Molecular geometries and other properties of H 2 O⋯AgI and H 3 N⋯AgI as characterised by rotational spectroscopy and ab initio calculations

• Published in: The Journal of chemical physics Vol. 147; no. 23; p. 234308
• Main Authors: Medcraft, Chris, Gougoula, Eva, Bittner, Dror M, Mullaney, John C, Blanco, Susana, Tew, David P, Walker, Nicholas R, Legon, Anthony C
• Format: Journal Article
• Language: English
• Published: United States 21.12.2017

The rotational spectra of H N⋯AgI and H O⋯AgI have been recorded between 6.5 and 18.5 GHz by chirped-pulse Fourier-transform microwave spectroscopy. The complexes were generated through laser vaporisation of a solid target of silver or silver iodide in the presence of an argon gas pulse containing a...