Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gasElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cp41690e
Non-basic hydrogen peroxide was found to be very easy to react with Cl 2 to produce singlet oxygen O 2 (a 1 Δ g ) ( i.e. the molecular oxygen in its first electronic excited state) when an H + absorbent such as C 5 H 5 N, CH 3 COONH 4 , HCOONH 4 or NH 4 F was added into H 2 O 2 aqueous solution, and...
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| Main Authors | , , , , |
|---|---|
| Format | Journal Article |
| Language | English |
| Published |
17.09.2012
|
| Online Access | Get full text |
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| Abstract | Non-basic hydrogen peroxide was found to be very easy to react with Cl
2
to produce singlet oxygen O
2
(a
1
Δ
g
) (
i.e.
the molecular oxygen in its first electronic excited state) when an H
+
absorbent such as C
5
H
5
N, CH
3
COONH
4
, HCOONH
4
or NH
4
F was added into H
2
O
2
aqueous solution, and the long concealed fact that molecular H
2
O
2
can react with Cl
2
to produce O
2
(a
1
Δ
g
) was then uncovered. It is only when an H
+
absorbent has provided a stronger base than H
2
O to absorb the H
+
produced during the reaction that O
2
(a
1
Δ
g
) can be produced.
The long concealed fact that molecular H
2
O
2
can react with Cl
2
to produce O
2
(a
1
Δ
g
) was uncovered by the addition of C
5
H
5
N, CH
3
COONH
4
, HCOONH
4
or NH
4
F into H
2
O
2
aqueous solution. |
|---|---|
| AbstractList | Non-basic hydrogen peroxide was found to be very easy to react with Cl
2
to produce singlet oxygen O
2
(a
1
Δ
g
) (
i.e.
the molecular oxygen in its first electronic excited state) when an H
+
absorbent such as C
5
H
5
N, CH
3
COONH
4
, HCOONH
4
or NH
4
F was added into H
2
O
2
aqueous solution, and the long concealed fact that molecular H
2
O
2
can react with Cl
2
to produce O
2
(a
1
Δ
g
) was then uncovered. It is only when an H
+
absorbent has provided a stronger base than H
2
O to absorb the H
+
produced during the reaction that O
2
(a
1
Δ
g
) can be produced.
The long concealed fact that molecular H
2
O
2
can react with Cl
2
to produce O
2
(a
1
Δ
g
) was uncovered by the addition of C
5
H
5
N, CH
3
COONH
4
, HCOONH
4
or NH
4
F into H
2
O
2
aqueous solution. |
| Author | Cui, Rongrong Yang, Heping Shi, Wenbo Deng, Liezheng Tian, Wenming |
| AuthorAffiliation | Chinese Academy of Sciences State Key Laboratory of Molecular Reaction Dynamics Dalian Institute of Chemical Physics |
| AuthorAffiliation_xml | – name: Dalian Institute of Chemical Physics – name: Chinese Academy of Sciences – name: State Key Laboratory of Molecular Reaction Dynamics |
| Author_xml | – sequence: 1 givenname: Wenming surname: Tian fullname: Tian, Wenming – sequence: 2 givenname: Wenbo surname: Shi fullname: Shi, Wenbo – sequence: 3 givenname: Heping surname: Yang fullname: Yang, Heping – sequence: 4 givenname: Rongrong surname: Cui fullname: Cui, Rongrong – sequence: 5 givenname: Liezheng surname: Deng fullname: Deng, Liezheng |
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| DOI | 10.1039/c2cp41690e |
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| Notes | 10.1039/c2cp41690e Electronic supplementary information (ESI) available. See DOI |
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| References_xml | – issn: 1969 publication-title: Dissociation Constants of Inorganic Acids and Bases in Aqueous Solution doi: Perrin – issn: 2003 publication-title: Gaussian 03, Version 6.2 doi: Frisch – issn: 1978 publication-title: US Pat. doi: Wolga – issn: 1992 publication-title: Absolute detection of O (a Δ) concentrations doi: Keating Hanko Helms Perram – issn: 2011 publication-title: CRC Handbook of Chemistry and Physics doi: Haynes |
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| Snippet | Non-basic hydrogen peroxide was found to be very easy to react with Cl
2
to produce singlet oxygen O
2
(a
1
Δ
g
) (
i.e.
the molecular oxygen in its first... |
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| Title | Production of singlet oxygen by the reaction of non-basic hydrogen peroxide with chlorine gasElectronic supplementary information (ESI) available. See DOI: 10.1039/c2cp41690e |
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