Chirality induction and amplification in methylene blue H-aggregates viad- and l-phenylalanine pre-adsorbed on the tungsten oxide nanocolloid surfaceElectronic supplementary information (ESI) available: Supporting UV/Vis and CD spectra in the Phe, WO3, MB-l-Phe binary, MB-WO3 binary, l-Phe-WO3 binary, reverse addition order MB-Phe-WO3 ternary system. See DOI: 10.1039/c2nj40415j
In the methylene blue (MB)-phenylalanine (Phe)-tungsten( vi ) oxide (WO 3 ) colloid ternary aqueous solution, the MB H-aggregates, which could recognize the chirality of d - and l -Phe, were formed and investigated by means of UV-Vis absorption and CD spectroscopy. These results demonstrate a chiral...
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| Main Authors | , , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
15.10.2012
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| Online Access | Get full text |
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| Abstract | In the methylene blue (MB)-phenylalanine (Phe)-tungsten(
vi
) oxide (WO
3
) colloid ternary aqueous solution, the MB H-aggregates, which could recognize the chirality of
d
- and
l
-Phe, were formed and investigated by means of UV-Vis absorption and CD spectroscopy. These results demonstrate a chirality transfer and amplification from only the pre-adsorbed Phe molecules to MB aggregates formed on the WO
3
colloid surface
via
non-covalent interactions.
In the MB-Phe-WO
3
ternary aqueous solution, the MB H-aggregates, which could recognize the chirality of
d
- and
l
-Phe, were investigated. |
|---|---|
| AbstractList | In the methylene blue (MB)-phenylalanine (Phe)-tungsten(
vi
) oxide (WO
3
) colloid ternary aqueous solution, the MB H-aggregates, which could recognize the chirality of
d
- and
l
-Phe, were formed and investigated by means of UV-Vis absorption and CD spectroscopy. These results demonstrate a chirality transfer and amplification from only the pre-adsorbed Phe molecules to MB aggregates formed on the WO
3
colloid surface
via
non-covalent interactions.
In the MB-Phe-WO
3
ternary aqueous solution, the MB H-aggregates, which could recognize the chirality of
d
- and
l
-Phe, were investigated. |
| Author | Tsukahara, Satoshi Adachi, Kenta Takechi, Hideaki Watarai, Hitoshi Yamazaki, Suzuko Tanaka, Shohei |
| AuthorAffiliation | Department of Chemistry Institute for NanoScience Design Department of Environmental Science & Engineering Yamaguchi University Graduate School of Science & Engineering Osaka University Graduate School of Science |
| AuthorAffiliation_xml | – name: Yamaguchi University – name: Department of Chemistry – name: Graduate School of Science – name: Osaka University – name: Department of Environmental Science & Engineering – name: Graduate School of Science & Engineering – name: Institute for NanoScience Design |
| Author_xml | – sequence: 1 givenname: Kenta surname: Adachi fullname: Adachi, Kenta – sequence: 2 givenname: Shohei surname: Tanaka fullname: Tanaka, Shohei – sequence: 3 givenname: Suzuko surname: Yamazaki fullname: Yamazaki, Suzuko – sequence: 4 givenname: Hideaki surname: Takechi fullname: Takechi, Hideaki – sequence: 5 givenname: Satoshi surname: Tsukahara fullname: Tsukahara, Satoshi – sequence: 6 givenname: Hitoshi surname: Watarai fullname: Watarai, Hitoshi |
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| ContentType | Journal Article |
| DOI | 10.1039/c2nj40415j |
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| Notes | 3 Phe-WO Electronic supplementary information (ESI) available: Supporting UV/Vis and CD spectra in the Phe, WO ternary system. See DOI binary binary, reverse addition order MB-Phe-WO Phe binary, MB-WO MB- 10.1039/c2nj40415j l |
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| References_xml | – issn: 2001 publication-title: Chemical Properties of Material Surfaces doi: Kosmulski – issn: 1983 publication-title: Exciton Coupling in Organic Chemistry. Circular Dichroic Spectroscopy doi: Harada Nakanishi – issn: 1991 publication-title: The Sigma-Aldrich Handbook of Stains, Dyes and Indicators doi: Green – issn: 2011 publication-title: Amino Acids, Peptides and Proteins in Organic Chemistry, Analysis and Function of Amino Acids and Peptides |
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| Snippet | In the methylene blue (MB)-phenylalanine (Phe)-tungsten(
vi
) oxide (WO
3
) colloid ternary aqueous solution, the MB H-aggregates, which could recognize the... |
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| Title | Chirality induction and amplification in methylene blue H-aggregates viad- and l-phenylalanine pre-adsorbed on the tungsten oxide nanocolloid surfaceElectronic supplementary information (ESI) available: Supporting UV/Vis and CD spectra in the Phe, WO3, MB-l-Phe binary, MB-WO3 binary, l-Phe-WO3 binary, reverse addition order MB-Phe-WO3 ternary system. See DOI: 10.1039/c2nj40415j |
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