Cascade reactions of nitrogen-substituted isocyanates: a new tool in heterocyclic chemistryElectronic supplementary information (ESI) available: Complete experimental procedures, characterization data, and NMR spectra. CCDC 1420522 and 1420523. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03197d

• Main Authors: Vincent-Rocan, Jean-François, Ivanovich, Ryan A, Clavette, Christian, Leckett, Kyle, Bejjani, Julien, Beauchemin, André M
• Format: Journal Article
• Published: 14.12.2015

In contrast to normal C -substituted isocyanates, nitrogen-substituted isocyanates ( N -isocyanates) are rare. Their high reactivity and amphoteric/ambident nature has prevented the scientific community from exploiting their synthetic potential. Recently, we have developed an in situ formation appro...