All-metal aromatic cationic palladium triangles can mimic aromatic donor ligands with Lewis acidic cationsElectronic supplementary information (ESI) available: Reaction procedures, characterization of complexes, copies of all spectra and cif files, modelling details and XYZ coordinates. CCDC 1410440-1410442. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03475j

We present that cationic rings can act as donor ligands thanks to suitably delocalized metal-metal bonds. This could grant parent complexes with the peculiar properties of aromatic rings that are crafted with main group elements. We assembled Pd nuclei into equilateral mono-cationic triangles with u...

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Bibliographic Details
Main Authors Wang, Yanlan, Monfredini, Anna, Deyris, Pierre-Alexandre, Blanchard, Florent, Derat, Etienne, Maestri, Giovanni, Malacria, Max
Format Journal Article
LanguageEnglish
Published 23.10.2017
Online AccessGet full text

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