Highly efficient Ni-Mn/SiO catalyst for the selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone under mild conditions
Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is a key reaction in the conversion of biomass to renewable fuels and value-added chemicals. Developing low-cost, highly efficient and reusable non-noble metal-based heterogeneous catalysts is vital but challenging. Herein, non-noble Ni-M...
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Published in | New journal of chemistry Vol. 47; no. 21; pp. 1455 - 1462 |
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Main Authors | , , , , , , |
Format | Journal Article |
Published |
30.05.2023
|
Online Access | Get full text |
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Abstract | Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is a key reaction in the conversion of biomass to renewable fuels and value-added chemicals. Developing low-cost, highly efficient and reusable non-noble metal-based heterogeneous catalysts is vital but challenging. Herein, non-noble Ni-Mn/SiO
2
catalysts with a low Ni loading (2.0 wt%) were designed for the selective hydrogenation of LA to GVL. The results showed that the optimal Ni-Mn/SiO
2
(Ni/Mn = 2) catalyst with well-dispersed and small-sized metal nanoparticles (2.21 nm) and moderate acid sites exhibited excellent activity and selectivity and achieved a 100% yield of GVL in a 1,4-dioxane solvent under mild reaction conditions (
e.g.
, 0.8 mol% Ni, 140 °C and 2.0 MPa H
2
) for 5.5 h and a 100% GVL yield at 180 °C for 2 h with a turnover frequency (TOF) of 190.2 h
−1
, which is better than most non-noble metal catalysts reported. Furthermore, the catalyst exhibited excellent reusability and could be recycled at least five times with only slight activity loss. This work provides new insights for the rational design of highly efficient and stable non-noble metal catalysts for the conversion of LA to GVL.
Herein, we report a highly efficient non-noble bimetallic Ni-Mn/SiO
2
catalyst for the selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone under mild reaction conditions. |
---|---|
AbstractList | Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is a key reaction in the conversion of biomass to renewable fuels and value-added chemicals. Developing low-cost, highly efficient and reusable non-noble metal-based heterogeneous catalysts is vital but challenging. Herein, non-noble Ni-Mn/SiO
2
catalysts with a low Ni loading (2.0 wt%) were designed for the selective hydrogenation of LA to GVL. The results showed that the optimal Ni-Mn/SiO
2
(Ni/Mn = 2) catalyst with well-dispersed and small-sized metal nanoparticles (2.21 nm) and moderate acid sites exhibited excellent activity and selectivity and achieved a 100% yield of GVL in a 1,4-dioxane solvent under mild reaction conditions (
e.g.
, 0.8 mol% Ni, 140 °C and 2.0 MPa H
2
) for 5.5 h and a 100% GVL yield at 180 °C for 2 h with a turnover frequency (TOF) of 190.2 h
−1
, which is better than most non-noble metal catalysts reported. Furthermore, the catalyst exhibited excellent reusability and could be recycled at least five times with only slight activity loss. This work provides new insights for the rational design of highly efficient and stable non-noble metal catalysts for the conversion of LA to GVL.
Herein, we report a highly efficient non-noble bimetallic Ni-Mn/SiO
2
catalyst for the selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone under mild reaction conditions. |
Author | Liu, Yingxin Chen, Mengting Ma, Jiao Zhong, Qifeng Wei, Zuojun Zhang, Zhiyang Deng, Shuguang |
AuthorAffiliation | Zhejiang University of Technology Key Laboratory of Biomass Chemical Engineering of the Ministry of Education Transport and Energy Arizona State University College of Chemical and Biological Engineering College of Pharmaceutical Science Zhejiang University School for Engineering of Matter |
AuthorAffiliation_xml | – name: Zhejiang University of Technology – name: College of Chemical and Biological Engineering – name: Arizona State University – name: College of Pharmaceutical Science – name: Zhejiang University – name: School for Engineering of Matter – name: Key Laboratory of Biomass Chemical Engineering of the Ministry of Education – name: Transport and Energy |
Author_xml | – sequence: 1 givenname: Mengting surname: Chen fullname: Chen, Mengting – sequence: 2 givenname: Qifeng surname: Zhong fullname: Zhong, Qifeng – sequence: 3 givenname: Jiao surname: Ma fullname: Ma, Jiao – sequence: 4 givenname: Zhiyang surname: Zhang fullname: Zhang, Zhiyang – sequence: 5 givenname: Yingxin surname: Liu fullname: Liu, Yingxin – sequence: 6 givenname: Zuojun surname: Wei fullname: Wei, Zuojun – sequence: 7 givenname: Shuguang surname: Deng fullname: Deng, Shuguang |
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Snippet | Hydrogenation of levulinic acid (LA) to γ-valerolactone (GVL) is a key reaction in the conversion of biomass to renewable fuels and value-added chemicals.... |
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Title | Highly efficient Ni-Mn/SiO catalyst for the selective hydrogenation of biomass-derived levulinic acid to γ-valerolactone under mild conditions |
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