Sub-5 nm structured films by hydrogen bonded siloxane liquid crystals and block copolymersElectronic supplementary information (ESI) available: Materials and methods, synthetic produces and characterization, Fig. S1-S9. See DOI: 10.1039/c8tc00627j

This paper describes the synthesis and characterization of a novel class of hydrogen-bonding oligo(dimethylsiloxane)-based thermotropic liquid crystals (LCs), with which polymeric supramolecules were obtained with glassy smectic and columnar sub-5 nm features when combined with poly(4-vinylpyridine)...

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Main Authors Nickmans, Koen, Verpaalen, Rob C. P, Murphy, Jeffrey N, Schenning, Albert P. H. J
Format Journal Article
LanguageEnglish
Published 22.03.2018
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Abstract This paper describes the synthesis and characterization of a novel class of hydrogen-bonding oligo(dimethylsiloxane)-based thermotropic liquid crystals (LCs), with which polymeric supramolecules were obtained with glassy smectic and columnar sub-5 nm features when combined with poly(4-vinylpyridine) homopolymer or poly(styrene)- b -poly(4-vinylpyridine) block copolymer (BCP). The hierarchical self-assembly afforded by the LC/BCP complexes further resulted in the vertical orientation of the LC features in thin films. Polymeric supramolecules were prepared using hydrogen-bonding oligo(dimethylsiloxane)-based liquid crystals and poly(4-vinylpyridine) homopolymer or poly(styrene)- b -poly(4-vinylpyridine) block copolymer. These materials form glassy, hybrid organic/inorganic thin films with sub-5 nm features.
AbstractList This paper describes the synthesis and characterization of a novel class of hydrogen-bonding oligo(dimethylsiloxane)-based thermotropic liquid crystals (LCs), with which polymeric supramolecules were obtained with glassy smectic and columnar sub-5 nm features when combined with poly(4-vinylpyridine) homopolymer or poly(styrene)- b -poly(4-vinylpyridine) block copolymer (BCP). The hierarchical self-assembly afforded by the LC/BCP complexes further resulted in the vertical orientation of the LC features in thin films. Polymeric supramolecules were prepared using hydrogen-bonding oligo(dimethylsiloxane)-based liquid crystals and poly(4-vinylpyridine) homopolymer or poly(styrene)- b -poly(4-vinylpyridine) block copolymer. These materials form glassy, hybrid organic/inorganic thin films with sub-5 nm features.
Author Murphy, Jeffrey N
Schenning, Albert P. H. J
Nickmans, Koen
Verpaalen, Rob C. P
AuthorAffiliation Institute for Complex Molecular Systems
Department of Chemical Engineering and Chemistry
Laboratory of Functional Organic Materials and Devices
Eindhoven University of Technology
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Electronic supplementary information (ESI) available: Materials and methods, synthetic produces and characterization, Fig. S1-S9. See DOI
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References_xml – issn: 2007
  end-page: p 113-177
  publication-title: Hydrogen Bonded Polymers
  doi: ten Brinke Ruokolainen Ikkala
– issn: 2013
  end-page: p 219-245
  publication-title: Liquid Crystalline Semiconductors
  doi: O'Neill Kelly
– issn: 2017
  end-page: 1012513
  publication-title: Proc. SPIE 10125
  doi: Nickmans Schenning
– issn: 2014
  end-page: p 257-280
  publication-title: Nanoscience with Liquid Crystals
  doi: Shimizu
– issn: 1989
  publication-title: Polymer Handbook
  doi: Wu
– issn: 2013
  end-page: p 247-268
  publication-title: Liquid Crystalline Semiconductors
  doi: O'Neill Kelly
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