Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactionsElectronic supplementary information (ESI) available: Full experimental details. See DOI: 10.1039/c3py21104e

Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combin...

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Main Authors McEwan, Kayleigh A, Slavin, Stacy, Tunnah, Edward, Haddleton, David M
Format Journal Article
LanguageEnglish
Published 19.03.2013
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Abstract Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials. Poly(glycidyl methacrylate) has been used for the functionalised by CCTP and a combination of epoxide ring-opening, thiol-Michael addition and epoxide ring-opening with commercial amines and thiols.
AbstractList Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain epoxide groups. Epoxide ring-opening and a combination of thiol-Michael addition and epoxide ring-opening has been used for the post-functionalisation with amines and thiols to prepare a range of functional materials. Poly(glycidyl methacrylate) has been used for the functionalised by CCTP and a combination of epoxide ring-opening, thiol-Michael addition and epoxide ring-opening with commercial amines and thiols.
Author McEwan, Kayleigh A
Tunnah, Edward
Slavin, Stacy
Haddleton, David M
AuthorAffiliation Department of Chemistry
University of Warwick
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  givenname: David M
  surname: Haddleton
  fullname: Haddleton, David M
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Electronic supplementary information (ESI) available: Full experimental details. See DOI
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  publication-title: Organic Chemistry
  doi: Clayden Greeves Warren Wothers
– issn: 2012
  end-page: p 249-275
  publication-title: Polymer Science: a Comprehensive Reference
  doi: Slavin McEwan Haddleton
– issn: , 1952
  volume-title: Chemical Products
  publication-title: GB Patent
  doi: Dupont de Numours
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Snippet Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two...
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