[ReH(SH)2 (PMe3 )4 ]: A Catalyst for Fundamental Transformations Involving H2 and H2 S
Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH)...
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| Published in | Angewandte Chemie International Edition Vol. 40; no. 12; pp. 2351 - 2353 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
18.06.2001
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| Online Access | Get full text |
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| Abstract | Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH) and hydridic (ReH) sites; these sites communicate by an intramolecular exchange process (see scheme; X=OMe, SH). |
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| AbstractList | Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur poisons catalysts is clearly inappropriate in this case. The catalytic properties of 1 result from its difunctional nature with both protic (SH) and hydridic (ReH) sites; these sites communicate by an intramolecular exchange process (see scheme; X=OMe, SH). |
| Author | Wilson, Scott R Dopke, Joel A Rauchfuss, Thomas B Schwarz, Daniel E |
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| Snippet | Not a poison! In contrast to the high reactivity of 1, the corresponding trihydride [ReH3 (PMe3 )4 ] is kinetically inert. Thus, the usual view that sulfur... |
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| Title | [ReH(SH)2 (PMe3 )4 ]: A Catalyst for Fundamental Transformations Involving H2 and H2 S |
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