Confinement Effects in Well-Defined Metal-Organic Frameworks (MOFs) for Selective CO 2 Hydrogenation: A Review
Decarbonization has become an urgent affair to restrain global warming. CO hydrogenation coupled with H derived from water electrolysis is considered a promising route to mitigate the negative impact of carbon emission and also promote the application of hydrogen. It is of great significance to deve...
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Published in | International journal of molecular sciences Vol. 24; no. 4 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Switzerland
20.02.2023
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Abstract | Decarbonization has become an urgent affair to restrain global warming. CO
hydrogenation coupled with H
derived from water electrolysis is considered a promising route to mitigate the negative impact of carbon emission and also promote the application of hydrogen. It is of great significance to develop catalysts with excellent performance and large-scale implementation. In the past decades, metal-organic frameworks (MOFs) have been widely involved in the rational design of catalysts for CO
hydrogenation due to their high surface areas, tunable porosities, well-ordered pore structures, and diversities in metals and functional groups. Confinement effects in MOFs or MOF-derived materials have been reported to promote the stability of CO
hydrogenation catalysts, such as molecular complexes of immobilization effect, active sites in size effect, stabilization in the encapsulation effect, and electron transfer and interfacial catalysis in the synergistic effect. This review attempts to summarize the progress of MOF-based CO
hydrogenation catalysts up to now, and demonstrate the synthetic strategies, unique features, and enhancement mechanisms compared with traditionally supported catalysts. Great emphasis will be placed on various confinement effects in CO
hydrogenation. The challenges and opportunities in precise design, synthesis, and applications of MOF-confined catalysis for CO
hydrogenation are also summarized. |
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AbstractList | Decarbonization has become an urgent affair to restrain global warming. CO
hydrogenation coupled with H
derived from water electrolysis is considered a promising route to mitigate the negative impact of carbon emission and also promote the application of hydrogen. It is of great significance to develop catalysts with excellent performance and large-scale implementation. In the past decades, metal-organic frameworks (MOFs) have been widely involved in the rational design of catalysts for CO
hydrogenation due to their high surface areas, tunable porosities, well-ordered pore structures, and diversities in metals and functional groups. Confinement effects in MOFs or MOF-derived materials have been reported to promote the stability of CO
hydrogenation catalysts, such as molecular complexes of immobilization effect, active sites in size effect, stabilization in the encapsulation effect, and electron transfer and interfacial catalysis in the synergistic effect. This review attempts to summarize the progress of MOF-based CO
hydrogenation catalysts up to now, and demonstrate the synthetic strategies, unique features, and enhancement mechanisms compared with traditionally supported catalysts. Great emphasis will be placed on various confinement effects in CO
hydrogenation. The challenges and opportunities in precise design, synthesis, and applications of MOF-confined catalysis for CO
hydrogenation are also summarized. |
Author | Lu, Xiaofei Li, Duanxing Song, Chuqiao Lin, Lili Qi, Xingyu |
Author_xml | – sequence: 1 givenname: Xiaofei surname: Lu fullname: Lu, Xiaofei organization: Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan – sequence: 2 givenname: Chuqiao surname: Song fullname: Song, Chuqiao organization: Institute of Industrial Catalysis, State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China – sequence: 3 givenname: Xingyu surname: Qi fullname: Qi, Xingyu organization: Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan – sequence: 4 givenname: Duanxing orcidid: 0000-0002-6669-5912 surname: Li fullname: Li, Duanxing organization: Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan – sequence: 5 givenname: Lili surname: Lin fullname: Lin, Lili organization: Institute of Industrial Catalysis, State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/36835639$$D View this record in MEDLINE/PubMed |
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Keywords | encapsulation synergy effect immobilization interface catalysis MOF-derived materials selective CO2 hydrogenation metal–organic frameworks size effect confinement effects |
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hydrogenation coupled with H
derived from water electrolysis is considered a... |
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Title | Confinement Effects in Well-Defined Metal-Organic Frameworks (MOFs) for Selective CO 2 Hydrogenation: A Review |
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