Mechanochemistry - a new powerful green approach to the direct synthesis of alkoxysilanesElectronic supplementary information (ESI) available. See DOI: 10.1039/c7gc03862c
The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplifi...
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08.05.2018
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Abstract | The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000-2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS).
The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes. |
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AbstractList | The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes by silicon mechanoactivation followed by a reaction with an alcohol. Alkoxysilanes were obtained with nearly complete silicon and alcohol conversion. This method allows for a considerable simplification of the traditional multistage process by eliminating three stages that include silicon and catalyst preparation, and adapts it to green chemistry requirements. Vibration milling removed the oxide film, and the mechanoactivation of the large silicon fraction (1000-2000 μm) occurs in the reactor working space. Abrasion of the reactor walls and grinding bodies made of brass results in a developed catalytic surface on silicon, as it has been proven by a set of physical analytical methods such as scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), powder X-ray diffraction (PXRD), and X-ray photoelectron spectroscopy (XPS).
The present work shows a new one-stage mechanochemical method for the direct synthesis of alkoxysilanes. |
Author | Muzafarov, Aziz M Katsoulis, Dimitris Kholodkov, Dmitry N Naumkin, Alexander V Goloveshkin, Alexander S Zhemchugov, Pavel V Temnikov, Maxim N Anisimov, Anton A Chistovalov, Sergey M |
AuthorAffiliation | A.N. Nesmeyanov Institute of Organoelement Compounds N.S. Enikolopov Institute of Synthetic Polymeric Materials Russian Academy of Sciences (ISPM RAS) Russian Academy of Sciences (INEOS RAS) Dow Corning Corporation. A wholly owned subsidiary of The Dow Chemical Company |
AuthorAffiliation_xml | – name: Dow Corning Corporation. A wholly owned subsidiary of The Dow Chemical Company – name: Russian Academy of Sciences (INEOS RAS) – name: A.N. Nesmeyanov Institute of Organoelement Compounds – name: N.S. Enikolopov Institute of Synthetic Polymeric Materials – name: Russian Academy of Sciences (ISPM RAS) |
Author_xml | – sequence: 1 givenname: Maxim N surname: Temnikov fullname: Temnikov, Maxim N – sequence: 2 givenname: Anton A surname: Anisimov fullname: Anisimov, Anton A – sequence: 3 givenname: Pavel V surname: Zhemchugov fullname: Zhemchugov, Pavel V – sequence: 4 givenname: Dmitry N surname: Kholodkov fullname: Kholodkov, Dmitry N – sequence: 5 givenname: Alexander S surname: Goloveshkin fullname: Goloveshkin, Alexander S – sequence: 6 givenname: Alexander V surname: Naumkin fullname: Naumkin, Alexander V – sequence: 7 givenname: Sergey M surname: Chistovalov fullname: Chistovalov, Sergey M – sequence: 8 givenname: Dimitris surname: Katsoulis fullname: Katsoulis, Dimitris – sequence: 9 givenname: Aziz M surname: Muzafarov fullname: Muzafarov, Aziz M |
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References_xml | – issn: 2009 volume-title: Process for Preparation of Trialkoxysilanes end-page: 7.582.788B2 publication-title: US Patent doi: Roston Cody Bowman – issn: 1972 publication-title: Vibrokipyashchiy sloy doi: Chlenol Mikhaylov – issn: 2000 publication-title: Silicon in Organic, Organometallic, and Polymer Chemistry doi: Brook – issn: 2008 volume-title: Process for the Direct Synthesis of Trialkoxysilane end-page: 7.429.672B2 publication-title: US Patent doi: Lewis Cameron Ritscher – issn: 2011 volume-title: Method of Producing a Hydrolyzable Silicone-Containing Compound end-page: WO2012091154A1 doi: Wakabayashi Oda Taniguchi Sugiura – issn: 2006 volume-title: Method for Preparing Alkoxysilanes end-page: 2277537C1 publication-title: RU Patent doi: Gorshkov Storozhenko – issn: 2008 volume-title: Nanosized Copper Catalyst Precursors for the Direct Synthesis of Trialkoxysilanes end-page: 2008081923A1 publication-title: US Patent doi: Lewis Eng Cromer Mereigh O'Young – issn: 2002 volume-title: Method of Regeneration of Solvent in Process Direct Synthesis of Alkoxysilane end-page: 2185384C1 publication-title: RU Patent doi: Kopylov Markacheva Polivanov – issn: 2004 volume-title: Apparatus and Process for Preparing Substantially Halogen-Free Trialkoxysilanes end-page: 6.727.375B2 publication-title: US Patent doi: Steding Grund Standke Horn Frings Monkiewicz Srebny Seiler Kotzsch – issn: 2007 end-page: 20070073076A1 publication-title: US Patent doi: Lewis Wang – issn: 2007 volume-title: Process for the Direct Synthesis of Trialkoxysilane end-page: 2007/0060764A1 publication-title: US Patent doi: Lewis Mereigh O'Young Cameron – issn: 2010 issue: 235 end-page: 161-183 publication-title: Advances in Polymer Science doi: Brook Grande Ganachaud – issn: 2003 volume-title: "Ivtekhim," Method of Synthesis of Alkoxysilanes end-page: 2196142C2 publication-title: RU Patent – issn: 2002 volume-title: Freshly Precipitated CuO as Catalyst for the trialkoxysilane synthesis end-page: 6.380.414B2 publication-title: US Patent doi: Brand – issn: 2002 volume-title: Fluorinated copper salts as catalysts for the synthesis of trialkoxysilanes end-page: 6.410.771B1 publication-title: US Patent doi: Brand – issn: 2012 volume-title: Catalyst of Direct Synthesis of Triethoxysilane and Method of its Obtaining end-page: 2468865C1 publication-title: RU Patent doi: Parmon Adonin Zajkovskij Prosvirin Mel'gunov Storozhenko Monin Bykova Rusakov Martynov Rogozhin – issn: 2013 volume-title: Method of Production Trialkoxysilane end-page: 2476435C1 publication-title: RU Patent doi: Monin Storozhenko Bykova Rusakov – issn: 2001 volume-title: Removal of Dissolved Silicates from Alcohol-Silicon Direct Synthesis Solvents end-page: 01/12635A1 publication-title: WO Patent doi: Simandan Mendicino – issn: 2008 volume-title: Process for Preparation of alkoxysilanes end-page: 2008/0132721A1 publication-title: US Patent doi: Roston Cody Bowman – issn: 2007 volume-title: Surface-Active Additives in the Direct Synthesis of Trialkoxysilanes end-page: RE39.650E publication-title: US Patent doi: Mendicino Lewis Magri Yu Childress – issn: 2004 volume-title: Method of Synthesis of Alkoxysilanes end-page: 2235726C1 publication-title: RU Patent doi: Gorshkov Markacheva Storozhenko – issn: 2001 volume-title: Nanosize copper catalyst precursors for the direct synthesis of trialkoxysilanes end-page: 2319851A1 publication-title: EP Patent doi: Lewis Eng Cromer O'Young Mereigh |
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