Flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/triethylamineElectronic supplementary information (ESI) available. See DOI: 10.1039/c4cc05216a

An efficient and practical catalytic method for the aerobic oxidative transformation of sulfides into sulfoxides, and thiols into disulfides with formic acid/TEA in the presence of a new, readily available, and stable flavin catalyst 5d is described. An efficient and practical method for flavin-cata...

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Main Authors Murahashi, Shun-Ichi, Zhang, Dazhi, Iida, Hiroki, Miyawaki, Toshio, Uenaka, Masaaki, Murano, Kenji, Meguro, Kanji
Format Journal Article
LanguageEnglish
Published 07.08.2014
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Abstract An efficient and practical catalytic method for the aerobic oxidative transformation of sulfides into sulfoxides, and thiols into disulfides with formic acid/TEA in the presence of a new, readily available, and stable flavin catalyst 5d is described. An efficient and practical method for flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/TEA is described.
AbstractList An efficient and practical catalytic method for the aerobic oxidative transformation of sulfides into sulfoxides, and thiols into disulfides with formic acid/TEA in the presence of a new, readily available, and stable flavin catalyst 5d is described. An efficient and practical method for flavin-catalyzed aerobic oxidation of sulfides and thiols with formic acid/TEA is described.
Author Murahashi, Shun-Ichi
Uenaka, Masaaki
Zhang, Dazhi
Iida, Hiroki
Meguro, Kanji
Murano, Kenji
Miyawaki, Toshio
AuthorAffiliation Hamari Chemicals Ltd
Department of Chemistry
Department of Molecular Design and Engineering
CT Laboratory
Okayama University of Science, Ridai-cho
Graduate School of Engineering
Nagoya University
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– name: Okayama University of Science, Ridai-cho
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– name: Nagoya University
– name: Hamari Chemicals Ltd
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  givenname: Shun-Ichi
  surname: Murahashi
  fullname: Murahashi, Shun-Ichi
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  givenname: Dazhi
  surname: Zhang
  fullname: Zhang, Dazhi
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  givenname: Hiroki
  surname: Iida
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  givenname: Toshio
  surname: Miyawaki
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  givenname: Masaaki
  surname: Uenaka
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  givenname: Kenji
  surname: Murano
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  givenname: Kanji
  surname: Meguro
  fullname: Meguro, Kanji
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Electronic supplementary information (ESI) available. See DOI
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References_xml – issn: 2007
  end-page: 77
  publication-title: Modern Biooxidation
  doi: Fraajije Janseen
– issn: 2010
  end-page: 277
  publication-title: Modern Oxidation Methods
  doi: Bäckvall
– issn: 2000
  publication-title: Biomimetic Oxidations Catalyzed by Transition Metal Complexes
  doi: Meunier
– issn: 1991
  publication-title: Chemistry and Biochemistry of Flavoenzymes
  doi: Müller
– issn: 1982
  end-page: 301
  publication-title: Flavins and Flavoproteins
  doi: Ballou
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