Toluene methylation process with increased methanol selectivity
A method of converting methanol to a xylene product is achieved by providing a reactor containing a non-steamed, phosphorus-treated ZSM-5-type zeolite catalyst. The catalyst is contacted with a toluene/methanol feed under reactor conditions suitable for the methylation of toluene. Water cofeed is in...
Saved in:
Main Authors | , , |
---|---|
Format | Patent |
Language | English |
Published |
09.10.2007
|
Online Access | Get full text |
Cover
Loading…
Abstract | A method of converting methanol to a xylene product is achieved by providing a reactor containing a non-steamed, phosphorus-treated ZSM-5-type zeolite catalyst. The catalyst is contacted with a toluene/methanol feed under reactor conditions suitable for the methylation of toluene. Water cofeed is introduced into the reactor during the methylation reaction under conditions that provide substantially no structural aluminum loss of the catalyst from such introduction of water to provide a selectivity for methanol of at least 40%. |
---|---|
AbstractList | A method of converting methanol to a xylene product is achieved by providing a reactor containing a non-steamed, phosphorus-treated ZSM-5-type zeolite catalyst. The catalyst is contacted with a toluene/methanol feed under reactor conditions suitable for the methylation of toluene. Water cofeed is introduced into the reactor during the methylation reaction under conditions that provide substantially no structural aluminum loss of the catalyst from such introduction of water to provide a selectivity for methanol of at least 40%. |
Author | Kulkarni, Neeta Harvey, Pamela Ghosh, Ashim Kumar |
Author_xml | – sequence: 1 givenname: Ashim Kumar surname: Ghosh fullname: Ghosh, Ashim Kumar – sequence: 2 givenname: Neeta surname: Kulkarni fullname: Kulkarni, Neeta – sequence: 3 givenname: Pamela surname: Harvey fullname: Harvey, Pamela |
BookMark | eNrjYmDJy89L5WSwD8nPKU3NS1XITS3JqMxJLMnMz1MoKMpPTi0uVijPLMlQyMxLLkpNLE5NAStJzMvPUShOzUlNLsksyyyp5GFgTUvMKU7lhdLcDApuriHOHrqlxQWJJal5JcXx6UWJIMrA3Mjc0szAwpgIJQDdazSg |
ContentType | Patent |
CorporateAuthor | Saudi Basic Industries Corporation |
CorporateAuthor_xml | – name: Saudi Basic Industries Corporation |
DBID | EFH |
DatabaseName | USPTO Issued Patents |
DatabaseTitleList | |
Database_xml | – sequence: 1 dbid: EFH name: USPTO Issued Patents url: http://www.uspto.gov/patft/index.html sourceTypes: Open Access Repository |
DeliveryMethod | fulltext_linktorsrc |
ExternalDocumentID | 07279608 |
GroupedDBID | EFH |
ID | FETCH-uspatents_grants_072796083 |
IEDL.DBID | EFH |
IngestDate | Sun Mar 05 22:33:57 EST 2023 |
IsOpenAccess | true |
IsPeerReviewed | false |
IsScholarly | false |
Language | English |
LinkModel | DirectLink |
MergedId | FETCHMERGED-uspatents_grants_072796083 |
OpenAccessLink | https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7279608 |
ParticipantIDs | uspatents_grants_07279608 |
PatentNumber | 7279608 |
PublicationCentury | 2000 |
PublicationDate | 20071009 |
PublicationDateYYYYMMDD | 2007-10-09 |
PublicationDate_xml | – month: 10 year: 2007 text: 20071009 day: 09 |
PublicationDecade | 2000 |
PublicationYear | 2007 |
References | Kim, J.-H., et al., Para-selectivity of Metallosilicates with MFI Zeolite Structure Zeolites, vol. 11, 1991, pp. 59-63, no month. Pellet et al. (4914067) 19900400 Faust et al. (5246688) 19930900 Kim, J.-H., et al., Preparation of Highly Para-selective Metallosilicate Catalysts for Alkylation of Ethylbenzene with Ethanol, Applied Catalysis A:100, 1993, pp. 27-36, no month. Hendriksen et al. (5430213) 19950700 Chang et al. (5498814) 19960300 He et al. (5951963) 19990900 Chen et al. (5607890) 19970300 Derouane et al. (4891197) 19900100 Chang et al. (5455213) 19951000 Butt et al. (5094995) 19920300 Brown et al. (6504072) 20030100 Cullo et al. (4721827) 19880100 Absil et al. (5348643) 19940900 Absil et al. (5833840) 19981100 Boehner et al. (6395664) 20020500 Chang et al. (5607888) 19970300 Yamamoto (6444610) 20020900 Bhat et al. (5811613) 19980900 Dessau et al. (5939597) 19990800 Chang et al. (5321183) 19940600 Crocco et al. (5646314) 19970700 Ghosh (5907073) 19990500 Brown et al. (6156949) 20001200 Wu et al. (5905051) 19990500 Hibino, T., et al., Shape-Selectivity Over HZSM-5 Modified by Chemical Vapor Deposition of Silicon Alkoxide, Journal of Catalysis 128, 1991, pp. 551-558, no month. Yao (6417421) 20020700 Gongwei et al. (5367100) 19941100 Schmitt (5689024) 19971100 Brown et al. (6506954) 20030100 Chu (4548914) 19851000 Chu et al. (4694114) 19870900 Sun (5925586) 19990700 Casci et al. (5345021) 19940900 Ban et al. (6034283) 20000300 Verduijn et al. (6504074) 20030100 Chang et al. (5563310) 19961000 Chang et al. (5571768) 19961100 Sikkenga (4891467) 19900100 Guan et al. (6342153) 20020100 Toulhoat (6799089) 20040900 Ou et al. (6388156) 20020500 Smith et al. (6160191) 20001200 Shi et al. (6211104) 20010400 Verduijn et al. (6150293) 20001100 Shamshoum et al. (5336824) 19940800 Chu (5047141) 19910900 Beck et al. (6187982) 20010200 Chao (4727209) 19880200 Brown et al. (6613951) 20030900 Sayed, M. B., et al., The Effect of Modification with Boron on the Catalytic Activity and Selectivity of HZSM-5, Journal of Catalysis 101, 1986, pp. 43-55, no month. Nirula, S.C., Para-Xylene From Toluene and Methanol, Process Economics Program, 1983, pp. 1-23, SRI International, Menlo Park, CA, no month. Chen et al. (5648580) 19970700 Young (4758328) 19880700 Chang et al. (5516736) 19960500 Gareiss et al. (6469095) 20021000 Shamshoum et al. (5387732) 19950200 Fajula et al. (5534239) 19960700 Butt et al. (5315033) 19940500 Casci et al. (5041402) 19910800 Ou et al. (6459006) 20021000 Dessau (4704495) 19871100 Olson et al. (5254770) 19931000 Absil et al. (5456821) 19951000 Yamamoto (6589901) 20030700 Casci et al. (5385718) 19950100 Mohr et al. (5994603) 19991100 Zhicheng et al. (5380690) 19950100 Beck et al. (5675047) 19971000 De Simone et al. (4670616) 19870600 Wu et al. (6090274) 20000700 Vinek, H., et al., Production and Reactions of Xylenes over H-ZSM-5, Journal of Molecular Catalysis, 64, 1991, pp. 23-39, no month. Quesada et al. (6726834) 20040400 Wang, I., et al., Para-selectivity of Diaklybenzenes over Modified HZSM-5 by Vapour Phase Deposition of Silica, Applied Catalysis, 54, 1989, 257-266, no month. Chen et al. (6060633) 20000500 Le Van Mao et al. (4847223) 19890700 Chen et al. (5902919) 19990500 Young (5248841) 19930900 Degnan et al. (5536894) 19960700 Chen et al. (6399530) 20020600 Martindale et al. (5043502) 19910800 Casci et al. (5446234) 19950800 Johnson et al. (6642426) 20031100 Butler et al. (6090991) 20000700 Cao et al. (6080303) 20000600 Chen et al. (5955641) 19990900 van den Berge et al. (6300535) 20011000 Barthomeuf et al. (5068483) 19911100 Chu (4590321) 19860500 Chen, N.Y., Reactions of Mixtures of Toluene and Methanol Over ZSM-5, Journal of Catalysis 114, 1988, pp. 17-22, no month. Butler et al. (6268305) 20010700 Chen (5573746) 19961100 Pieters et al. (4638106) 19870100 Yashima, T., et al., Selective Formation of p-Xylene by Alkylation of Toluene with Methanol on ZSM-5 Type Zeolites, Stud. Surf. Sci. Catal., 1981, 7, pp. 739-751, no month. Ghosh et al. (5847255) 19981200 Ghosh (5990031) 19991100 Ou et al. (6613708) 20030900 Monque et al. (5576256) 19961100 Chen (4716135) 19871200 Yamamoto et al. (6518213) 20030200 Yamamoto (6503862) 20030100 Das, J., et al., Ethylbenzene Dealkylation and Realkylation over Pore Size Regulated MFI Zeolite, Ind. Eng. Chem. Res., 32, 1993, pp. 2525-2529, no month. Shamshoum et al. (5227558) 19930700 Kumar (5378670) 19950100 Chen et al. (5789335) 19980800 Pellet et al. (5523510) 19960600 Koehl et al. (6100437) 20000800 Strohmaier et al. (6294493) 20010900 Yamamoto et al. (6047544) 20000400 Beck et al. (5698756) 19971200 Kowalski (5318696) 19940600 Chu (4912073) 19900300 Valyocsik et al. (4973781) 19901100 Casci et al. (5178748) 19930100 Yoshikawa (6770251) 20040800 Merrill et al. (6057485) 20000500 Fraenkel et al. (4962255) 19901000 Casci et al. (5464799) 19951100 Absil et al. (5658454) 19970800 Chitnis et al. (5110776) 19920500 Lesch et al. (6773694) 20040800 Waller (5124299) 19920600 Absil et al. (5231064) 19930700 Williams et al. (6689929) 20040200 Nimry et al. (4673767) 19870600 Yao et al. (6074975) 20000600 Drake et al. (6040257) 20000300 Chen et al. (5561095) 19961000 Sumitani et al. (4695667) 19870900 Cottrell et al. (4861930) 19890800 Casci (5108579) 19920400 Froment et al. (6548725) 20030400 Yao et al. (6124227) 20000900 Cullo et al. (4623530) 19861100 Guth et al. (5399336) 19950300 Chang et al. (5349113) 19940900 Chu (4665251) 19870500 van der Berge et al. (6812181) 20041100 Guth et al. (5371307) 19941200 Zhang et al. (6080698) 20000600 Mohr et al. (6699811) 20040300 Valyocsik (4902406) 19900200 Beck et al. (5569805) 19961000 Vogt et al. (6566293) 20030500 Shamshoum et al. (5210356) 19930500 Ho et al. (5294578) 19940300 Chen et al. (5780563) 19980700 Chang et al. (5365003) 19941100 Hatanaka et al. (6217748) 20010400 Chao et al. (4695666) 19870900 Kocal (4746763) 19880500 Harris et al. (5922922) 19990700 Rodriguez et al. (6306790) 20011000 Dwyer (5254767) 19931000 Dwyer et al. (5336478) 19940800 Brown et al. (6423879) 20020700 Kaeding, W.W., et al., Selective Alkylation of Toluene to Produce para-Xylene, Journal of Catalysis 67, 1981, pp. 159-174, no month. Ghosh (6096938) 20000800 Butt et al. (5430212) 19950700 Young (4623633) 19861100 Waller (5105047) 19920400 Absil et al. (5173461) 19921200 Kim, J.-H, et al., Generation of Shape-Selectivity of p-Xylene Formation in the Synthesized ZSM-5 Zeolites, Journal of Catalysis 173, 1998, pp. 433-439, no month. Steacy (4761513) 19880800 Ghosh et al. (6222084) 20010400 D'Amore et al. (4935574) 19900600 Weinstein (3965207) 19760600 Chang et al. (5541146) 19960700 Brown et al. (6048816) 20000400 Young, L.B., et al., Shape Selective Reactions with Zeolite Catalysts, Journal of Catalysis 76, 1982, pp. 418-432, no month. Gaffney et al. (5171921) 19921200 Hatanaka et al. (6251263) 20010600 Chang et al. (5475179) 19951200 Argauer et al. (3702886) 19721100 Nicolaides (5503818) 19960400 Mohr et al. (6811684) 20041100 Absil et al. (5366948) 19941100 Chu et al. (4278827) 19810700 Drake et al. (6083865) 20000700 Valyocsik et al. (4873067) 19891000 Butt et al. (5233102) 19930800 Chen et al. (6723297) 20040400 Kisen et al. (6046128) 20000400 |
References_xml | – year: 19880800 ident: 4761513 contributor: fullname: Steacy – year: 19721100 ident: 3702886 contributor: fullname: Argauer et al. – year: 19880200 ident: 4727209 contributor: fullname: Chao – year: 19970300 ident: 5607890 contributor: fullname: Chen et al. – year: 20021000 ident: 6459006 contributor: fullname: Ou et al. – year: 19890700 ident: 4847223 contributor: fullname: Le Van Mao et al. – year: 20010400 ident: 6217748 contributor: fullname: Hatanaka et al. – year: 19930500 ident: 5210356 contributor: fullname: Shamshoum et al. – year: 19880700 ident: 4758328 contributor: fullname: Young – year: 19990700 ident: 5922922 contributor: fullname: Harris et al. – year: 20040400 ident: 6723297 contributor: fullname: Chen et al. – year: 19940500 ident: 5315033 contributor: fullname: Butt et al. – year: 20010200 ident: 6187982 contributor: fullname: Beck et al. – year: 20030100 ident: 6506954 contributor: fullname: Brown et al. – year: 19920500 ident: 5110776 contributor: fullname: Chitnis et al. – year: 19941100 ident: 5367100 contributor: fullname: Gongwei et al. – year: 19981200 ident: 5847255 contributor: fullname: Ghosh et al. – year: 20030100 ident: 6504072 contributor: fullname: Brown et al. – year: 20030100 ident: 6503862 contributor: fullname: Yamamoto – year: 19980700 ident: 5780563 contributor: fullname: Chen et al. – year: 19810700 ident: 4278827 contributor: fullname: Chu et al. – year: 20021000 ident: 6469095 contributor: fullname: Gareiss et al. – year: 19851000 ident: 4548914 contributor: fullname: Chu – year: 19871200 ident: 4716135 contributor: fullname: Chen – year: 20040900 ident: 6799089 contributor: fullname: Toulhoat – year: 19920400 ident: 5105047 contributor: fullname: Waller – year: 19940900 ident: 5345021 contributor: fullname: Casci et al. – year: 19981100 ident: 5833840 contributor: fullname: Absil et al. – year: 20000700 ident: 6090274 contributor: fullname: Wu et al. – year: 20020500 ident: 6388156 contributor: fullname: Ou et al. – year: 19870100 ident: 4638106 contributor: fullname: Pieters et al. – year: 19950100 ident: 5385718 contributor: fullname: Casci et al. – year: 19960700 ident: 5541146 contributor: fullname: Chang et al. – year: 19930900 ident: 5246688 contributor: fullname: Faust et al. – year: 19861100 ident: 4623633 contributor: fullname: Young – year: 19941200 ident: 5371307 contributor: fullname: Guth et al. – year: 20040400 ident: 6726834 contributor: fullname: Quesada et al. – year: 20000500 ident: 6057485 contributor: fullname: Merrill et al. – year: 20000600 ident: 6080698 contributor: fullname: Zhang et al. – year: 19920300 ident: 5094995 contributor: fullname: Butt et al. – year: 19870900 ident: 4694114 contributor: fullname: Chu et al. – year: 19880100 ident: 4721827 contributor: fullname: Cullo et al. – year: 20000300 ident: 6040257 contributor: fullname: Drake et al. – year: 19920600 ident: 5124299 contributor: fullname: Waller – year: 20010600 ident: 6251263 contributor: fullname: Hatanaka et al. – year: 19930700 ident: 5231064 contributor: fullname: Absil et al. – year: 19990900 ident: 5951963 contributor: fullname: He et al. – year: 20011000 ident: 6306790 contributor: fullname: Rodriguez et al. – year: 19951100 ident: 5464799 contributor: fullname: Casci et al. – year: 19890800 ident: 4861930 contributor: fullname: Cottrell et al. – year: 20020100 ident: 6342153 contributor: fullname: Guan et al. – year: 20000600 ident: 6074975 contributor: fullname: Yao et al. – year: 20010400 ident: 6222084 contributor: fullname: Ghosh et al. – year: 19910900 ident: 5047141 contributor: fullname: Chu – year: 20000900 ident: 6124227 contributor: fullname: Yao et al. – year: 20011000 ident: 6300535 contributor: fullname: van den Berge et al. – year: 19971200 ident: 5698756 contributor: fullname: Beck et al. – year: 19990500 ident: 5902919 contributor: fullname: Chen et al. – year: 20000400 ident: 6046128 contributor: fullname: Kisen et al. – year: 19901000 ident: 4962255 contributor: fullname: Fraenkel et al. – year: 20020900 ident: 6444610 contributor: fullname: Yamamoto – year: 19950200 ident: 5387732 contributor: fullname: Shamshoum et al. – year: 20020700 ident: 6423879 contributor: fullname: Brown et al. – year: 20030200 ident: 6518213 contributor: fullname: Yamamoto et al. – year: 19990500 ident: 5905051 contributor: fullname: Wu et al. – year: 19961100 ident: 5576256 contributor: fullname: Monque et al. – year: 19970700 ident: 5646314 contributor: fullname: Crocco et al. – year: 19930900 ident: 5248841 contributor: fullname: Young – year: 19991100 ident: 5990031 contributor: fullname: Ghosh – year: 19951000 ident: 5456821 contributor: fullname: Absil et al. – year: 19980800 ident: 5789335 contributor: fullname: Chen et al. – year: 20000400 ident: 6048816 contributor: fullname: Brown et al. – year: 19960600 ident: 5523510 contributor: fullname: Pellet et al. – year: 19950100 ident: 5380690 contributor: fullname: Zhicheng et al. – year: 19950700 ident: 5430213 contributor: fullname: Hendriksen et al. – year: 19940300 ident: 5294578 contributor: fullname: Ho et al. – year: 20010400 ident: 6211104 contributor: fullname: Shi et al. – year: 19941100 ident: 5365003 contributor: fullname: Chang et al. – year: 20030100 ident: 6504074 contributor: fullname: Verduijn et al. – year: 19940900 ident: 5349113 contributor: fullname: Chang et al. – year: 19990500 ident: 5907073 contributor: fullname: Ghosh – year: 20001200 ident: 6156949 contributor: fullname: Brown et al. – year: 19921200 ident: 5171921 contributor: fullname: Gaffney et al. – year: 19931000 ident: 5254767 contributor: fullname: Dwyer – year: 19960400 ident: 5503818 contributor: fullname: Nicolaides – year: 19990900 ident: 5955641 contributor: fullname: Chen et al. – year: 20010900 ident: 6294493 contributor: fullname: Strohmaier et al. – year: 19950300 ident: 5399336 contributor: fullname: Guth et al. – year: 20030900 ident: 6613951 contributor: fullname: Brown et al. – year: 19950700 ident: 5430212 contributor: fullname: Butt et al. – year: 19951200 ident: 5475179 contributor: fullname: Chang et al. – year: 19961000 ident: 5569805 contributor: fullname: Beck et al. – year: 20000700 ident: 6090991 contributor: fullname: Butler et al. – year: 19941100 ident: 5366948 contributor: fullname: Absil et al. – year: 19900100 ident: 4891197 contributor: fullname: Derouane et al. – year: 19900300 ident: 4912073 contributor: fullname: Chu – year: 20020600 ident: 6399530 contributor: fullname: Chen et al. – year: 19901100 ident: 4973781 contributor: fullname: Valyocsik et al. – year: 20041100 ident: 6811684 contributor: fullname: Mohr et al. – year: 19900400 ident: 4914067 contributor: fullname: Pellet et al. – year: 19860500 ident: 4590321 contributor: fullname: Chu – year: 20031100 ident: 6642426 contributor: fullname: Johnson et al. – year: 19900100 ident: 4891467 contributor: fullname: Sikkenga – year: 20001200 ident: 6160191 contributor: fullname: Smith et al. – year: 20020500 ident: 6395664 contributor: fullname: Boehner et al. – year: 20041100 ident: 6812181 contributor: fullname: van der Berge et al. – year: 19940600 ident: 5321183 contributor: fullname: Chang et al. – year: 19911100 ident: 5068483 contributor: fullname: Barthomeuf et al. – year: 20000700 ident: 6083865 contributor: fullname: Drake et al. – year: 19870900 ident: 4695666 contributor: fullname: Chao et al. – year: 19870900 ident: 4695667 contributor: fullname: Sumitani et al. – year: 19940800 ident: 5336478 contributor: fullname: Dwyer et al. – year: 20000600 ident: 6080303 contributor: fullname: Cao et al. – year: 19760600 ident: 3965207 contributor: fullname: Weinstein – year: 19970700 ident: 5648580 contributor: fullname: Chen et al. – year: 19940600 ident: 5318696 contributor: fullname: Kowalski – year: 20030700 ident: 6589901 contributor: fullname: Yamamoto – year: 19980900 ident: 5811613 contributor: fullname: Bhat et al. – year: 19931000 ident: 5254770 contributor: fullname: Olson et al. – year: 19990800 ident: 5939597 contributor: fullname: Dessau et al. – year: 19871100 ident: 4704495 contributor: fullname: Dessau – year: 19921200 ident: 5173461 contributor: fullname: Absil et al. – year: 19930800 ident: 5233102 contributor: fullname: Butt et al. – year: 20030500 ident: 6566293 contributor: fullname: Vogt et al. – year: 20040200 ident: 6689929 contributor: fullname: Williams et al. – year: 19880500 ident: 4746763 contributor: fullname: Kocal – year: 19930100 ident: 5178748 contributor: fullname: Casci et al. – year: 19870500 ident: 4665251 contributor: fullname: Chu – year: 19971100 ident: 5689024 contributor: fullname: Schmitt – year: 19900600 ident: 4935574 contributor: fullname: D'Amore et al. – year: 19910800 ident: 5041402 contributor: fullname: Casci et al. – year: 19971000 ident: 5675047 contributor: fullname: Beck et al. – year: 20040800 ident: 6773694 contributor: fullname: Lesch et al. – year: 19940900 ident: 5348643 contributor: fullname: Absil et al. – year: 19961100 ident: 5573746 contributor: fullname: Chen – year: 19990700 ident: 5925586 contributor: fullname: Sun – year: 19961000 ident: 5563310 contributor: fullname: Chang et al. – year: 20030400 ident: 6548725 contributor: fullname: Froment et al. – year: 19940800 ident: 5336824 contributor: fullname: Shamshoum et al. – year: 19960700 ident: 5534239 contributor: fullname: Fajula et al. – year: 19961000 ident: 5561095 contributor: fullname: Chen et al. – year: 20000800 ident: 6096938 contributor: fullname: Ghosh – year: 19870600 ident: 4673767 contributor: fullname: Nimry et al. – year: 19961100 ident: 5571768 contributor: fullname: Chang et al. – year: 19861100 ident: 4623530 contributor: fullname: Cullo et al. – year: 19910800 ident: 5043502 contributor: fullname: Martindale et al. – year: 19951000 ident: 5455213 contributor: fullname: Chang et al. – year: 19900200 ident: 4902406 contributor: fullname: Valyocsik – year: 20040800 ident: 6770251 contributor: fullname: Yoshikawa – year: 20000800 ident: 6100437 contributor: fullname: Koehl et al. – year: 19970800 ident: 5658454 contributor: fullname: Absil et al. – year: 20000400 ident: 6047544 contributor: fullname: Yamamoto et al. – year: 20001100 ident: 6150293 contributor: fullname: Verduijn et al. – year: 19870600 ident: 4670616 contributor: fullname: De Simone et al. – year: 19960300 ident: 5498814 contributor: fullname: Chang et al. – year: 19920400 ident: 5108579 contributor: fullname: Casci – year: 19960700 ident: 5536894 contributor: fullname: Degnan et al. – year: 20040300 ident: 6699811 contributor: fullname: Mohr et al. – year: 20000500 ident: 6060633 contributor: fullname: Chen et al. – year: 19950800 ident: 5446234 contributor: fullname: Casci et al. – year: 20020700 ident: 6417421 contributor: fullname: Yao – year: 19930700 ident: 5227558 contributor: fullname: Shamshoum et al. – year: 19970300 ident: 5607888 contributor: fullname: Chang et al. – year: 19991100 ident: 5994603 contributor: fullname: Mohr et al. – year: 20010700 ident: 6268305 contributor: fullname: Butler et al. – year: 20030900 ident: 6613708 contributor: fullname: Ou et al. – year: 19891000 ident: 4873067 contributor: fullname: Valyocsik et al. – year: 19960500 ident: 5516736 contributor: fullname: Chang et al. – year: 20000300 ident: 6034283 contributor: fullname: Ban et al. – year: 19950100 ident: 5378670 contributor: fullname: Kumar |
Score | 2.6845827 |
Snippet | A method of converting methanol to a xylene product is achieved by providing a reactor containing a non-steamed, phosphorus-treated ZSM-5-type zeolite... |
SourceID | uspatents |
SourceType | Open Access Repository |
Title | Toluene methylation process with increased methanol selectivity |
URI | https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7279608 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3fS8MwED62IahPiorzF3nwNdqltTZPPshKEZQ9TNjbSJurCDMtS4f433uXyvBF30ISLkfC5S7Jl-8ArlNmRbNlJK0mc0uqKJbGqInEylYTlZZoA8XG80tavCZPi7vFAIrtX5gPMiPZki7-ZuPbrgngStre-4WXPfkzcwQ6Zh_4dKvG2Jmtb8kPUzCeDWGYRQztm-bFPuySCArZXOd_OY38AHZmofYQBuiO4GHecDoQFJy0-auHoIm2x-kLvg4V745DOI82dDGuWQkf0tSEBA_HIPLp_LGQ29GWb2tGsSyjH63iExjRaR5PQcSxukcMgbxJSlVrpXStKkNFRJ1mYxj_Kebsn7Zz2AvXjvy2rS9g1K03eEn-siuvwmR8A0Xcd_c |
link.rule.ids | 230,309,783,805,888,64367 |
linkProvider | USPTO |
linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV07T8MwED6VgnhMIECUpwdWQ-qEUE8MQBReVYYidYuc-IKQihPVqRD_nrODKhbYLNs6n2yd7-HzdwDnsUNF00XAtSRxi8og5EqJIcdSl0MRF6g9xMbLOE5fo8fp1bQH6fIvzAeJEW-IF3uxsE1b--RKut67g-cd-LPDCDQOfeDTzGqlM11dkh4mY3y0AqukY2PvkiXpFmwQETLaTGt_qY1kG9Yy37sDPTS7cDOpXUEQZK5s81eXhMaaLlOfuYAoezfOiLOo_RRl6hmzvlCNL_GwByy5n9ymfLla_jZ3eSx58MNXuA998ufxAFgYimtEb8qrqBCVFEJWolTURJTxaACDP8kc_jN2BuvZXZI_P4yfjmDTxyDdQ7c8hn47X-AJKc-2OPX78g1SpXr0 |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Apatent&rft.title=Toluene+methylation+process+with+increased+methanol+selectivity&rft.inventor=Ghosh%2C+Ashim+Kumar&rft.inventor=Kulkarni%2C+Neeta&rft.inventor=Harvey%2C+Pamela&rft.number=7279608&rft.date=2007-10-09&rft.externalDBID=n%2Fa&rft.externalDocID=07279608 |