Zn(NH)CO: a "three-in-one" UV nonlinear optical crystal built by a polar molecule bonding strategy
Noncentrosymmetric (NCS) crystals are of great interest because of their functions, such as nonlinear optical (NLO) properties, but their syntheses are still difficult. Remarkably, polar inorganic molecules often have a "Midas touch" in the process of the crystallization of NCS structures....
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| Published in | Journal of materials chemistry. C, Materials for optical and electronic devices Vol. 9; no. 46; pp. 16477 - 16484 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Published |
02.12.2021
|
| Online Access | Get full text |
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| Abstract | Noncentrosymmetric (NCS) crystals are of great interest because of their functions, such as nonlinear optical (NLO) properties, but their syntheses are still difficult. Remarkably, polar inorganic molecules often have a "Midas touch" in the process of the crystallization of NCS structures. Zn(NH
3
)CO
3
has a "three-in-one" NLO-active motif which includes a polar NH
3
molecule, polar displaced Zn
2+
, and π-conjugated CO
3
2−
ions. Zn(NH
3
)CO
3
shows a second harmonic generation (SHG) response of 1.5× KH
2
PO
4
, a short UV cut-off edge of 204 nm, suitable birefringence (0.087 at 546 nm), a short SHG phase-matching wavelength (shortest
λ
PM
= 217 nm), a high laser damage threshold (LDT) (126.3 MW cm
−2
), and good stability. Meanwhile, Zn(NH
3
)CO
3
with a structure like a Chinese knot has excellent crystal growth that makes it easy to obtain centimeter sized blocky crystals. For the first time, ZnO
3
(NH
3
) is used as a new NLO-active motif to explore the formation of NCS zinc carbonate. This research sheds new light on polar molecule bonding strategies to build desired NCS structures, and it reveals for the first time ammine complexes for use as new UV NLO crystals with a bright future.
Centimeter-sized Zn(NH
3
)CO
3
is a "three-in-one" UV nonlinear optical crystal, featuring a Chinese-knot-like framework and great optical performance. |
|---|---|
| AbstractList | Noncentrosymmetric (NCS) crystals are of great interest because of their functions, such as nonlinear optical (NLO) properties, but their syntheses are still difficult. Remarkably, polar inorganic molecules often have a "Midas touch" in the process of the crystallization of NCS structures. Zn(NH
3
)CO
3
has a "three-in-one" NLO-active motif which includes a polar NH
3
molecule, polar displaced Zn
2+
, and π-conjugated CO
3
2−
ions. Zn(NH
3
)CO
3
shows a second harmonic generation (SHG) response of 1.5× KH
2
PO
4
, a short UV cut-off edge of 204 nm, suitable birefringence (0.087 at 546 nm), a short SHG phase-matching wavelength (shortest
λ
PM
= 217 nm), a high laser damage threshold (LDT) (126.3 MW cm
−2
), and good stability. Meanwhile, Zn(NH
3
)CO
3
with a structure like a Chinese knot has excellent crystal growth that makes it easy to obtain centimeter sized blocky crystals. For the first time, ZnO
3
(NH
3
) is used as a new NLO-active motif to explore the formation of NCS zinc carbonate. This research sheds new light on polar molecule bonding strategies to build desired NCS structures, and it reveals for the first time ammine complexes for use as new UV NLO crystals with a bright future.
Centimeter-sized Zn(NH
3
)CO
3
is a "three-in-one" UV nonlinear optical crystal, featuring a Chinese-knot-like framework and great optical performance. |
| Author | Bao, Wen-Xiu Wu, Xin-Tao Fu, Rui-Biao Tang, Hong-Xin Shui, Qi-Rui Zhou, Zi-Qi Ma, Zu-Ju |
| AuthorAffiliation | State Key Laboratory of Structural Chemistry Chinese Academy of Sciences Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China Yantai University Fujian Institute of Research on the Structure of Matter University of Chinese Academy of Sciences School of Environmental and Materials Engineering |
| AuthorAffiliation_xml | – name: Chinese Academy of Sciences – name: Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China – name: State Key Laboratory of Structural Chemistry – name: School of Environmental and Materials Engineering – name: Yantai University – name: University of Chinese Academy of Sciences – name: Fujian Institute of Research on the Structure of Matter |
| Author_xml | – sequence: 1 givenname: Hong-Xin surname: Tang fullname: Tang, Hong-Xin – sequence: 2 givenname: Qi-Rui surname: Shui fullname: Shui, Qi-Rui – sequence: 3 givenname: Rui-Biao surname: Fu fullname: Fu, Rui-Biao – sequence: 4 givenname: Zi-Qi surname: Zhou fullname: Zhou, Zi-Qi – sequence: 5 givenname: Wen-Xiu surname: Bao fullname: Bao, Wen-Xiu – sequence: 6 givenname: Zu-Ju surname: Ma fullname: Ma, Zu-Ju – sequence: 7 givenname: Xin-Tao surname: Wu fullname: Wu, Xin-Tao |
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| Title | Zn(NH)CO: a "three-in-one" UV nonlinear optical crystal built by a polar molecule bonding strategy |
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