titanium imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)(2)}(py)] with (BuCP)-C-t and MeCN

The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2-C5H4N)(CH2-NSiMe3)(2)] undergoes a [2+2] cycloaddition reaction with (BuCP)-C-t to form the mononuclear product [Ti{N(Bu-t)PC(Bu-t)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti-2{mu-et...

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Published inOrganometallics Vol. 19; no. 16; pp. 3205 - 3210
Main Authors Pugh, SM, Trosch, DJM, Wilson, DJ, Bashall, A, Cloke, FGN, Gade, LH, Hitchcock, PB, McPartlin, M, Nixon, JF, Mountford, P
Format Journal Article
LanguageEnglish
Published WASHINGTON Amer Chemical Soc 07.08.2000
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
ARYLOXIDE
COORDINATION CHEMISTRY
ACTIVATION
MONONUCLEAR
LIGANDS
NITRILES
MOLECULAR-STRUCTURES
COMPLEXES
REACTIVITY
ALKYNES
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Abstract The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2-C5H4N)(CH2-NSiMe3)(2)] undergoes a [2+2] cycloaddition reaction with (BuCP)-C-t to form the mononuclear product [Ti{N(Bu-t)PC(Bu-t)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti-2{mu-eta(2)-NC(Me)NBut}(2)(L)(2)] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4).
AbstractList The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2-C5H4N)(CH2-NSiMe3)(2)] undergoes a [2+2] cycloaddition reaction with (BuCP)-C-t to form the mononuclear product [Ti{N(Bu-t)PC(Bu-t)}(L)] (2). In contrast, reaction of 1 with MeCN affords the binuclear derivative [Ti-2{mu-eta(2)-NC(Me)NBut}(2)(L)(2)] (3), which contains a doubly deprotonated N-tert-butylacetamidinate ligand. Compound 3 undergoes a quantitative cycloreversion reaction at elevated temperatures yielding MeCN and [Ti(NBut)(L)] (4).
Author Cloke, FGN
Nixon, JF
Trosch, DJM
Gade, LH
Bashall, A
Hitchcock, PB
Mountford, P
Pugh, SM
Wilson, DJ
McPartlin, M
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Issue 16
Keywords ARYLOXIDE
COORDINATION CHEMISTRY
ACTIVATION
MONONUCLEAR
LIGANDS
NITRILES
MOLECULAR-STRUCTURES
COMPLEXES
REACTIVITY
ALKYNES
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References NIXON JF (WOS:000088605400035.31) 1995
EDELMANN, FT (WOS:A1994PW81800012) 1994; 137
Collier, PE (WOS:A1997XW83900011) 1997
Tabellion, F (WOS:000074426500010) 1998; 37
WALSH, PJ (WOS:A1993LX17200049) 1993; 12
ALLEN FH (WOS:000088605400035.2) 1993; 8
LEE, SY (WOS:A1995QU56000002) 1995; 51
Collier, PE (WOS:000086867000026) 2000; 39
Gade, LH (WOS:000084993100001) 2000
BLAKE AJ (WOS:000088605400035.9) 1997
BINGER P (WOS:000088605400035.8) 1988; 27
Blake, AJ (WOS:000078696700017) 1999
Friedrich, S (WOS:A1997YJ81200006) 1997; 130
BECKER G (WOS:000088605400035.6) 1990; 27
BARKER, J (WOS:A1994NY51600009) 1994; 133
Bennett, JL (WOS:A1997YE66100017) 1997; 119
Polse, JL (WOS:000077874300017) 1998; 120
Clancy, GP (WOS:000082733200010) 1999
NIXON, JF (WOS:A1988R052900016) 1988; 88
DILLON KB (WOS:000088605400035.17) 1998
WALSH, PJ (WOS:A1992HF63900026) 1992; 114
WIGLEY, DE (WOS:A1994BC32J00004) 1994; 42
REGITZ M (WOS:000088605400035.34) 1990
ALLEN FH (WOS:000088605400035.3) 1993; 8
Bashall, A (WOS:000077430700002) 1998
Stewart, PJ (WOS:000075154600027) 1998; 17
Michelin, RA (WOS:A1996UA17600008) 1996; 147
DOXSEE, KM (WOS:A1991GP03700042) 1991; 113
Zuckerman, RL (WOS:000085294700001) 2000; 122
Mountford, P (WOS:A1997YG75800001) 1997
Love, JB (WOS:000081765000010) 1999; 121
PUGH SM (WOS:000088605400035.33) 1999
CARNEY, MJ (WOS:A1992HE29800040) 1992; 11
Fletcher, DA (WOS:A1996VA56800019) 1996; 36
Gade, LH (WOS:000085534800015) 2000; 6
SIEM AN INSTR INC (WOS:000088605400035.1) 1994
Stewart, PJ (WOS:A1997XR23800010) 1997; 36
LEE SY (WOS:000088605400035.24) 1995; 117
Stewart, PJ (WOS:A1997WW12800038) 1997; 36
Clentsmith, GKB (WOS:000083719800035) 1999; 121
MCGRANE, PL (WOS:A1993ML59000053) 1993; 115
Cloke, FGN (WOS:000079636100046) 1999
SHELDRICK GM (WOS:000088605400035.35) 1997
References_xml – start-page: 3345
  year: 1999
  ident: WOS:000082733200010
  article-title: Vanadium(III) complexes incorporating the silylamino(disilylamido) ligand [(Me3Si)N{CH2CH2N(SiMe3)}(2)](2-) [N{N ''}(2)](2-). Synthesis and crystal structure of the dimeric, non-metallocene vanadium(III) hydride [{V(N{N ''}(2))}(2)(mu-H)(2)]
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
  contributor:
    fullname: Clancy, GP
– volume: 37
  start-page: 1233
  year: 1998
  ident: WOS:000074426500010
  article-title: Novel reactions of phosphaalkynes in the coordination sphere of tert-butylimido-vanadium(v) complexes: A simple synthesis of 3-aza-1,2,4,6-tetraphosphaquadricyclanes and 1,3,5-triphosphabenzenes
  publication-title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  contributor:
    fullname: Tabellion, F
– year: 1998
  ident: WOS:000088605400035.17
  publication-title: PHOSPHORUS CARBON CO
  contributor:
    fullname: DILLON KB
– start-page: 173
  year: 2000
  ident: WOS:000084993100001
  article-title: Taming early transition metals: the use of polydentate amido-donor ligands to create well defined reactive sites in reagents and catalysts
  publication-title: CHEMICAL COMMUNICATIONS
  contributor:
    fullname: Gade, LH
– volume: 113
  start-page: 8889
  year: 1991
  ident: WOS:A1991GP03700042
  article-title: SYNTHESIS AND FORMAL [4+2]-CYCLOADDITION REACTIONS OF VINYLIMIDO COMPLEXES OF TITANOCENE
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: DOXSEE, KM
– start-page: 2127
  year: 1997
  ident: WOS:A1997YG75800001
  article-title: New titanium imido chemistry
  publication-title: CHEMICAL COMMUNICATIONS
  contributor:
    fullname: Mountford, P
– volume: 12
  start-page: 3705
  year: 1993
  ident: WOS:A1993LX17200049
  article-title: MONOMERIC AND DIMERIC ZIRCONOCENE IMIDO COMPOUNDS - SYNTHESIS, STRUCTURE, AND REACTIVITY
  publication-title: ORGANOMETALLICS
  contributor:
    fullname: WALSH, PJ
– volume: 88
  start-page: 1327
  year: 1988
  ident: WOS:A1988R052900016
  article-title: THE COORDINATION CHEMISTRY OF COMPOUNDS CONTAINING PHOSPHORUS CARBON MULTIPLE BONDS
  publication-title: CHEMICAL REVIEWS
  contributor:
    fullname: NIXON, JF
– volume: 6
  start-page: 692
  year: 2000
  ident: WOS:000085534800015
  article-title: Cooperative reactivity of early-late heterodinuclear transition metal complexes with polar organic substrates
  publication-title: CHEMISTRY-A EUROPEAN JOURNAL
  contributor:
    fullname: Gade, LH
– start-page: 1555
  year: 1997
  ident: WOS:000088605400035.9
  publication-title: J CHEM SOC CHEM COMM
  contributor:
    fullname: BLAKE AJ
– volume: 39
  start-page: 2001
  year: 2000
  ident: WOS:000086867000026
  article-title: Titanium and niobium imido complexes derived from diamidoamine ligands
  publication-title: INORGANIC CHEMISTRY
  contributor:
    fullname: Collier, PE
– volume: 120
  start-page: 13405
  year: 1998
  ident: WOS:000077874300017
  article-title: Reactivity of a terminal Ti(IV) imido complex toward alkenes and alkynes: Cycloaddition vs C-H activation
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: Polse, JL
– volume: 119
  start-page: 10696
  year: 1997
  ident: WOS:A1997YE66100017
  article-title: Selectivities in hydrocarbon activation: Kinetic and thermodynamic investigations of reversible 1,2-RH-elimination from (silox)(2)((Bu3SiNH)-Bu-t)TiR (silox = (Bu3SiO)-Bu-t)
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: Bennett, JL
– start-page: 2911
  year: 1997
  ident: WOS:A1997XW83900011
  article-title: Mono- and bi-nuclear titanium imido complexes supported by aryloxide ligands: fine control by ortho substituents
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
  contributor:
    fullname: Collier, PE
– volume: 8
  start-page: 31
  year: 1993
  ident: WOS:000088605400035.3
  publication-title: CHEM DESIGN AUTOMATI
  contributor:
    fullname: ALLEN FH
– volume: 36
  start-page: 3616
  year: 1997
  ident: WOS:A1997XR23800010
  article-title: Titanium imido complexes supported by amidinate ligands: Synthesis, solution dynamics, and solid state structures
  publication-title: INORGANIC CHEMISTRY
  contributor:
    fullname: Stewart, PJ
– start-page: 2555
  year: 1998
  ident: WOS:000077430700002
  article-title: C-H bond activation and C-N coupling reactions of methylacetylenes and allenes with an imidotitanium complex
  publication-title: CHEMICAL COMMUNICATIONS
  contributor:
    fullname: Bashall, A
– volume: 130
  start-page: 1751
  year: 1997
  ident: WOS:A1997YJ81200006
  article-title: Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand
  publication-title: CHEMISCHE BERICHTE-RECUEIL
  contributor:
    fullname: Friedrich, S
– start-page: 379
  year: 1999
  ident: WOS:000078696700017
  article-title: Cycloaddition reactions of titanium and zirconium imido, oxo and hydrazido complexes supported by tetraaza macrocyclic ligands
  publication-title: JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
  contributor:
    fullname: Blake, AJ
– volume: 122
  start-page: 751
  year: 2000
  ident: WOS:000085294700001
  article-title: Zirconium-mediated metathesis of imines: A study of the scope, longevity, and mechanism of a complicated catalytic system
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: Zuckerman, RL
– volume: 117
  start-page: 5877
  year: 1995
  ident: WOS:000088605400035.24
  publication-title: J AM CHEM SOC
  contributor:
    fullname: LEE SY
– start-page: 319
  year: 1995
  ident: WOS:000088605400035.31
  publication-title: CHEM SOC REV
  contributor:
    fullname: NIXON JF
– volume: 27
  start-page: 249
  year: 1990
  ident: WOS:000088605400035.6
  publication-title: INORG SYNTH
  contributor:
    fullname: BECKER G
– volume: 36
  start-page: 1982
  year: 1997
  ident: WOS:A1997WW12800038
  article-title: Mononuclear niobium imido and oxo complexes supported by N,N'-bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [Nb(NBut){PhC(NSiMe3)(2)}Cl-2(py)] and [Nb(O){(4-C6H4Me)C(NSiMe3)(2)}(2)Cl]
  publication-title: INORGANIC CHEMISTRY
  contributor:
    fullname: Stewart, PJ
– volume: 137
  start-page: 403
  year: 1994
  ident: WOS:A1994PW81800012
  article-title: N-SILYLATED BENZAMIDINES - VERSATILE BUILDING-BLOCKS IN MAIN-GROUP AND COORDINATION CHEMISTRY
  publication-title: COORDINATION CHEMISTRY REVIEWS
  contributor:
    fullname: EDELMANN, FT
– volume: 42
  start-page: 239
  year: 1994
  ident: WOS:A1994BC32J00004
  article-title: ORGANOIMIDO COMPLEXES OF THE TRANSITION-METALS
  publication-title: PROGRESS IN INORGANIC CHEMISTRY, VOL 42
  contributor:
    fullname: WIGLEY, DE
– volume: 27
  start-page: 1541
  year: 1988
  ident: WOS:000088605400035.8
  publication-title: ANGEW CHEM INT EDIT
  contributor:
    fullname: BINGER P
– volume: 36
  start-page: 746
  year: 1996
  ident: WOS:A1996VA56800019
  article-title: The United Kingdom Chemical Database Service
  publication-title: JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES
  contributor:
    fullname: Fletcher, DA
– volume: 121
  start-page: 10444
  year: 1999
  ident: WOS:000083719800035
  article-title: Reductive cleavage of dinitrogen by a vanadium diamidoamine complex: The molecular structures of [V(Me3SiN{CH2CH2NSiMe3}(2))(mu-N)](2) and K[V(Me3SiN{ CH2CH2NSiMe3}(2))(mu-N)](2)
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: Clentsmith, GKB
– year: 1999
  ident: WOS:000088605400035.33
  publication-title: THESIS U OXFORD
  contributor:
    fullname: PUGH SM
– volume: 121
  start-page: 6843
  year: 1999
  ident: WOS:000081765000010
  article-title: A non-metallocene hydride of titanium(III)
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: Love, JB
– volume: 133
  start-page: 219
  year: 1994
  ident: WOS:A1994NY51600009
  article-title: THE COORDINATION CHEMISTRY OF THE AMIDINE LIGAND
  publication-title: COORDINATION CHEMISTRY REVIEWS
  contributor:
    fullname: BARKER, J
– year: 1990
  ident: WOS:000088605400035.34
  publication-title: MULTIPLE BONDS LOW C
  contributor:
    fullname: REGITZ M
– year: 1997
  ident: WOS:000088605400035.35
  publication-title: SHELXL97 PROGRAM CRY
  contributor:
    fullname: SHELDRICK GM
– volume: 8
  start-page: 1
  year: 1993
  ident: WOS:000088605400035.2
  publication-title: CHEM DESIGN AUTOMATI
  contributor:
    fullname: ALLEN FH
– volume: 147
  start-page: 299
  year: 1996
  ident: WOS:A1996UA17600008
  article-title: Reactions of transition metal-coordinated nitriles
  publication-title: COORDINATION CHEMISTRY REVIEWS
  contributor:
    fullname: Michelin, RA
– year: 1994
  ident: WOS:000088605400035.1
  publication-title: SHELXTL PC VERS 5 03
  contributor:
    fullname: SIEM AN INSTR INC
– volume: 51
  start-page: 4255
  year: 1995
  ident: WOS:A1995QU56000002
  article-title: MECHANISM AND REGIOCHEMISTRY OF AZAMETALLACYCLOBUTENE FORMATION FROM IMIDOZIRCONOCENE COMPLEXES AND ALKYNES
  publication-title: TETRAHEDRON
  contributor:
    fullname: LEE, SY
– start-page: 661
  year: 1999
  ident: WOS:000079636100046
  article-title: One- and two-step [2+2] cycloaddition reactions of group 4 imides with the phosphaalkyne (BuCP)-C-t. Crystal and molecular structures of [Zr(eta(5)-C5H5)(2)((PCBuNC6H3Me2)-N-t-2,6)] and [TiCl2((P2C2Bu2NBut)-N-t)(py)] (py)=pyridine
  publication-title: CHEMICAL COMMUNICATIONS
  contributor:
    fullname: Cloke, FGN
– volume: 114
  start-page: 1708
  year: 1992
  ident: WOS:A1992HF63900026
  article-title: STOICHIOMETRIC AND CATALYTIC HYDROAMINATION OF ALKYNES AND ALLENE BY ZIRCONIUM BISAMIDES CP2ZR(NHR)2
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: WALSH, PJ
– volume: 115
  start-page: 11485
  year: 1993
  ident: WOS:A1993ML59000053
  article-title: SYNTHETIC APPLICATIONS OF IMIDOTITANIUM ALKYNE [2+2] CYCLOADDITIONS - A CONCISE, STEREOCONTROLLED TOTAL SYNTHESIS OF THE ANTIFUNGAL AGENT (+)-PREUSSIN
  publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
  contributor:
    fullname: MCGRANE, PL
– volume: 17
  start-page: 3271
  year: 1998
  ident: WOS:000075154600027
  article-title: New titanium complexes containing an amidinate-imide supporting ligand set: Cyclopentadienyl, alkyl, borohydride, aryloxide, and amide derivatives
  publication-title: ORGANOMETALLICS
  contributor:
    fullname: Stewart, PJ
– volume: 11
  start-page: 761
  year: 1992
  ident: WOS:A1992HE29800040
  article-title: GENERATION OF THE HIGHLY REACTIVE INTERMEDIATES CP-STAR-2ZR=0 AND CP-STAR-2ZR=S - TRAPPING REACTIONS WITH ALKYNES, NITRILES, AND DATIVE LIGANDS
  publication-title: ORGANOMETALLICS
  contributor:
    fullname: CARNEY, MJ
SSID ssj0006732
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Snippet The diamidopyridine-supported titanium imide [Ti(NBut)(L)(py)] [1, L = MeC(2-C5H4N)(CH2-NSiMe3)(2)] undergoes a [2+2] cycloaddition reaction with (BuCP)-C-t to...
Source Web of Science
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SourceType Index Database
Enrichment Source
StartPage 3205
SubjectTerms Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
Title Cycloaddition reactions of the titanium imide [Ti(NBut){MeC(2-C5H4N)(CH2NSiMe3)(2)}(py)] with (BuCP)-C-t and MeCN
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Volume 19
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