Molecular iodine-mediated reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts: an easy route to naphthyl ketones and iodo-substituted isochromenesElectronic supplementary information (ESI) available: Detailed experimental procedures and the 1H and 13C NMR spectra for relevant compounds. CCDC 972525, 978566, 973915 and 1009697. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4ob00938j

The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I 2 , naphthyl ketone derivatives are produced, whereas in the presence of I 2 /K 3 PO 4 , iodo-substituted isochromene derivatives are produced. The iodine mediated reaction o...

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Bibliographic Details
Main Authors Janreddy, Donala, Kavala, Veerababurao, Kotipalli, Trimurtulu, Rajawinslin, R. R, Kuo, Chun-Wei, Huang, Wen-Chang, Yao, Ching-Fa
Format Journal Article
LanguageEnglish
Published 01.10.2014
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Summary:The molecular iodine-promoted reaction of 2-(2-phenylethynyl)-Morita-Baylis-Hillman adducts is reported. In the presence of I 2 , naphthyl ketone derivatives are produced, whereas in the presence of I 2 /K 3 PO 4 , iodo-substituted isochromene derivatives are produced. The iodine mediated reaction of 2-(2-phenylethynyl)-MBH gives corresponding naphthyl ketones and iodo-substituted isochromenes.
Bibliography:13
Electronic supplementary information (ESI) available: Detailed experimental procedures and the
10.1039/c4ob00938j
972525
973915
,
1
For ESI and crystallographic data in CIF or other electronic format see DOI
1009697
C NMR spectra for relevant compounds. CCDC
and
H and
978566
ISSN:1477-0520
1477-0539
DOI:10.1039/c4ob00938j