A structural and functional mimic of the active site of NiFe hydrogenasesThis article is part of a ChemComm 'Hydrogen' web-based themed issue.Electronic supplementary information (ESI) available: Experimental procedures and additional crystallographic, spectroscopic, electrochemical and electrocatalytical data. CCDC 760104. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c001675f

• Main Authors: Canaguier, Sigolène, Field, Martin, Oudart, Yohan, Pécaut, Jacques, Fontecave, Marc, Artero, Vincent
• Format: Journal Article
• Language: English
• Published: 03.08.2010

The structural mimic of the active site of NiFe hydrogenases, [Ni(xbsms)FeCp(CO)](BF 4 ), is an electrocatalyst for hydrogen evolution from trifluoroacetic acid in DMF [Ni(xbsms)FeCp(CO)](BF 4 ) is both a structural and functional bio-inspired model of the active site of NiFe hydrogenases catalyzing...