Synthesis of cyclic α-1,4-oligo--acetylglucosamine 'cyclokasaodorin' a one-pot electrochemical polyglycosylation-isomerization-cyclization process

• Published in: Chemical communications (Cambridge, England) Vol. 58; no. 57; pp. 7948 - 7951
• Main Authors: Endo, Hirofumi, Ochi, Masaharu, Rahman, Md Azadur, Hamada, Tomoaki, Kawano, Takahiro, Nokami, Toshiki
• Format: Journal Article
• Published: 14.07.2022

Electrochemical synthesis of unnatural cyclic oligosaccharides composed of N -acetylglucosamine with α-1,4-glycosidic linkages has been accomplished. A thioglycoside monomer equipped with the 2,3-oxazolidinone protecting group was used to prepare linear oligosaccharides by electrochemical polyglycos...