Room-temperature reduction of NO 2 in a Li-NO 2 battery: a proof of concept

Although considerable effort has been devoted to purifying nitrogen oxides (NO ), it is still challenging to effectively reduce NO at room temperature and ambient pressure without catalysts. In this study, as a proof-of-concept, we have for the first time demonstrated the room-temperature reduction...

Full description

Saved in:
Bibliographic Details
Published inScience bulletin Vol. 65; no. 1; p. 55
Main Authors Liang, Jiachen, Zhang, Chen, Liu, Donghai, Wu, Tianhao, Tao, Ying, Ling, Guo-Wei, Yu, Hai-Jun, Lu, Jun, Yang, Quan-Hong
Format Journal Article
LanguageEnglish
Published Netherlands 15.01.2020
Subjects
Li-NO battery
Air pollutants
Energy-storage devices
Nitrogen dioxide
Carbon
Online AccessGet more information

Cover

Abstract Although considerable effort has been devoted to purifying nitrogen oxides (NO ), it is still challenging to effectively reduce NO at room temperature and ambient pressure without catalysts. In this study, as a proof-of-concept, we have for the first time demonstrated the room-temperature reduction of nitrogen dioxide (NO ) using a rechargeable lithium-nitrogen dioxide (Li-NO ) battery. The battery shows a capacity of 884 mAh g at 50 mA g (an actual energy density of 666 Wh kg ) and a promising electrochemical Faraday efficiency (FE) of 67%. The unique properties of Li-NO rechargeable batteries not only provide a way to reduce and recycle NO but also highlight the potential of oxidative air pollutants as energy sources for next-generation electrochemical energy storage (EES) systems.
AbstractList Although considerable effort has been devoted to purifying nitrogen oxides (NO ), it is still challenging to effectively reduce NO at room temperature and ambient pressure without catalysts. In this study, as a proof-of-concept, we have for the first time demonstrated the room-temperature reduction of nitrogen dioxide (NO ) using a rechargeable lithium-nitrogen dioxide (Li-NO ) battery. The battery shows a capacity of 884 mAh g at 50 mA g (an actual energy density of 666 Wh kg ) and a promising electrochemical Faraday efficiency (FE) of 67%. The unique properties of Li-NO rechargeable batteries not only provide a way to reduce and recycle NO but also highlight the potential of oxidative air pollutants as energy sources for next-generation electrochemical energy storage (EES) systems.
Author Liang, Jiachen
Liu, Donghai
Tao, Ying
Yang, Quan-Hong
Ling, Guo-Wei
Wu, Tianhao
Zhang, Chen
Yu, Hai-Jun
Lu, Jun
Author_xml – sequence: 1
  givenname: Jiachen
  surname: Liang
  fullname: Liang, Jiachen
  organization: Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300350, China
– sequence: 2
  givenname: Chen
  surname: Zhang
  fullname: Zhang, Chen
  organization: School of Marine Science and Technology, Tianjin University, Tianjin 300350, China
– sequence: 3
  givenname: Donghai
  surname: Liu
  fullname: Liu, Donghai
  organization: Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300350, China
– sequence: 4
  givenname: Tianhao
  surname: Wu
  fullname: Wu, Tianhao
  organization: College of Materials Science and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing University of Technology, Beijing 100124, China
– sequence: 5
  givenname: Ying
  surname: Tao
  fullname: Tao, Ying
  organization: Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300350, China
– sequence: 6
  givenname: Guo-Wei
  surname: Ling
  fullname: Ling, Guo-Wei
  organization: School of Marine Science and Technology, Tianjin University, Tianjin 300350, China
– sequence: 7
  givenname: Hai-Jun
  surname: Yu
  fullname: Yu, Hai-Jun
  organization: College of Materials Science and Engineering, Key Laboratory of Advanced Functional Materials, Ministry of Education, Beijing University of Technology, Beijing 100124, China
– sequence: 8
  givenname: Jun
  surname: Lu
  fullname: Lu, Jun
  organization: Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne, IL 60439, USA
– sequence: 9
  givenname: Quan-Hong
  surname: Yang
  fullname: Yang, Quan-Hong
  email: qhyangcn@tju.edu.cn
  organization: Nanoyang Group, State Key Laboratory of Chemical Engineering, School of Chemical Engineering and Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300350, China; Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China. Electronic address: qhyangcn@tju.edu.cn
BackLink https://www.ncbi.nlm.nih.gov/pubmed/36659069$$D View this record in MEDLINE/PubMed
BookMark eNqFjcsKwjAURIMo1kd_QfIDgRib0rgVRVAUxH1J21sImAe36aJ_bxFdCwPDHA7MkkyddzAhC8GVZEoU24SkXWcqLrOMy4KrOUl2eS4Vz9WCXB7eWxbBBkAdewSK0PR1NN5R39LbnQpqHNX0athnVDpGwGE_ooB-VMbU3tUQ4prMWv3qIP32imxOx-fhzEJfWWjKgMZqHMrfu_grvAGZLzsl
ContentType Journal Article
Copyright Copyright © 2019 Science China Press. Published by Elsevier B.V. All rights reserved.
Copyright_xml – notice: Copyright © 2019 Science China Press. Published by Elsevier B.V. All rights reserved.
DBID NPM
DatabaseName PubMed
DatabaseTitle PubMed
DatabaseTitleList PubMed
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod no_fulltext_linktorsrc
EISSN 2095-9281
ExternalDocumentID 36659069
Genre Journal Article
GroupedDBID ALMA_UNASSIGNED_HOLDINGS
NPM
ID FETCH-pubmed_primary_366590692
IngestDate Wed Mar 20 10:58:35 EDT 2024
IsPeerReviewed true
IsScholarly true
Issue 1
Keywords Li-NO battery
Air pollutants
Energy-storage devices
Nitrogen dioxide
Carbon
Language English
License Copyright © 2019 Science China Press. Published by Elsevier B.V. All rights reserved.
LinkModel OpenURL
MergedId FETCHMERGED-pubmed_primary_366590692
PMID 36659069
ParticipantIDs pubmed_primary_36659069
PublicationCentury 2000
PublicationDate 2020-Jan-15
PublicationDateYYYYMMDD 2020-01-15
PublicationDate_xml – month: 01
  year: 2020
  text: 2020-Jan-15
  day: 15
PublicationDecade 2020
PublicationPlace Netherlands
PublicationPlace_xml – name: Netherlands
PublicationTitle Science bulletin
PublicationTitleAlternate Sci Bull (Beijing)
PublicationYear 2020
SSID ssib054405809
Score 4.283827
Snippet Although considerable effort has been devoted to purifying nitrogen oxides (NO ), it is still challenging to effectively reduce NO at room temperature and...
SourceID pubmed
SourceType Index Database
StartPage 55
Title Room-temperature reduction of NO 2 in a Li-NO 2 battery: a proof of concept
URI https://www.ncbi.nlm.nih.gov/pubmed/36659069
Volume 65
hasFullText
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3NS8MwFA9OL15E8ftj5OBtZJS0SRtvMpQxtQOZsNtIutb1YDfGdtC_3pekXxYn6qW0L6Et_SWvvzzyfg-h68hlXHAliM98l3iJMyVScViqUBFIz5kKJnXu8FPI-y_eYMzGVRVHk12yUt3o49u8kv-gCjbAVWfJ_gHZ8qZggHPAF46AMBx_hfEzsF6ixaVyZeTOUguxFhwwHHaoDmdIWHgTc6GMmOa7TXAG1wmdzK5yk7lYp6nFjFd1cW69bSfNw8uDVAtBl_Yy7NyrGR_TtaXo2etMpqX3X9shIrOZnNdjDlRvXSM267IbG99EHV3ikdpqK4UjtUUfvgwY6xWtEG8NkMWbQcTlnAnHlmr5ubWhiV00tVDLD7R3C6sYDfOAgwaOloMtujWWDIY6jPbRXs758a0F8ABtxdkhemiCh0vw8DzB4RBTnGZYYgMeXOTg3YDJQKd75dAdofb93ajXJ_b5k4WVEJkUb0aP0XY2z-JThGXscWAssMQLHA-mieAskipRCfwCApeLM3Sy4SbnG1su0G4F3yXaSWDgx1fAolaqbT7aJ_xMIjU
link.rule.ids 783
linkProvider National Library of Medicine
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Room-temperature+reduction+of+NO+2+in+a+Li-NO+2+battery%3A+a+proof+of+concept&rft.jtitle=Science+bulletin&rft.au=Liang%2C+Jiachen&rft.au=Zhang%2C+Chen&rft.au=Liu%2C+Donghai&rft.au=Wu%2C+Tianhao&rft.date=2020-01-15&rft.eissn=2095-9281&rft.volume=65&rft.issue=1&rft.spage=55&rft_id=info%3Apmid%2F36659069&rft_id=info%3Apmid%2F36659069&rft.externalDocID=36659069