Preparative and Catalytic Properties of Mo VI Mononuclear and Metallosupramolecular Coordination Assemblies Bearing Hydrazonato Ligands

• Published in: International journal of molecular sciences Vol. 25; no. 3
• Main Authors: Mandarić, Mirna, Topić, Edi, Agustin, Dominique, Pisk, Jana, Vrdoljak, Višnja
• Format: Journal Article
• Language: English
• Published: Switzerland 25.01.2024
• Subjects: Catalysis; Cyclooctanes; Hydrazones; Ligands; Water; dinuclear; metallosupramolecular; DFT; epoxidation; cyclooctene; catalysis; polymers; hydrazone; metallacycles; molybdenum

A series of polynuclear, dinuclear, and mononuclear Mo(VI) complexes were synthesized with the hydrazonato ligands derived from 5-methoxysalicylaldehyde and the corresponding hydrazides (isonicotinic hydrazide (H L ), nicotinic hydrazide (H L ), 2-aminobenzhydrazide (H L ), or 4-aminobenzhydrazide (...