Efficient optical resolution of water-soluble self-assembled tetrahedral M4L6 cages with 1,1′-bi-2-naphtholElectronic supplementary information (ESI) available: Supplemental figures and schemes, experimental details and characterization. See DOI: 10.1039/c4cc04145c

In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe 4 L 6 ] 4− was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by ( R )-/( S )-1,1′-bi-2-naphthol. The enantiomeric excess of the resolved Fe( ii ) cage was 99%. Self-assembled tetrahedral M 4 L 6 cages were succes...

Full description

Saved in:
Bibliographic Details
Main Authors Wan, Shigang, Lin, Li-Rong, Zeng, Lili, Lin, Yiji, Zhang, Hui
Format Journal Article
LanguageEnglish
Published 11.11.2014
Online AccessGet full text

Cover

More Information
Summary:In this paper, a water-soluble racemic self-assembled tetrahedral cage [Fe 4 L 6 ] 4− was successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by ( R )-/( S )-1,1′-bi-2-naphthol. The enantiomeric excess of the resolved Fe( ii ) cage was 99%. Self-assembled tetrahedral M 4 L 6 cages were successfully resolved into their ΔΔΔΔ and ΛΛΛΛ enantiomers by ( R )-/( S )-1,1′-bi-2-naphthol.
Bibliography:10.1039/c4cc04145c
Electronic supplementary information (ESI) available: Supplemental figures and schemes, experimental details and characterization. See DOI
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc04145c