Electrochemical generation of silver acetylides from terminal alkynes with a Ag anode and integration into sequential Pd-catalysed coupling with arylboronic acidsElectronic supplementary information (ESI) available: experimental details. See DOI: 10.1039/c0cc02633f

An electro-oxidative method for generating silver acetylides from acetylenes with a Ag anode was developed. The reaction could be integrated into a Pd-catalysed electrochemical Sonogashira-type reaction. In the presence of the catalytic amount of Pd(OAc) 2 and 4-BzO-TEMPO, electro-generated silver a...

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Bibliographic Details
Main Authors Mitsudo, Koichi, Shiraga, Takuya, Mizukawa, Jun-ichi, Suga, Seiji, Tanaka, Hideo
Format Journal Article
LanguageEnglish
Published 28.12.2010
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