Heavier pnictinidene gold(i) complexesElectronic supplementary information (ESI) available: Details of crystallographic and theoretical studies. CCDC 1553193-1553198 and 1555817. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt03022g

• Main Authors: Ko enková, Monika, Kremlá ek, Vít, Erben, Milan, Jirásko, Robert, De Proft, Frank, Turek, Jan, Jambor, Roman, R i ka, Aleš, Císa ová, Ivana, Dostál, Libor
• Format: Journal Article
• Published: 23.10.2018

N , C , N -Chelated pnictinidenes ArE [where E = As, Sb or Bi; Ar = 2,6-( t BuN&z.dbd;CH) 2 C 6 H 3 ] were used as ligands for the coordination of various gold( i ) complexes. Thus, the reaction of ArE with [AuCl(Me 2 S)] gave complexes [AuCl(ArE)] [where E = As ( 1 ) or Sb ( 2 )] that exhibited...