Synthesis and characterization of a tris(2-hydroxyphenyl)methane-based cryptand and its triiron(iii) complexElectronic supplementary information (ESI) available: Synthesis, spectroscopic data, crystallographic data and cyclic voltammagrams. CCDC 866977-866978. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt30312d
Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. Metallation with iron( iii ) chloride results in a substantial conformational change of this ligand to give a trianionic triiron( iii ) complex. Ferric ca...
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| Main Authors | , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
15.06.2012
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| Online Access | Get full text |
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| Abstract | Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. Metallation with iron(
iii
) chloride results in a substantial conformational change of this ligand to give a trianionic triiron(
iii
) complex. Ferric cations line the periphery of the internal cavity with each adopting a square pyramidal N
3
Cl
2
coordination environment.
Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. |
|---|---|
| AbstractList | Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. Metallation with iron(
iii
) chloride results in a substantial conformational change of this ligand to give a trianionic triiron(
iii
) complex. Ferric cations line the periphery of the internal cavity with each adopting a square pyramidal N
3
Cl
2
coordination environment.
Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. |
| Author | Abboud, Khalil A Dumont, Matthieu F Murray, Leslie J Guillet, Gary L Sloane, Forrest T |
| AuthorAffiliation | Department of Chemistry University of Florida Center for Catalysis Department of Physics and National High Magnetic Field Laboratory |
| AuthorAffiliation_xml | – name: Department of Chemistry – name: Department of Physics and National High Magnetic Field Laboratory – name: Center for Catalysis – name: University of Florida |
| Author_xml | – sequence: 1 givenname: Gary L surname: Guillet fullname: Guillet, Gary L – sequence: 2 givenname: Forrest T surname: Sloane fullname: Sloane, Forrest T – sequence: 3 givenname: Matthieu F surname: Dumont fullname: Dumont, Matthieu F – sequence: 4 givenname: Khalil A surname: Abboud fullname: Abboud, Khalil A – sequence: 5 givenname: Leslie J surname: Murray fullname: Murray, Leslie J |
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| ContentType | Journal Article |
| DOI | 10.1039/c2dt30312d |
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| Notes | For ESI and crystallographic data in CIF or other electronic format see DOI 10.1039/c2dt30312d 866977-866978 Electronic supplementary information (ESI) available: Synthesis, spectroscopic data, crystallographic data and cyclic voltammagrams. CCDC |
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| Snippet | Reaction of tris(5-amino-2-ethoxy-3-isopropylphenyl)methane and pyridine-2,6-dicarbonyl-dichloride affords a multi-dentate cryptand in 48% yield. Metallation... |
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| Title | Synthesis and characterization of a tris(2-hydroxyphenyl)methane-based cryptand and its triiron(iii) complexElectronic supplementary information (ESI) available: Synthesis, spectroscopic data, crystallographic data and cyclic voltammagrams. CCDC 866977-866978. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c2dt30312d |
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