First examples of two ferromagnetic end-to-end cyanate bridged 1D linear coordination polymers of nickel(ii) containing an unsymmetrical diamineElectronic supplementary information (ESI) available: Synthetic details, materials and magnetic susceptibility measurements, crystallographic data including bond distances and angles (Tables S1 and S2) of compounds 1 and 2, and structures (Fig. S1-S4) of 1 and 2. CCDC 867595 (1) and 867596 (2). For ESI and crystallographic data in CIF or other electronic

Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges. Two new end-to-end cyanate brid...

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Main Authors Choubey, Somnath, Bhar, Kishalay, Chattopadhyay, Soumi, Hazra, Arpan, Maji, Tapas Kumar, Ribas, Joan, Ghosh, Barindra Kumar
Format Journal Article
LanguageEnglish
Published 11.09.2012
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Abstract Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges. Two new end-to-end cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling..
AbstractList Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges. Two new end-to-end cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling..
Author Choubey, Somnath
Chattopadhyay, Soumi
Ghosh, Barindra Kumar
Hazra, Arpan
Bhar, Kishalay
Maji, Tapas Kumar
Ribas, Joan
AuthorAffiliation Chemistry and Physics of Materials Unit
Department of Chemistry
The University of Burdwan
Universitat de Barcelona
Departament de Química Inorgánica
Jawaharlal Nehru Centre for Advanced Scientific Research
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  publication-title: Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
  doi: Liu Xie Liu
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  publication-title: SAINT Plus, Data Reduction and Correction Program, v. 6.01
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  publication-title: Molecular Magnetism
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  publication-title: SADABS v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program
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  publication-title: Magnetism: Molecules to Materials V
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Title First examples of two ferromagnetic end-to-end cyanate bridged 1D linear coordination polymers of nickel(ii) containing an unsymmetrical diamineElectronic supplementary information (ESI) available: Synthetic details, materials and magnetic susceptibility measurements, crystallographic data including bond distances and angles (Tables S1 and S2) of compounds 1 and 2, and structures (Fig. S1-S4) of 1 and 2. CCDC 867595 (1) and 867596 (2). For ESI and crystallographic data in CIF or other electronic
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