Preparation of substituted indenes

The present invention relates to a simple process for preparing specifically substituted indenes of the formula (I) or (Ia) to compounds of the formula (II) serving as starting materials and to the use of the compounds of the formula (II) as starting materials for the synthesis of substituted indene...

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Main Authors Schulte, Jörg, Schottek, Jörg, Fisch, Lothar
Format Patent
LanguageEnglish
Published 03.04.2007
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Abstract The present invention relates to a simple process for preparing specifically substituted indenes of the formula (I) or (Ia) to compounds of the formula (II) serving as starting materials and to the use of the compounds of the formula (II) as starting materials for the synthesis of substituted indenes.
AbstractList The present invention relates to a simple process for preparing specifically substituted indenes of the formula (I) or (Ia) to compounds of the formula (II) serving as starting materials and to the use of the compounds of the formula (II) as starting materials for the synthesis of substituted indenes.
Author Schottek, Jörg
Schulte, Jörg
Fisch, Lothar
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References Sullivan et al. (5789634) 19980800
(WO-98/40331) 19980900
Ellis, William W. et al., "Synthesis, Structure, and Properties of Chiral Titanium and Zirconium Complexes Bearing Biaryl Strapped Substituted Cyclopentadienyl Ligands", Organometallics 1993, vol. 12, pp. 4391-4401.
Witte, Peter et al., "Synthesis of Unbridged Bis(2-R-indenyl)zirconocenes Containing Functional Groups and Investigations in Propylene Polymerization", Organometallics 1999, vol. 18, pp. 4147-4155.
Beilstein Online, Registry No. 6314119, BE618638, XP002270402, 1994 and 1962, respectivley.
Küber et al. (5770753) 19980600
Fukuoka et al. (5723640) 19980300
Holm, Torkil, "Thermochemical Bond Dissociation Energies of Carbon-Magnesium Bonds", J. Chem.Soc. Perkin Trans.2, 1981, pp. 464-467.
Ikoma, Yoshiharu et al., "Non-ligated Nickel Chloride-Catalyzed Cross-Coupling of Aromatic Grignard Reagents with Aryl Halides", Synthesis 1990, pp. 147-148.
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Snippet The present invention relates to a simple process for preparing specifically substituted indenes of the formula (I) or (Ia) to compounds of the formula (II)...
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