Amphiphilic block copolymer-toughened epoxy resins and electrical laminates made therefrom
A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure pro...
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Format | Patent |
Language | English |
Published |
12.04.2011
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Online Access | Get full text |
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Abstract | A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure provided that the polyether structure of said immiscible block segment contains at least one or more alkylene oxide monomer units having at least four carbon atoms; such that when the epoxy resin composition is cured, the toughness of the resulting cured epoxy resin composition is increased; (c) a curing agent; and (d) a curing catalyst. The amphiphilic block copolymer is preferably an all polyether block copolymer such as a PEO-PBO diblock copolymer or a PEO-PBO-PEO triblock copolymer. |
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AbstractList | A curable laminate epoxy composition comprising (a) an epoxy resin; (b) an amphiphilic block copolymer containing at least one epoxy resin miscible block segment and at least one epoxy resin immiscible block segment; wherein the immiscible block segment comprises at least one polyether structure provided that the polyether structure of said immiscible block segment contains at least one or more alkylene oxide monomer units having at least four carbon atoms; such that when the epoxy resin composition is cured, the toughness of the resulting cured epoxy resin composition is increased; (c) a curing agent; and (d) a curing catalyst. The amphiphilic block copolymer is preferably an all polyether block copolymer such as a PEO-PBO diblock copolymer or a PEO-PBO-PEO triblock copolymer. |
Author | Verghese, Kandathil E Hearn, Robert L |
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References | Gan et al. (6613839) 20030900 Journal of Polymer Science, Part B: Polymer Phusics, 2001, 39 (23), 2996-3010. Macromolecules, 2000, 33 (26), 9522-9534. Rosenkranz et al. (4014771) 19770300 (H9-324110) 19971200 Macromolecules, 2002, 35, 3133-3144. Macromolecules 2000, 33, 5235-5244. Najvar (3892819) 19750700 Radlove et al. (3804735) 19740400 Hoyles et al. (6710139) 20040300 Journal of The American Chemical Society, 1997, 119(11), 2749-2750. Lee and Neville, Handbook of Epoxy Resins, Chapter 2, McGraw Hill, N.Y., 1967. Journal of Applied Polymer Science, 1994, 54, 815. Wu (3662030) 19720500 Elrick et al. (3948698) 19760400 Harris et al. (4431782) 19840200 Whitmarsh, R.H., In Nonionic Surfactants Polyoxylalkylene Block Copolymers; Nace, V.M., Ed.; Surfactant Science Series; vol. 60; Marcel Dekker, N.Y., 1996, Chapter 1. Dean et al. (2004/0247881) 20041200 Allen et al. (4119609) 19781000 |
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Title | Amphiphilic block copolymer-toughened epoxy resins and electrical laminates made therefrom |
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