Coordination Structure of Aluminum in Magnesium Aluminum Hydroxide Studied by 27Al NMR
O6; The coordination structure of aluminum in magnesium aluminum hydroxide was studiedby 27Al NMR. The result showed that tetrahedral aluminum (AlⅣ) existed in magnesiumaluminum hydroxide, and the contents of AlⅣ increased with the increase of the ratio of Al/Mg andwith the peptizing temperature. Al...
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| Published in | 中国化学快报(英文版) Vol. 14; no. 6; pp. 605 - 608 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Key Lab of Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100
2003
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| Subjects | |
| Online Access | Get full text |
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| Abstract | O6; The coordination structure of aluminum in magnesium aluminum hydroxide was studiedby 27Al NMR. The result showed that tetrahedral aluminum (AlⅣ) existed in magnesiumaluminum hydroxide, and the contents of AlⅣ increased with the increase of the ratio of Al/Mg andwith the peptizing temperature. AlⅣ originated from the so-called Al13 polymer with the structureof one Al tetrahedron surrounded by twelve Al octahedrons. |
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| AbstractList | O6; The coordination structure of aluminum in magnesium aluminum hydroxide was studiedby 27Al NMR. The result showed that tetrahedral aluminum (AlⅣ) existed in magnesiumaluminum hydroxide, and the contents of AlⅣ increased with the increase of the ratio of Al/Mg andwith the peptizing temperature. AlⅣ originated from the so-called Al13 polymer with the structureof one Al tetrahedron surrounded by twelve Al octahedrons. |
| Author | Jun XU Wan Guo HOU Wen Xiu DANG Shu Hua HAN |
| AuthorAffiliation | Key Lab of Colloid and Interface Chemistry of State Education Ministry, Shandong University, Jinan, 250100 |
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| Keywords | Coordination structure magnesium aluminum hydroxide 27Al NMR |
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| Title | Coordination Structure of Aluminum in Magnesium Aluminum Hydroxide Studied by 27Al NMR |
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