Branched isomeric 1,2,3-triazolium-based ionic liquids: new insight into structure-property relationshipsElectronic supplementary information (ESI) available. See DOI: 10.1039/c5cp04756k

A series of four isomeric 1,2,3-triazolium-based ionic liquids (ILs) with vary degree of branching were synthesized and characterized to investigate the effect of ion branching on thermal and physical properties of the resulting IL. It was found that increased branching led to a higher ionicity and...

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Main Authors Lartey, M, Meyer-Ilse, J, Watkins, J. D, Roth, E. A, Bowser, S, Kusuma, V. A, Damodaran, K, Zhou, X, Haranczyk, M, Albenze, E, Luebke, D. R, Hopkinson, D, Kortright, J. B, Nulwala, H. B
Format Journal Article
LanguageEnglish
Published 05.11.2015
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Abstract A series of four isomeric 1,2,3-triazolium-based ionic liquids (ILs) with vary degree of branching were synthesized and characterized to investigate the effect of ion branching on thermal and physical properties of the resulting IL. It was found that increased branching led to a higher ionicity and higher viscosity. The thermal properties were also altered significantly and spectral changes in the near edge X-ray absorption fine structure (NEXAFS) spectra show that branching affects intermolecular interaction. While the ionicity and viscosity varying linearly with branching, the MDSC and NEXAFS measurements show that the cation shape has a stronger influence on the melting temperature and absorptive properties than the number of branched alkyl substituents. Series of branched isomeric 1,2,3-triazolium-based ionic liquids (ILs) were synthesized and characterized. The effect of branching on thermal and physical properties is investigated.
AbstractList A series of four isomeric 1,2,3-triazolium-based ionic liquids (ILs) with vary degree of branching were synthesized and characterized to investigate the effect of ion branching on thermal and physical properties of the resulting IL. It was found that increased branching led to a higher ionicity and higher viscosity. The thermal properties were also altered significantly and spectral changes in the near edge X-ray absorption fine structure (NEXAFS) spectra show that branching affects intermolecular interaction. While the ionicity and viscosity varying linearly with branching, the MDSC and NEXAFS measurements show that the cation shape has a stronger influence on the melting temperature and absorptive properties than the number of branched alkyl substituents. Series of branched isomeric 1,2,3-triazolium-based ionic liquids (ILs) were synthesized and characterized. The effect of branching on thermal and physical properties is investigated.
Author Albenze, E
Kortright, J. B
Bowser, S
Luebke, D. R
Zhou, X
Lartey, M
Watkins, J. D
Roth, E. A
Hopkinson, D
Meyer-Ilse, J
Damodaran, K
Haranczyk, M
Nulwala, H. B
Kusuma, V. A
AuthorAffiliation Department of Chemistry
Carnegie Mellon University
Liquid Ion Solutions
Chevron Science Center
University of Pittsburgh
Computational Research Division
Lawrence Berkeley National Laboratory
Materials Science Division
National Energy Technology Laboratory
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  publication-title: Organic Chemistry for Advanced Students
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  publication-title: CRC Handbook of Chemistry and Physics
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  publication-title: Principles of Polymerization
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