The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} coreElectronic supplementary information (ESI) available: Experimental details, magnetic data and computational details and information. CCDC 1032631. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc08811e
We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru III 2 Dy III 2 (OMe) 2 (O 2 CPh) 4 (mdea) 2 (NO 3 ) 2 ] displays a butterfly type core, with an anisotropy barrier of 10.7 cm −1 . Ab initio and DFT calculations provide insight into...
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| Main Authors | , , , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
22.01.2015
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| Online Access | Get full text |
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| Abstract | We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru
III
2
Dy
III
2
(OMe)
2
(O
2
CPh)
4
(mdea)
2
(NO
3
)
2
] displays a butterfly type core, with an anisotropy barrier of 10.7 cm
−1
.
Ab initio
and DFT calculations provide insight into the observed magnetic behaviour.
The first 4d-4f single-molecule magnet of formula [Ru
III
2
Dy
III
2
(OMe)
2
(O
2
CPh)
4
(mdea)
2
(NO
3
)
2
] shows an anisotropy barrier
U
eff
of 11 cm
−1
. |
|---|---|
| AbstractList | We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru
III
2
Dy
III
2
(OMe)
2
(O
2
CPh)
4
(mdea)
2
(NO
3
)
2
] displays a butterfly type core, with an anisotropy barrier of 10.7 cm
−1
.
Ab initio
and DFT calculations provide insight into the observed magnetic behaviour.
The first 4d-4f single-molecule magnet of formula [Ru
III
2
Dy
III
2
(OMe)
2
(O
2
CPh)
4
(mdea)
2
(NO
3
)
2
] shows an anisotropy barrier
U
eff
of 11 cm
−1
. |
| Author | Murray, Keith S Langley, Stuart K Moubaraki, Boujemaa Chibotaru, Liviu F Vieru, Veacheslav Wielechowski, Daniel P Chilton, Nicholas F |
| AuthorAffiliation | The University of Manchester Monash University Theory of Nanomaterials Group and INPAC - Institute of Nanoscale Physics and Chemistry Katholieke Universiteit Leuven School of Chemistry |
| AuthorAffiliation_xml | – name: Katholieke Universiteit Leuven – name: Monash University – name: Theory of Nanomaterials Group and INPAC - Institute of Nanoscale Physics and Chemistry – name: The University of Manchester – name: School of Chemistry |
| Author_xml | – sequence: 1 givenname: Stuart K surname: Langley fullname: Langley, Stuart K – sequence: 2 givenname: Daniel P surname: Wielechowski fullname: Wielechowski, Daniel P – sequence: 3 givenname: Veacheslav surname: Vieru fullname: Vieru, Veacheslav – sequence: 4 givenname: Nicholas F surname: Chilton fullname: Chilton, Nicholas F – sequence: 5 givenname: Boujemaa surname: Moubaraki fullname: Moubaraki, Boujemaa – sequence: 6 givenname: Liviu F surname: Chibotaru fullname: Chibotaru, Liviu F – sequence: 7 givenname: Keith S surname: Murray fullname: Murray, Keith S |
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| ContentType | Journal Article |
| DOI | 10.1039/c4cc08811e |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI Electronic supplementary information (ESI) available: Experimental details, magnetic data and computational details and information. CCDC 1032631 10.1039/c4cc08811e |
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| References_xml | – doi: Neese Becker Wennmohs Ganiouchine Petrenko – volume-title: Computational Modelling of the Magnetic Properties of Lanthanide Compounds publication-title: Lanthanides and Actinides in Molecular Magnetism doi: Ungur Chibotaru – issn: 1986 end-page: 155 publication-title: Applied Quantum Chemistry doi: Yamaguchi Takahara Fueno Smith |
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| Snippet | We report the synthesis, structure and magnetic properties of the first 4d-4f single-molecule magnet. The complex [Ru
III
2
Dy
III
2
(OMe)
2
(O
2
CPh)
4
(mdea)... |
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| Title | The first 4d/4f single-molecule magnet containing a {RuIII2DyIII2} coreElectronic supplementary information (ESI) available: Experimental details, magnetic data and computational details and information. CCDC 1032631. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc08811e |
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