Phosphaalkene vs. phosphinidene: the nature of the P-C bond in carbonyl-decorated carbene → PPh adductsElectronic supplementary information (ESI) available: General experimental information, synthetic procedures, computational data, and additional figures. CCDC 946638-946640. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc45134h

Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses. Novel phosphaalk...

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Main Authors Rodrigues, Roberta R, Dorsey, Christopher L, Arceneaux, Chelsee A, Hudnall, Todd W
Format Journal Article
Published 28.11.2013
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Summary:Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses. Novel phosphaalkenes can be prepared when PPh forms adducts with strongly π-acidic diamidocarbenes that favor the formation of π-bonds.
Bibliography:946638-946640
For ESI and crystallographic data in CIF or other electronic format see DOI
10.1039/c3cc45134h
Electronic supplementary information (ESI) available: General experimental information, synthetic procedures, computational data, and additional figures. CCDC
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc45134h