First examples of two ferromagnetic end-to-end cyanate bridged 1D linear coordination polymers of nickel(ii) containing an unsymmetrical diamineElectronic supplementary information (ESI) available: Synthetic details, materials and magnetic susceptibility measurements, crystallographic data including bond distances and angles (Tables S1 and S2) of compounds 1 and 2, and structures (Fig. S1-S4) of 1 and 2. CCDC 867595 (1) and 867596 (2). For ESI and crystallographic data in CIF or other electronic

Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges. Two new end-to-end cyanate brid...

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Main Authors Choubey, Somnath, Bhar, Kishalay, Chattopadhyay, Soumi, Hazra, Arpan, Maji, Tapas Kumar, Ribas, Joan, Ghosh, Barindra Kumar
Format Journal Article
LanguageEnglish
Published 11.09.2012
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Summary:Two new end-to-end (EE) cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling in agreement with the reported theoretical model for linear EE bridges. Two new end-to-end cyanate bridged 1D coordination polymers of Ni II are isolated which contain linear (180°) Ni-N-C and Ni-O-C angles in Ni-NCO-Ni bridges and show ferromagnetic (F) coupling..
Bibliography:CCDC
Electronic supplementary information (ESI) available: Synthetic details, materials and magnetic susceptibility measurements, crystallographic data including bond distances and angles (Tables S1 and S2) of compounds
1
For ESI and crystallographic data in CIF or other electronic format see DOI
2
and structures (Fig. S1-S4) of
and
10.1039/c2dt30429e
(
867595
867596
ISSN:1477-9226
1477-9234
DOI:10.1039/c2dt30429e