Synthesis of phosphonosulfonic acid building blocks as linkers for coordination polymersElectronic supplementary information (ESI) available: Linker synthesis and characterization, [La4(H2L)3(H2O)8] synthesis and characterization, PXRD data, and X-ray crystallographic files. CCDC 1547972. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7nj01697b
Ten aromatic building blocks ( 8-11 , 23-28 ) containing phosphonic and sulfonic acid groups within one molecule were synthesized. Twofold nucleophilic substitution starting from 1,2,4,5-tetrakis(bromomethyl)benzene ( 1 ) followed by hydrolysis gave building blocks 8-11 . To obtain building blocks 2...
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Format | Journal Article |
Language | English |
Published |
21.08.2017
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Abstract | Ten aromatic building blocks (
8-11
,
23-28
) containing phosphonic and sulfonic acid groups within one molecule were synthesized. Twofold nucleophilic substitution starting from 1,2,4,5-tetrakis(bromomethyl)benzene (
1
) followed by hydrolysis gave building blocks
8-11
. To obtain building blocks
23-28
, the respective bromobenzenesulfonic acids
13
,
16
,
18-20
and
22
had to be synthesized first. Palladium-catalysed cross coupling with triethylphosphite followed by hydrolysis gave the desired building blocks with phosphonic and sulfonic acid groups. Building block
9
was successfully used as a linker for the synthesis of a new La-based CP with the composition [La
2
(H
2
L)
1.5
(H
2
O)
4
].
Ten benzene based linkers containing sulfonic and phosphonic acids have been synthesized. One lanthanum MOF was isolated and characterized. |
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AbstractList | Ten aromatic building blocks (
8-11
,
23-28
) containing phosphonic and sulfonic acid groups within one molecule were synthesized. Twofold nucleophilic substitution starting from 1,2,4,5-tetrakis(bromomethyl)benzene (
1
) followed by hydrolysis gave building blocks
8-11
. To obtain building blocks
23-28
, the respective bromobenzenesulfonic acids
13
,
16
,
18-20
and
22
had to be synthesized first. Palladium-catalysed cross coupling with triethylphosphite followed by hydrolysis gave the desired building blocks with phosphonic and sulfonic acid groups. Building block
9
was successfully used as a linker for the synthesis of a new La-based CP with the composition [La
2
(H
2
L)
1.5
(H
2
O)
4
].
Ten benzene based linkers containing sulfonic and phosphonic acids have been synthesized. One lanthanum MOF was isolated and characterized. |
Author | Homburg, T Stock, N Beyer, O Albat, M Lüning, U |
AuthorAffiliation | Institut für Anorganische Chemie Otto-Diels-Institut für Organische Chemie Christian-Albrechts-Universität zu Kiel |
AuthorAffiliation_xml | – name: Christian-Albrechts-Universität zu Kiel – name: Institut für Anorganische Chemie – name: Otto-Diels-Institut für Organische Chemie |
Author_xml | – sequence: 1 givenname: O surname: Beyer fullname: Beyer, O – sequence: 2 givenname: T surname: Homburg fullname: Homburg, T – sequence: 3 givenname: M surname: Albat fullname: Albat, M – sequence: 4 givenname: N surname: Stock fullname: Stock, N – sequence: 5 givenname: U surname: Lüning fullname: Lüning, U |
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ContentType | Journal Article |
DOI | 10.1039/c7nj01697b |
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Notes | Electronic supplementary information (ESI) available: Linker synthesis and characterization, [La 10.1039/c7nj01697b For ESI and crystallographic data in CIF or other electronic format see DOI 2 3 4 1547972 H 8 L O synthesis and characterization, PXRD data, and X-ray crystallographic files. CCDC |
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References_xml | – issn: 2012 publication-title: US Pat. doi: Teasley – issn: 2009 publication-title: US Pat. doi: Litt Kang – issn: 2016 publication-title: The Chemistry of Metal-Organic Frameworks. Synthesis, Characterization, and Applications – issn: 2011 publication-title: Metal-Organic Frameworks. Applications from Catalysis to Gas Storage |
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Snippet | Ten aromatic building blocks (
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Title | Synthesis of phosphonosulfonic acid building blocks as linkers for coordination polymersElectronic supplementary information (ESI) available: Linker synthesis and characterization, [La4(H2L)3(H2O)8] synthesis and characterization, PXRD data, and X-ray crystallographic files. CCDC 1547972. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7nj01697b |
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