A novel in situ preparation method for nanostructured α-Fe2O3 films from electrodeposited Fe films for efficient photoelectrocatalytic water splitting and the degradation of organic pollutantsElectronic supplementary information (ESI) available. See DOI: 10.1039/c4ta06017b
A novel method has been developed for the preparation of nanostructured haematite (α-Fe 2 O 3 ) films for use in photoelectrocatalytic (PEC) water splitting and the degradation of organic pollutants. The method has two stages, the electrodeposition of Fe films in alkalescent aqueous electrolyte with...
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Format | Journal Article |
Language | English |
Published |
10.02.2015
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Abstract | A novel method has been developed for the preparation of nanostructured haematite (α-Fe
2
O
3
) films for use in photoelectrocatalytic (PEC) water splitting and the degradation of organic pollutants. The method has two stages, the electrodeposition of Fe films in alkalescent aqueous electrolyte with ferrous sulphate and ammonia, and the
in situ
thermal oxidation of the Fe films to α-Fe
2
O
3
. The thickness and crystallinity of the α-Fe
2
O
3
films can be precisely controlled by adjusting the duration and the annealing conditions of the electrodeposition, respectively, avoiding the microstructural defects arising from the traditional electrodeposition of FeOOH films and the unwanted phases of FeO and Fe
3
O
4
produced by thermal oxidation of Fe foils. This facilitates the generation, transportation and collection of photogenerated charges on the α-Fe
2
O
3
film. The optimized α-Fe
2
O
3
film, obtained from a Fe film deposited for 30 s and then annealed at 500 °C for 2 h, showed a stable PEC water oxidation current around 1.35 mA cm
−2
at 1.23 V
vs.
a reversible hydrogen electrode (RHE) under AM 1.5 irradiation. This was the highest current so far obtained using undoped α-Fe
2
O
3
films produced by electrodeposition. When further coated with a cobalt phosphate (Co-Pi) co-catalyst, the optimized Co-Pi/α-Fe
2
O
3
photoanode showed an incident photon-to-current conversion efficiency (IPCE) above 18% at 400 nm and a stable photocurrent of 1.89 mA cm
−2
. The α-Fe
2
O
3
film also showed excellent stability and degradation efficiency (rate constant 0.9372 h
−1
) in the PEC degradation of methylene blue (MB) in neutral aqueous solution under a positive bias potential.
Highly photoactive α-Fe
2
O
3
films prepared from novel electrodeposited Fe films were reported for PEC water splitting and organic pollutant degradation. |
---|---|
AbstractList | A novel method has been developed for the preparation of nanostructured haematite (α-Fe
2
O
3
) films for use in photoelectrocatalytic (PEC) water splitting and the degradation of organic pollutants. The method has two stages, the electrodeposition of Fe films in alkalescent aqueous electrolyte with ferrous sulphate and ammonia, and the
in situ
thermal oxidation of the Fe films to α-Fe
2
O
3
. The thickness and crystallinity of the α-Fe
2
O
3
films can be precisely controlled by adjusting the duration and the annealing conditions of the electrodeposition, respectively, avoiding the microstructural defects arising from the traditional electrodeposition of FeOOH films and the unwanted phases of FeO and Fe
3
O
4
produced by thermal oxidation of Fe foils. This facilitates the generation, transportation and collection of photogenerated charges on the α-Fe
2
O
3
film. The optimized α-Fe
2
O
3
film, obtained from a Fe film deposited for 30 s and then annealed at 500 °C for 2 h, showed a stable PEC water oxidation current around 1.35 mA cm
−2
at 1.23 V
vs.
a reversible hydrogen electrode (RHE) under AM 1.5 irradiation. This was the highest current so far obtained using undoped α-Fe
2
O
3
films produced by electrodeposition. When further coated with a cobalt phosphate (Co-Pi) co-catalyst, the optimized Co-Pi/α-Fe
2
O
3
photoanode showed an incident photon-to-current conversion efficiency (IPCE) above 18% at 400 nm and a stable photocurrent of 1.89 mA cm
−2
. The α-Fe
2
O
3
film also showed excellent stability and degradation efficiency (rate constant 0.9372 h
−1
) in the PEC degradation of methylene blue (MB) in neutral aqueous solution under a positive bias potential.
Highly photoactive α-Fe
2
O
3
films prepared from novel electrodeposited Fe films were reported for PEC water splitting and organic pollutant degradation. |
Author | Zhou, Baoxue Huang, Ke Bai, Jing Li, Jinhua Xia, Ligang Li, Xuejin Zeng, Qingyi |
AuthorAffiliation | School of Environmental Science and Engineering Shanghai Jiao Tong University |
AuthorAffiliation_xml | – name: Shanghai Jiao Tong University – name: School of Environmental Science and Engineering |
Author_xml | – sequence: 1 givenname: Qingyi surname: Zeng fullname: Zeng, Qingyi – sequence: 2 givenname: Jing surname: Bai fullname: Bai, Jing – sequence: 3 givenname: Jinhua surname: Li fullname: Li, Jinhua – sequence: 4 givenname: Ligang surname: Xia fullname: Xia, Ligang – sequence: 5 givenname: Ke surname: Huang fullname: Huang, Ke – sequence: 6 givenname: Xuejin surname: Li fullname: Li, Xuejin – sequence: 7 givenname: Baoxue surname: Zhou fullname: Zhou, Baoxue |
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DOI | 10.1039/c4ta06017b |
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Snippet | A novel method has been developed for the preparation of nanostructured haematite (α-Fe
2
O
3
) films for use in photoelectrocatalytic (PEC) water splitting... |
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Title | A novel in situ preparation method for nanostructured α-Fe2O3 films from electrodeposited Fe films for efficient photoelectrocatalytic water splitting and the degradation of organic pollutantsElectronic supplementary information (ESI) available. See DOI: 10.1039/c4ta06017b |
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