A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of esterElectronic supplementary information (ESI) available. See DOI: 10.1039/c6cy02187e

A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C 2 H 5 ) 3 H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. T...

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Main Authors Samal, Akshaya K, Zhu, Haibo, Harb, Moussab, Sangaru, Shiv Shankar, Anjum, Dalaver H, Hedhili, Mohamed N, Saih, Youssef, Basset, Jean-Marie
Format Journal Article
LanguageEnglish
Published 07.02.2017
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Abstract A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C 2 H 5 ) 3 H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol. A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts.
AbstractList A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts. The synthesis was performed by simply mixing the super hydride [LiB(C 2 H 5 ) 3 H], with a metal (Ru, Rh or Ir) salt and an organotin complex in tetrahydrofuran solvent without using any surfactant. This leads to the formation of monodispersed M-Sn (M = Ru, Rh or Ir) bimetallic nanoparticles (NPs). These bimetallic catalysts show high performances in the hydrogenolysis of ester to the corresponding alcohol. A versatile synthetic method was applied for the preparation of Sn containing bimetallic catalysts.
Author Harb, Moussab
Hedhili, Mohamed N
Samal, Akshaya K
Basset, Jean-Marie
Zhu, Haibo
Anjum, Dalaver H
Saih, Youssef
Sangaru, Shiv Shankar
AuthorAffiliation King Abdullah University of Science and Technology
Imaging and Characterization Lab
KAUST Catalysis Center
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Title A general approach for the synthesis of bimetallic M-Sn (M = Ru, Rh and Ir) catalysts for efficient hydrogenolysis of esterElectronic supplementary information (ESI) available. See DOI: 10.1039/c6cy02187e
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