Denovo asymmetric synthesis of the mezzettiaside family of natural products via the iterative use of a dual B-/Pd-catalyzed glycosylationElectronic supplementary information (ESI) available: Experimental procedures, 1H and 13C NMR spectra and correlation studies. See DOI: 10.0000/c4sc00593g

• Main Authors: Bajaj, Sumit O, Sharif, Ehesan U, Akhmedov, Novruz G, O'Doherty, George A
• Format: Journal Article
• Language: English
• Published: 07.05.2014

The first synthesis of any and all members of the mezzettiaside family of natural products has been achieved. The reported synthesis features the iterative use of the Taylor catalyst in a dual nucleophilic boron/electrophilic palladium catalyzed regioselective glycosylation. In addition, the de novo...