Size-selective hydrogenation at the subnanometer scale over platinum nanoparticles encapsulated in silicalite-1 single crystal hollow shellsElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc48648f

Highly controlled "ship-in-a-bottle" platinum nanoparticles in silicalite-1 hollow single crystals have been prepared. This catalyst is highly active for toluene hydrogenation but shows no activity for the hydrogenation of 1,3,5-trimethylbenzene. A new method enables preparing a single par...

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Main Authors Li, Shiwen, Boucheron, Tommy, Tuel, Alain, Farrusseng, David, Meunier, Frederic
Format Journal Article
LanguageEnglish
Published 23.01.2014
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Abstract Highly controlled "ship-in-a-bottle" platinum nanoparticles in silicalite-1 hollow single crystals have been prepared. This catalyst is highly active for toluene hydrogenation but shows no activity for the hydrogenation of 1,3,5-trimethylbenzene. A new method enables preparing a single particle of platinum encapsulated in a hollow single crystal of a microporous silicalite-1. The sample was able to hydrogenate toluene, but not mesitylene, proving that the level of defects in the structure was negligible.
AbstractList Highly controlled "ship-in-a-bottle" platinum nanoparticles in silicalite-1 hollow single crystals have been prepared. This catalyst is highly active for toluene hydrogenation but shows no activity for the hydrogenation of 1,3,5-trimethylbenzene. A new method enables preparing a single particle of platinum encapsulated in a hollow single crystal of a microporous silicalite-1. The sample was able to hydrogenate toluene, but not mesitylene, proving that the level of defects in the structure was negligible.
Author Tuel, Alain
Li, Shiwen
Farrusseng, David
Boucheron, Tommy
Meunier, Frederic
AuthorAffiliation Université Lyon 1
Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON)
CNRS 2
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  givenname: Shiwen
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  givenname: David
  surname: Farrusseng
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– sequence: 5
  givenname: Frederic
  surname: Meunier
  fullname: Meunier, Frederic
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Snippet Highly controlled "ship-in-a-bottle" platinum nanoparticles in silicalite-1 hollow single crystals have been prepared. This catalyst is highly active for...
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Title Size-selective hydrogenation at the subnanometer scale over platinum nanoparticles encapsulated in silicalite-1 single crystal hollow shellsElectronic supplementary information (ESI) available. See DOI: 10.1039/c3cc48648f
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