Anti-fouling ultrafiltration membrane prepared from polysulfone-graft-methyl acrylate copolymers by UV-induced grafting method
X1; Membrane fouling is one of the most important challenges faced in membrane ultrafiltration operations. The copolymers of polysulfone-graft-methyl acrylate were synthesized by homogeneous photo-initiated graft copolymerization. The variables affecting the degree of grafting, such as the time of U...
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Published in | 环境科学学报(英文版) Vol. 20; no. 5; pp. 565 - 570 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
Published |
Department of Environment and Chemistry Engineering, Nanchang Hangkong University, Nanchang 330034, China%Department of Environment and Chemistry Engineering, Nanchang Hangkong University, Nanchang 330034, China%Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China%The Greatwall Pharmaceutical Factory of Beijing, Beijing 100071, China
2008
Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China |
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Abstract | X1; Membrane fouling is one of the most important challenges faced in membrane ultrafiltration operations. The copolymers of polysulfone-graft-methyl acrylate were synthesized by homogeneous photo-initiated graft copolymerization. The variables affecting the degree of grafting, such as the time of UV(Ultraviolet-visible)irradiation and the concentrations of the methyl acrylate and photoinitiator, were investigated. The graft copolymer membranes were prepared by the phase inversion method. The chemical and morphological changes were characterized by attenuated total reflection-Fourier transform infrared spectroscopy(ATR/FT-IR), scanning electron microscopy, and water contact angles measurements. Results revealed that methyl acrylate groups were present on the membranes and the graft degree of methyl acrylate had remarkable effect on the performance of membranes. Pure water contact allgle on the membrane surface decreases with the increase of methyl acrylate graftdegree. which indicated that the hydrophilicity of graft copolymer membranes Was improved. The permeation fluxes of pure water and bovine serum albumin solution were measured to evaluate the antifouling property of graft copolymer membranes, the results of which have shown an enhancement of antifouling property for graft copoly mermembranes. |
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AbstractList | X1; Membrane fouling is one of the most important challenges faced in membrane ultrafiltration operations. The copolymers of polysulfone-graft-methyl acrylate were synthesized by homogeneous photo-initiated graft copolymerization. The variables affecting the degree of grafting, such as the time of UV(Ultraviolet-visible)irradiation and the concentrations of the methyl acrylate and photoinitiator, were investigated. The graft copolymer membranes were prepared by the phase inversion method. The chemical and morphological changes were characterized by attenuated total reflection-Fourier transform infrared spectroscopy(ATR/FT-IR), scanning electron microscopy, and water contact angles measurements. Results revealed that methyl acrylate groups were present on the membranes and the graft degree of methyl acrylate had remarkable effect on the performance of membranes. Pure water contact allgle on the membrane surface decreases with the increase of methyl acrylate graftdegree. which indicated that the hydrophilicity of graft copolymer membranes Was improved. The permeation fluxes of pure water and bovine serum albumin solution were measured to evaluate the antifouling property of graft copolymer membranes, the results of which have shown an enhancement of antifouling property for graft copoly mermembranes. |
Author | HUA Helin ZHONG Hui LI Na YUAN Zonghuan WU Linlin WU Guangxia LIN Xiangwei TANG Lianyi |
AuthorAffiliation | Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China;Department of Environment and Chemistry Engineering, Nanchang Hangkong University, Nanchang 330034, China%Department of Environment and Chemistry Engineering, Nanchang Hangkong University, Nanchang 330034, China%Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China%The Greatwall Pharmaceutical Factory of Beijing, Beijing 100071, China |
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Title | Anti-fouling ultrafiltration membrane prepared from polysulfone-graft-methyl acrylate copolymers by UV-induced grafting method |
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