A simple and highly selective receptor for iodide in aqueous solutionElectronic supplementary information (ESI) available. See DOI: 10.1039/c1an15834a

We synthesized a simple fluorescent receptor 3 bearing two boronic acid groups as recognition sites. The recognition behaviour of receptor 3 towards various anions was evaluated in THF/H 2 O (1:1, v/v) solution. Receptor 3 showed high selectivity for iodide among a series of anions. Fluorescence spe...

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Main Authors Cheng, Hsiu-Jung, Yan, Hongbin, Sun, Yao-Lin, Lu, Cheng-Yi, Huang, Tzu-Yu, Chen, Shau-Jiun, Hu, Ching-Han, Wu, Ying-Yann, Wu, An-Tai
Format Journal Article
LanguageEnglish
Published 10.01.2012
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Abstract We synthesized a simple fluorescent receptor 3 bearing two boronic acid groups as recognition sites. The recognition behaviour of receptor 3 towards various anions was evaluated in THF/H 2 O (1:1, v/v) solution. Receptor 3 showed high selectivity for iodide among a series of anions. Fluorescence spectroscopy and computational calculations revealed that the electrostatic interaction played a crucial role in its high selectivity for iodide. A simple boronic acid-based fluorescent receptor was synthesized and the receptor showed high selectivity for iodide among a series of anions.
AbstractList We synthesized a simple fluorescent receptor 3 bearing two boronic acid groups as recognition sites. The recognition behaviour of receptor 3 towards various anions was evaluated in THF/H 2 O (1:1, v/v) solution. Receptor 3 showed high selectivity for iodide among a series of anions. Fluorescence spectroscopy and computational calculations revealed that the electrostatic interaction played a crucial role in its high selectivity for iodide. A simple boronic acid-based fluorescent receptor was synthesized and the receptor showed high selectivity for iodide among a series of anions.
Author Cheng, Hsiu-Jung
Huang, Tzu-Yu
Sun, Yao-Lin
Wu, Ying-Yann
Yan, Hongbin
Wu, An-Tai
Hu, Ching-Han
Chen, Shau-Jiun
Lu, Cheng-Yi
AuthorAffiliation Department of Chemistry
Brock University
Rezwave Technology Inc
National Changhua University of Education
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  givenname: Hsiu-Jung
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  givenname: Cheng-Yi
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  givenname: Tzu-Yu
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  givenname: An-Tai
  surname: Wu
  fullname: Wu, An-Tai
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Electronic supplementary information (ESI) available. See DOI
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