The highly efficient removal of HCN over CuMn/CeO catalytic material

• Published in: RSC advances Vol. 11; no. 15; pp. 8886 - 8896
• Main Authors: Yi, Zhihao, Sun, Jie, Li, Jigang, Yang, Yulin, Zhou, Tian, Wei, Shouping, Zhu, Anna
• Format: Journal Article
• Published: 26.02.2021
• DOI: 10.1039/d0ra10177j

In this work, porous CeO 2 flower-like spheres loaded with bimetal oxides were prepared to achieve effective removal of HCN in the lower temperature region of 30-150 °C. Among all samples, the CeO 2 loaded with copper and manganese oxides at the mass ratio of 8/2 (Cu 8 Mn 2 /CeO 2 ) exhibited the highest catalytic activity: the HCN removal rate was nearly 100% at 90 °C at the conditions of 120 000 h −1 and 5 vol% H 2 O, the catalytic activity of which was higher than for other reported catalysts. The introduction of MnO x could improve the dispersion of CuO particles and increase the total acid sites of the prepared samples. It was proved that the synergy between CuO and MnO x , the chemisorption oxygen, the oxygen vacancies, the Cu 2+ and Mn 4+ all played an important role in determining the good catalytic activity of the prepared samples. NH 3 -TPD analysis indicated the introduction of MnO x promoted the conversion of NH 3 and N 2 selectivity by increasing the acid sites of the sample. According to the C, N balance data and FT-IR results, when the temperature was below 30 °C, the removal of HCN over Cu 8 Mn 2 /CeO 2 was mainly by chemisorption and the HCN breakthrough behaviors corresponded to the Yoon and Nelson's model. When temperature was above 120 °C, the HCN was totally removed by catalytic hydrolysis and catalytic oxidation. In this work, porous CeO 2 flower-like spheres loaded with bimetal oxides were prepared to achieve effective removal of HCN in the lower temperature region of 30-150 °C.