Formation of charge-transfer complexes based on a tropylium cation and 2,6-helic[6]arenes: a visible redox stimulus-responsive processElectronic supplementary information (ESI) available: Additional 1H NMR spectra, ESI-MS for the complexes, determination of the association constants and theoretical study. See DOI: 10.1039/c7cc00600d
Charge-transfer (CT) complexes formed from 2,6-helic[6]arene hosts and a tropylium cation are described in detail. In particular, it was found that the binding and release processes of the guest in the complexes could be efficiently controlled by a redox stimulus, and the responsive process could be...
Saved in:
Main Authors | , , |
---|---|
Format | Journal Article |
Language | English |
Published |
23.02.2017
|
Online Access | Get full text |
Cover
Loading…
Abstract | Charge-transfer (CT) complexes formed from 2,6-helic[6]arene hosts and a tropylium cation are described in detail. In particular, it was found that the binding and release processes of the guest in the complexes could be efficiently controlled by a redox stimulus, and the responsive process could be visually observed by the color change of the solution. To our knowledge, this represents the first visible redox stimulus-responsive host-guest system formed from the tropylium cation.
Charge-transfer complexes between 2,6-helic[6]arenes and a tropylium cation formed, and they could undergo visible redox stimulus-responsive and switchable complexation processes. |
---|---|
AbstractList | Charge-transfer (CT) complexes formed from 2,6-helic[6]arene hosts and a tropylium cation are described in detail. In particular, it was found that the binding and release processes of the guest in the complexes could be efficiently controlled by a redox stimulus, and the responsive process could be visually observed by the color change of the solution. To our knowledge, this represents the first visible redox stimulus-responsive host-guest system formed from the tropylium cation.
Charge-transfer complexes between 2,6-helic[6]arenes and a tropylium cation formed, and they could undergo visible redox stimulus-responsive and switchable complexation processes. |
Author | Chen, Chuan-Feng Shi, Qiang Zhang, Geng-Wu |
AuthorAffiliation | Chinese Academy of Sciences Institute of Chemistry Beijing National Laboratory for Molecular Sciences CAS Key Laboratory of Molecular Recognition and Function University of Chinese Academy of Sciences |
AuthorAffiliation_xml | – name: Beijing National Laboratory for Molecular Sciences – name: CAS Key Laboratory of Molecular Recognition and Function – name: Institute of Chemistry – name: Chinese Academy of Sciences – name: University of Chinese Academy of Sciences |
Author_xml | – sequence: 1 givenname: Geng-Wu surname: Zhang fullname: Zhang, Geng-Wu – sequence: 2 givenname: Qiang surname: Shi fullname: Shi, Qiang – sequence: 3 givenname: Chuan-Feng surname: Chen fullname: Chen, Chuan-Feng |
BookMark | eNqFUE1PAkEMXQ0mAnrxblJvmrC46_J9MwqBA5iIBxNjyDDTlTGzM5vpLIF_76wYOJhoL236Xl_7Wgsq2mgMgos4asZR0r_lXc6jqBNF4jioxkmnFbZbvddKWbf7YTdptU-DGtFn5CNu96pHs5GxGXPSaDAp8BWzHxg6yzSlaIGbLFe4QYIlIxTgWQycNflWySIDvhtkWsBdoxOuUEn-1nlnFjXSwFPXkuRSIVgUZgPkZFaogkKLlBtNco2QW8ORaKiQe10tOVCR-50ZasfsFqRO9wdeD-eTG2BrJhXzqgO4F0KWCFMQj2E2fQbKSx3WAE8Np3Pww-BWeDDSAIEObSb13nSJMyLD5a7F_WmOaUffxjxqLDrJ_RJyhdg2YY4Ij0-TAfz--llwkjJFeP6T68HlaPjyMA4t8UVuZeY9LQ70pB5c_YUvcpEm_2l8Af8op4A |
ContentType | Journal Article |
DOI | 10.1039/c7cc00600d |
DatabaseTitleList | |
DeliveryMethod | fulltext_linktorsrc |
Discipline | Chemistry |
EISSN | 1364-548X |
EndPage | 2585 |
ExternalDocumentID | c7cc00600d |
GroupedDBID | -JG 0-7 1TJ 705 70J 70~ 7~J AAEMU ABGFH ACLDK ADSRN AEFDR AFVBQ AGSTE AUDPV BSQNT C6K EE0 EF- GNO H~N IDZ J3I R7B R7C R7D RCNCU RPMJG RRA RRC RSCEA SKA SKF SKH SLH VH6 |
ID | FETCH-rsc_primary_c7cc00600d3 |
ISSN | 1359-7345 |
IngestDate | Mon Jan 28 17:14:38 EST 2019 Thu May 30 17:44:32 EDT 2019 |
IsPeerReviewed | true |
IsScholarly | true |
Issue | 17 |
Language | English |
LinkModel | OpenURL |
MergedId | FETCHMERGED-rsc_primary_c7cc00600d3 |
Notes | 1 H NMR spectra, ESI-MS for the complexes, determination of the association constants and theoretical study. See DOI Electronic supplementary information (ESI) available: Additional 10.1039/c7cc00600d |
PageCount | 4 |
ParticipantIDs | rsc_primary_c7cc00600d |
ProviderPackageCode | RRA J3I ACLDK RRC 7~J AEFDR 70~ VH6 GNO RCNCU SLH 70J EE0 RSCEA AFVBQ C6K H~N 0-7 IDZ RPMJG 1TJ SKA -JG AGSTE AUDPV EF- BSQNT SKF SKH ADSRN ABGFH 705 R7B R7D AAEMU R7C |
PublicationCentury | 2000 |
PublicationDate | 20170223 |
PublicationDateYYYYMMDD | 2017-02-23 |
PublicationDate_xml | – month: 2 year: 2017 text: 20170223 day: 23 |
PublicationDecade | 2010 |
PublicationYear | 2017 |
References_xml | – issn: 1995 publication-title: Supramolecular Chemistry doi: Lehn – issn: 2009 publication-title: Supramol. Chem. doi: Steed Atwood – issn: 2005 publication-title: Macrocyclic Chemistry: Current Trends and Future Perspectives doi: Gloe |
SSID | ssj0000158 |
Score | 4.531035 |
Snippet | Charge-transfer (CT) complexes formed from 2,6-helic[6]arene hosts and a tropylium cation are described in detail. In particular, it was found that the binding... |
SourceID | rsc |
SourceType | Enrichment Source Publisher |
StartPage | 2582 |
Title | Formation of charge-transfer complexes based on a tropylium cation and 2,6-helic[6]arenes: a visible redox stimulus-responsive processElectronic supplementary information (ESI) available: Additional 1H NMR spectra, ESI-MS for the complexes, determination of the association constants and theoretical study. See DOI: 10.1039/c7cc00600d |
Volume | 53 |
hasFullText | 1 |
inHoldings | 1 |
isFullTextHit | |
isPrint | |
link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnZ3vb9JAGMfPjb3QN8Zfi5vOPC9coinHoKUt3bu5McEIRoeRxBhybQ8kYUBKu0z_ep_n2l6LYKK-IdDrNVyfT3vXp8_3eRh7GTZa9aY_trlntuq82QpCLqRpcRF6MnBd4QZ1Ejj3-k7nc_Pd0B7u7J6UopaS2K8FP7fqSv7HqrgN7Uoq2X-wrD4obsDvaF_8RAvj51_Z-DJXHqrgcMp5JHmsVqIySoPF5a1cGTRThfRWQBhxtFj-mE2TayN11al3ByaeZ4d_l7NpcGy_cY7tC1KIpcFywiD1OcmrKLPorYF3hOtklqx4lAXX3pDSSokN2kVFnRXVCk3j0iMSFmqJJC1o21dd8kWIGzGdkXBL-SbDcJp5JRsdo9_7ZCgJqCqCZGAH3rvSAZF6YNQW5uE8-WmgPUTBHIXV0wI4XuWxolq3qTLr1vBuKY2LD13lGlHZASg1auAGASWRqYcbnvW3cj7hXxLtmlJVkY2PeJlNilgJmcUyJGLOEZlJ2bmCEzaJ1a3SfGDZHnetNONlTWbbnCbHB71heRKxrfLF4panBDutrpQtL_CnvXXq2jq89VTgReMu2zNdz7YrbO-sPei-L2VMUyVp9f_OM_Ja3knRG9dRUV7fRq2jBg_Y_ewBCM5Smh-yHTl_xO6e53UHH9_pa6phMYbfqAZtfFBUA-4lQFMNKdWApgazmjH91fmW8nyKu2Y0g6IZttAMGzTDGs1QohleIZqvQZN8CgXH0OgAcgwZx1VIKQbsDEhhMZAqrDFMg6b2EsOgGVYDKzEMKcOADAMyfAqbVnjCji7bg_MOR1uMlmlumVHRbO2zynwxl08ZmLaoWy0ZhgE-QIzNho_zqO_7wiNluWs5B2x_-zEO2OH2htEyHB_-qdczdq-4Fp6zShwl8giX3rH_IsPtFwKp5rk |
link.rule.ids | 315,786,790,27955,27956 |
linkProvider | Royal Society of Chemistry |
openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Formation+of+charge-transfer+complexes+based+on+a+tropylium+cation+and+2%2C6-helic%5B6%5Darenes%3A+a+visible+redox+stimulus-responsive+processElectronic+supplementary+information+%28ESI%29+available%3A+Additional+1H+NMR+spectra%2C+ESI-MS+for+the+complexes%2C+determination+of+the+association+constants+and+theoretical+study.+See+DOI%3A+10.1039%2Fc7cc00600d&rft.au=Zhang%2C+Geng-Wu&rft.au=Shi%2C+Qiang&rft.au=Chen%2C+Chuan-Feng&rft.date=2017-02-23&rft.issn=1359-7345&rft.eissn=1364-548X&rft.volume=53&rft.issue=17&rft.spage=2582&rft.epage=2585&rft_id=info:doi/10.1039%2Fc7cc00600d&rft.externalDocID=c7cc00600d |
thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1359-7345&client=summon |
thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1359-7345&client=summon |
thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1359-7345&client=summon |