One-dimensional alignment of strong Lewis acid sites in a porous coordination polymerElectronic supplementary information (ESI) available: Experimental procedures and characterization. CCDC 901070 and 901071. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c3cc43384f

A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinat...

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Main Authors Kajiwara, Takashi, Higuchi, Masakazu, Yuasa, Akihiro, Higashimura, Hideyuki, Kitagawa, Susumu
Format Journal Article
LanguageEnglish
Published 15.10.2013
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Abstract A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinated solvent. A new lanthanoid porous coordination polymer was synthesized and structurally characterized to have densely aligned one-dimensional Lewis acid sites.
AbstractList A new lanthanoid porous coordination polymer, La-BTTc (BTTc = benzene-1,3,5-tris(2-thiophene-5-carboxylate)), was synthesized and structurally characterized to have densely aligned one-dimensional open metal sites, which were found to act as strong Lewis acid sites after the removal of the coordinated solvent. A new lanthanoid porous coordination polymer was synthesized and structurally characterized to have densely aligned one-dimensional Lewis acid sites.
Author Higuchi, Masakazu
Kajiwara, Takashi
Kitagawa, Susumu
Higashimura, Hideyuki
Yuasa, Akihiro
AuthorAffiliation Kyoto University
Department of Synthetic Chemistry and Biological Chemistry
Graduate School of Engineering
Institute for Integrated Cell-Material Sciences (iCeMS)
Advanced Materials Research Laboratory
Sumitomo Chemical Co., Ltd
AuthorAffiliation_xml – name: Advanced Materials Research Laboratory
– name: Sumitomo Chemical Co., Ltd
– name: Graduate School of Engineering
– name: Kyoto University
– name: Institute for Integrated Cell-Material Sciences (iCeMS)
– name: Department of Synthetic Chemistry and Biological Chemistry
Author_xml – sequence: 1
  givenname: Takashi
  surname: Kajiwara
  fullname: Kajiwara, Takashi
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  givenname: Masakazu
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  fullname: Higuchi, Masakazu
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  givenname: Akihiro
  surname: Yuasa
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  givenname: Hideyuki
  surname: Higashimura
  fullname: Higashimura, Hideyuki
– sequence: 5
  givenname: Susumu
  surname: Kitagawa
  fullname: Kitagawa, Susumu
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