Amphiphilic block copolymer-toughened epoxy resins and electrical laminates made therefrom

A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure pro...

Full description

Saved in:
Bibliographic Details
Main Authors Verghese, Kandathil E, Hearn, Robert L
Format Patent
LanguageEnglish
Published 12.04.2011
Online AccessGet full text

Cover

Loading…
Abstract A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure provided that the polyether structure of said immiscible block segment contains at least one or more alkylene oxide monomer units having at least four carbon atoms; such that when the epoxy resin composition is cured, the toughness of the resulting cured epoxy resin composition is increased; (c) a curing agent; and (d) a curing catalyst. The amphiphilic block copolymer is preferably an all polyether block copolymer such as a PEO-PBO diblock copolymer or a PEO-PBO-PEO triblock copolymer.
AbstractList A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure provided that the polyether structure of said immiscible block segment contains at least one or more alkylene oxide monomer units having at least four carbon atoms; such that when the epoxy resin composition is cured, the toughness of the resulting cured epoxy resin composition is increased; (c) a curing agent; and (d) a curing catalyst. The amphiphilic block copolymer is preferably an all polyether block copolymer such as a PEO-PBO diblock copolymer or a PEO-PBO-PEO triblock copolymer.
Author Verghese, Kandathil E
Hearn, Robert L
Author_xml – sequence: 1
  givenname: Kandathil E
  surname: Verghese
  fullname: Verghese, Kandathil E
– sequence: 2
  givenname: Robert L
  surname: Hearn
  fullname: Hearn, Robert L
BookMark eNqNiksKwjAQQLPQhb87zAUKxSyKSxHFA7hyI2M6bYOTmZCkYG9vBQ8gPHjweGuzEBVamfsxxMHPsHfwZHUvcBqVp0CpKjr2Awm1QFHfEyTKXjKgzIHJleQdMjAGL1goQ8CWoAyUqEsatmbZIWfa_bwxcDnfTtdqzHHepeRHn_Crujnsbd1Y-8fyAYWaPn0
ContentType Patent
DBID EFH
DatabaseName USPTO Issued Patents
DatabaseTitleList
Database_xml – sequence: 1
  dbid: EFH
  name: USPTO Issued Patents
  url: http://www.uspto.gov/patft/index.html
  sourceTypes: Open Access Repository
DeliveryMethod fulltext_linktorsrc
ExternalDocumentID 07923073
GroupedDBID EFH
ID FETCH-uspatents_grants_079230733
IEDL.DBID EFH
IngestDate Sun Mar 05 22:30:52 EST 2023
IsOpenAccess true
IsPeerReviewed false
IsScholarly false
Language English
LinkModel DirectLink
MergedId FETCHMERGED-uspatents_grants_079230733
OpenAccessLink https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7923073
ParticipantIDs uspatents_grants_07923073
PatentNumber 7923073
PublicationCentury 2000
PublicationDate 20110412
PublicationDateYYYYMMDD 2011-04-12
PublicationDate_xml – month: 04
  year: 2011
  text: 20110412
  day: 12
PublicationDecade 2010
PublicationYear 2011
References Gan et al. (6613839) 20030900
Journal of Polymer Science, Part B: Polymer Phusics, 2001, 39 (23), 2996-3010.
Macromolecules, 2000, 33 (26), 9522-9534.
Rosenkranz et al. (4014771) 19770300
(H9-324110) 19971200
Macromolecules, 2002, 35, 3133-3144.
Macromolecules 2000, 33, 5235-5244.
Najvar (3892819) 19750700
Radlove et al. (3804735) 19740400
Hoyles et al. (6710139) 20040300
Journal of The American Chemical Society, 1997, 119(11), 2749-2750.
Lee and Neville, Handbook of Epoxy Resins, Chapter 2, McGraw Hill, N.Y., 1967.
Journal of Applied Polymer Science, 1994, 54, 815.
Wu (3662030) 19720500
Elrick et al. (3948698) 19760400
Harris et al. (4431782) 19840200
Whitmarsh, R.H., In Nonionic Surfactants Polyoxylalkylene Block Copolymers; Nace, V.M., Ed.; Surfactant Science Series; vol. 60; Marcel Dekker, N.Y., 1996, Chapter 1.
Dean et al. (2004/0247881) 20041200
Allen et al. (4119609) 19781000
References_xml – year: 20040300
  ident: 6710139
  contributor:
    fullname: Hoyles et al.
– year: 19760400
  ident: 3948698
  contributor:
    fullname: Elrick et al.
– year: 19740400
  ident: 3804735
  contributor:
    fullname: Radlove et al.
– year: 19770300
  ident: 4014771
  contributor:
    fullname: Rosenkranz et al.
– year: 20030900
  ident: 6613839
  contributor:
    fullname: Gan et al.
– year: 20041200
  ident: 2004/0247881
  contributor:
    fullname: Dean et al.
– year: 19720500
  ident: 3662030
  contributor:
    fullname: Wu
– year: 19750700
  ident: 3892819
  contributor:
    fullname: Najvar
– year: 19840200
  ident: 4431782
  contributor:
    fullname: Harris et al.
– year: 19971200
  ident: H9-324110
– year: 19781000
  ident: 4119609
  contributor:
    fullname: Allen et al.
Score 2.8011649
Snippet A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block...
SourceID uspatents
SourceType Open Access Repository
Title Amphiphilic block copolymer-toughened epoxy resins and electrical laminates made therefrom
URI https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7923073
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1LS8NAEB7aImhPior1xRy8RpMmm6THIg1BUHpQKF7KJruVoNmGZIv23zuTSPGi111YhtmdxzfMfgNwowIxll7GfTo8wswLVkx5O3ZCV0eTaEJYruXZfnwK05fgYSEWPUh3f2FKMiOnIlma201T2XXbXEnuvbt4pyN_Zo5Aw-wDn-ZjLdVcre6YB4-eax_6scutfbMkHcI-HUEpm7HNr6CRHMLevF09gp42x_A6JcUVFRcwcswohrxjzhMKtqWuHcvDcsjtKKSE-GuLBIIL0yDBfOwG1bAukW6vMJwcYimVRs7dNP8POQFMZs_3qbMTZPlWc4PL0v0R2D-FAQF9fQZImvEiKQg2xjIIfR1rX0lBFij8nMKuHMHoz2PO_9m7gIOuEsoMhZcwsPVGX1Eotdl1q6dvDLaAMQ
link.rule.ids 230,309,783,805,888,64375
linkProvider USPTO
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1LT8MwDLbGQDxOIEBsvHzgWljX13ZEsKq8ph5AmrhUaZOhajSr2k5s_x67RRMXuCaSZdlJ7C9xPgNcSdvpCzPmOh1uYWbaU6a87RtuT3lDb0hYrubZfhm7wZv9OHEmLQjWf2Ey2kZGTrqU14syr-Z1cSUd743jjYb8mTkCNbMPfOnPuZChnN4wDx4t1w3Y5KcoLu4b-cEe7JAQStp0Vf4KG_4-bIX16AG0lD6E91syXZrzFUaCMUWRGSbco2CVqcKouF0OHTwSKSVerpBgcKpLJKCPTasatiaS_1LN6SFmQirk7E3xD5EjQH_0ehcYa0Wij4JLXKLej8rWMbQJ6qsTQLKN6QmHgONA2K6lBsqSwqE96FgJBV7Rgc6fYrr_zF3CdnjvR88P46dT2G2uRZmu8AzaVbFQ5xRXq_iiNtk3fKODLQ
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&rft.title=Amphiphilic+block+copolymer-toughened+epoxy+resins+and+electrical+laminates+made+therefrom&rft.inventor=Verghese%2C+Kandathil+E&rft.inventor=Hearn%2C+Robert+L&rft.number=7923073&rft.date=2011-04-12&rft.externalDBID=n%2Fa&rft.externalDocID=07923073