Photocatalytic reduction of benzonitrile to benzylamine in aqueous suspensions of palladium-loaded titanium(iv) oxideElectronic supplementary information (ESI) available: Experimental procedure and Fig. S1. See: DOI: 10.1039/c3cc46439c
Benzonitrile (PhCN) was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium (Pd)-loaded titanium( iv ) oxide (TiO 2 ) photocatalyst in the presence of oxalic acid as a hole scavenger, although the reduction potential of PhCN is believed to be much higher than the potent...
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|---|---|
| Format | Journal Article |
| Language | English |
| Published |
29.10.2013
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| Online Access | Get full text |
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| Abstract | Benzonitrile (PhCN) was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium (Pd)-loaded titanium(
iv
) oxide (TiO
2
) photocatalyst in the presence of oxalic acid as a hole scavenger, although the reduction potential of PhCN is believed to be much higher than the potential of the conduction band (CB) of TiO
2
, indicating that a Pd co-catalyst strongly contributes to PhCN reduction and that the applicability of photocatalytic reduction is not limited by the CB position of semiconductor photocatalysts.
Benzonitrile was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium-loaded titanium(
iv
) oxide photocatalyst in the presence of oxalic acid as a hole scavenger. |
|---|---|
| AbstractList | Benzonitrile (PhCN) was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium (Pd)-loaded titanium(
iv
) oxide (TiO
2
) photocatalyst in the presence of oxalic acid as a hole scavenger, although the reduction potential of PhCN is believed to be much higher than the potential of the conduction band (CB) of TiO
2
, indicating that a Pd co-catalyst strongly contributes to PhCN reduction and that the applicability of photocatalytic reduction is not limited by the CB position of semiconductor photocatalysts.
Benzonitrile was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium-loaded titanium(
iv
) oxide photocatalyst in the presence of oxalic acid as a hole scavenger. |
| Author | Imamura, Kazuya Kominami, Hiroshi Yoshikawa, Takayuki Nakanishi, Kousuke Hashimoto, Keiji |
| AuthorAffiliation | Department of Applied Chemistry Kinki University Faculty of Science and Engineering |
| AuthorAffiliation_xml | – name: Faculty of Science and Engineering – name: Department of Applied Chemistry – name: Kinki University |
| Author_xml | – sequence: 1 givenname: Kazuya surname: Imamura fullname: Imamura, Kazuya – sequence: 2 givenname: Takayuki surname: Yoshikawa fullname: Yoshikawa, Takayuki – sequence: 3 givenname: Kousuke surname: Nakanishi fullname: Nakanishi, Kousuke – sequence: 4 givenname: Keiji surname: Hashimoto fullname: Hashimoto, Keiji – sequence: 5 givenname: Hiroshi surname: Kominami fullname: Kominami, Hiroshi |
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| DOI | 10.1039/c3cc46439c |
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| Notes | Electronic supplementary information (ESI) available: Experimental procedure and Fig. S1. See: DOI 10.1039/c3cc46439c |
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| References_xml | – issn: 1965 publication-title: Catalytic hydrogenation: Techniques and application in organic synthesis doi: Augustine – issn: 1998 publication-title: Green Chemistry: Theory and Practice doi: Anastas Warner – issn: 2001 publication-title: Handbook of Heterogeneous Catalytic Hydrogenation for Organic Synthesis doi: Nishimura |
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| Snippet | Benzonitrile (PhCN) was successfully reduced to benzyl amine in acidic aqueous suspensions of a palladium (Pd)-loaded titanium(
iv
) oxide (TiO
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| Title | Photocatalytic reduction of benzonitrile to benzylamine in aqueous suspensions of palladium-loaded titanium(iv) oxideElectronic supplementary information (ESI) available: Experimental procedure and Fig. S1. See: DOI: 10.1039/c3cc46439c |
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