Stability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres
We revealed the inherent instability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres due to the denitrification toward alpha -Fe by forming NH sub(3) at the particle surface. Coating the particle surface with SiO sub(2) to suppress the formation of NH sub(3) has proven to be a si...
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Published in | Chemical communications (Cambridge, England) Vol. 50; no. 53; pp. 7040 - 7043 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
01.06.2014
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Subjects | |
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Abstract | We revealed the inherent instability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres due to the denitrification toward alpha -Fe by forming NH sub(3) at the particle surface. Coating the particle surface with SiO sub(2) to suppress the formation of NH sub(3) has proven to be a simple yet powerful method to enhance the stability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres. |
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AbstractList | We revealed the inherent instability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres due to the denitrification toward alpha -Fe by forming NH sub(3) at the particle surface. Coating the particle surface with SiO sub(2) to suppress the formation of NH sub(3) has proven to be a simple yet powerful method to enhance the stability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres. |
Author | Kobayashi, Naoya Takano, Mikio Ogawa, Tomoyuki Gallage, Ruwan Isoda, Seiji Ogata, Yasunobu Hayashi, Naoaki Takahashi, Migaku Kusano, Yoshihiro Yamamoto, Shinpei |
Author_xml | – sequence: 1 givenname: Shinpei surname: Yamamoto fullname: Yamamoto, Shinpei – sequence: 2 givenname: Ruwan surname: Gallage fullname: Gallage, Ruwan – sequence: 3 givenname: Seiji surname: Isoda fullname: Isoda, Seiji – sequence: 4 givenname: Yasunobu surname: Ogata fullname: Ogata, Yasunobu – sequence: 5 givenname: Yoshihiro surname: Kusano fullname: Kusano, Yoshihiro – sequence: 6 givenname: Naoya surname: Kobayashi fullname: Kobayashi, Naoya – sequence: 7 givenname: Tomoyuki surname: Ogawa fullname: Ogawa, Tomoyuki – sequence: 8 givenname: Naoaki surname: Hayashi fullname: Hayashi, Naoaki – sequence: 9 givenname: Migaku surname: Takahashi fullname: Takahashi, Migaku – sequence: 10 givenname: Mikio surname: Takano fullname: Takano, Mikio |
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Title | Stability of alpha ''-Fe sub(16)N sub(2) in hydrogenous atmospheres |
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