Halogen bonding influences perylene-core twists in non-core substituted perylene tetraestersElectronic supplementary information (ESI) available: See for experimental methods including synthesis of PTE, methods for obtaining single crystals, Hirshfeld analysis, and binding studies. CCDC 1468082-1468085. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6ce00929h

Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects...

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Main Authors Wojciechowski, Jonathan P, Martin, Adam D, Bhadbhade, Mohan, Webb, James E. A, Thordarson, Pall
Format Journal Article
Published 14.06.2016
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Abstract Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects its spectral properties. We show this interaction exists in both the solution and solid state through spectroscopy studies and single crystal analysis. C&z.dbd;O X halogen bonding of perylene tetraesters causes perylene-core torsion which affects their spectral properties.
AbstractList Halogen bonding has emerged as a popular synthon in supramolecular architectures. Its effects on supramolecular perylene systems however have been under investigated. We report X O halogen bonding of perylene-3,4,9,10-tetracarboxylic tetra esters. This templates a twisted perylene core which affects its spectral properties. We show this interaction exists in both the solution and solid state through spectroscopy studies and single crystal analysis. C&z.dbd;O X halogen bonding of perylene tetraesters causes perylene-core torsion which affects their spectral properties.
Author Martin, Adam D
Thordarson, Pall
Bhadbhade, Mohan
Webb, James E. A
Wojciechowski, Jonathan P
AuthorAffiliation The Australian Centre for Nanomedicine and the ARC Centre of Excellence for Convergent Bio-Nano Science and Technology
Mark Wainwright Analytical Centre
The University of New South Wales
School of Chemistry
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  givenname: Pall
  surname: Thordarson
  fullname: Thordarson, Pall
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For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c6ce00929h
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Title Halogen bonding influences perylene-core twists in non-core substituted perylene tetraestersElectronic supplementary information (ESI) available: See for experimental methods including synthesis of PTE, methods for obtaining single crystals, Hirshfeld analysis, and binding studies. CCDC 1468082-1468085. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6ce00929h
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