Structure and electric properties of BaCe0.77 − xZrxGd0.2Cu0.03O3 − δ
Absract In the present work, samples with the composition of BaCe 0.77 − x Zr x Gd 0.2 Cu 0.03 O 3 − δ ( x = 0, 0.1…0.7, 0.77) were synthesized according to the standard solid state technique. The effect of zirconium oxide on the phase character, structure, and conductivity was studied using the met...
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Published in | Russian journal of electrochemistry Vol. 47; no. 12; pp. 1404 - 1410 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
SP MAIK Nauka/Interperiodica
2011
|
Subjects | |
Online Access | Get full text |
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Abstract | Absract
In the present work, samples with the composition of BaCe
0.77 −
x
Zr
x
Gd
0.2
Cu
0.03
O
3 − δ
(
x
= 0, 0.1…0.7, 0.77) were synthesized according to the standard solid state technique. The effect of zirconium oxide on the phase character, structure, and conductivity was studied using the methods of X-ray diffraction analysis, scanning electron microscopy, and four-probe method, accordingly. Stability of these materials in the flow of carbon dioxide was studied. The results show that introduction of zirconium oxide leads to preservation of a single-phase system (
x
≤ 0.6), a decrease in the grain size, and an increase in stability in the CO
2
atmosphere. |
---|---|
AbstractList | Absract
In the present work, samples with the composition of BaCe
0.77 −
x
Zr
x
Gd
0.2
Cu
0.03
O
3 − δ
(
x
= 0, 0.1…0.7, 0.77) were synthesized according to the standard solid state technique. The effect of zirconium oxide on the phase character, structure, and conductivity was studied using the methods of X-ray diffraction analysis, scanning electron microscopy, and four-probe method, accordingly. Stability of these materials in the flow of carbon dioxide was studied. The results show that introduction of zirconium oxide leads to preservation of a single-phase system (
x
≤ 0.6), a decrease in the grain size, and an increase in stability in the CO
2
atmosphere. |
Author | Antonov, B. D. Medvedev, D. A. Gorbova, E. V. Demin, A. K. |
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Copyright | Pleiades Publishing, Ltd. 2011 |
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DOI | 10.1134/S1023193511090138 |
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Keywords | BaCeO density sintering conductivity BaZrO phase composition CuO |
Language | English |
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PublicationTitle | Russian journal of electrochemistry |
PublicationTitleAbbrev | Russ J Electrochem |
PublicationYear | 2011 |
Publisher | SP MAIK Nauka/Interperiodica |
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Snippet | Absract
In the present work, samples with the composition of BaCe
0.77 −
x
Zr
x
Gd
0.2
Cu
0.03
O
3 − δ
(
x
= 0, 0.1…0.7, 0.77) were synthesized according to... |
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StartPage | 1404 |
SubjectTerms | Chemistry Chemistry and Materials Science Electrochemistry Physical Chemistry |
Title | Structure and electric properties of BaCe0.77 − xZrxGd0.2Cu0.03O3 − δ |
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